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DON concentration was determined by subtracting the concentrations of PNsusp, NH4+, and NO3-+NO2- (reported in Berthelot et al., 2015, Biogeosciences) from the measured TN concentration of each sample with a propagated error of +/- 0.5 \u03bcM.  The d15N of the resulting NO3- was measured using the denitrifier method (Casciotti et al., 2002; McIlvin and Casciotti, 2011; Sigman et al., 2001). </p>\n<p>The d15N of PNsink was measured using a Thermo Scientific Flash 2000 Elemental Analyzer coupled with a Delta Plus Thermo Scientific mass spectrometer. </p>\n<p>The average standard deviation for individual DON concentration measurements was +/- 0.3 \u00b5M. DON concentration was determined by subtracting the concentrations of PNsusp, NH4+, and NO3-+NO2- (reported in Berthelot et al., 2015, Biogeosciences) from the measured TN concentration of each sample with a propagated error of +/- 0.5 \u03bcM. </p>\n<p>The d15N of TN was determined via persulfate oxidation of TN to NO3-  (Knapp et al., 2005) and subsequent analysis of NO3- d15N by the denitrifier method, with a propagated error for DON d15N calculated using a Monte Carlo method (Press et al., 1992) of +/- 0.6\u2030. Samples were calibrated with IAEA N3 and USGS 34 NO3- d15N isotopic reference materials as described in McIlvin and Casciotti, 2011. </p>\n<p>The d15N of PNsink was measured using a Thermo Scientific Flash 2000 Elemental Analyzer coupled<br />\nwith a Delta Plus Thermo Scientific mass spectrometer. The average standard deviation for standards was +/- 0.06\u2030.</p></div>","@type":"rdf:HTML"}],"http://purl.org/dc/terms/description":[{"@value":"<div><p>These data were published in\u00a0Knapp et al., 2016, Biogeosciences, Supplementary Table 1.</p></div>","@type":"rdf:HTML"}],"http://www.w3.org/2000/01/rdf-schema#label":[{"@value":"VAHINE nitrogen","@type":"xsd:string"}],"http://ocean-data.org/schema/hasProcessingDescription":[{"@value":"<div><p>BCO-DMO Data Manager Processing Notes:<br />\n* added a conventional header with dataset name, PI name, version date<br />\n* modified parameter names to conform with BCO-DMO naming conventions<br />\n* blank values in this dataset are displayed as \"nd\" for \"no data.\"\u00a0 nd is the default missing data identifier in the BCO-DMO system.</p></div>","@type":"rdf:HTML"}],"http://purl.org/dc/terms/identifier":[{"@value":"739646","@type":"xsd:int"}],"http://purl.org/dc/terms/title":[{"@value":"VAHINE nitrogen"}],"http://purl.org/dc/terms/date":[{"@value":"2018-07-10T15:07:01-04:00","@type":"xsd:dateTime"}],"http://purl.org/dc/terms/created":[{"@value":"2018-07-10T15:07:01-04:00","@type":"xsd:dateTime"}],"http://purl.org/dc/terms/modified":[{"@value":"2023-07-07T16:10:26-04:00","@type":"xsd:dateTime"}],"http://rdfs.org/ns/void#inDataset":[{"@id":"http://www.bco-dmo.org/"}],"http://ocean-data.org/schema/namedGraph":[{"@value":"urn:bcodmo:dataset:739646","@type":"xsd:token"}],"http://ocean-data.org/schema/osprey_page":[{"@id":"https://osprey.bco-dmo.org/dataset/739646"}],"http://ocean-data.org/schema/identifier":[{"@id":"urn:bcodmo:osprey:v2:node:identifier:739646"}],"http://ocean-data.org/schema/datasetTitle":[{"@value":"Dissolved and sinking particulate organic nitrogen data from a large volume mesocosm experiment in the Noumea Lagoon, New Caledonia, measured from January to February 2013","@language":"en-US"}],"http://ocean-data.org/schema/abstract":[{"@value":"This dataset includes water column dissolved organic nitrogen (DON) concentration and d15N data, as well as sinking particulate nitrogen d15N (\u201cPNsink d15N\u201d) data. These samples were collected inside triplicate (\u201cM1\u201d, \u201cM2\u201d, and \u201cM3\u201d) large volume (i.e., 2.3 m diameter, 15 m deep) mesocosm experiments deployed in a lagoon off of Noumea, New Caledonia. DON samples were collected at 6 m depth daily by a Teflon pump and PVC tubing. PNsink d15N samples were collected daily by SCUBA divers who removed a screw-top plastic bottle from the bottom of the plastic mesocosm. \u201cSwimmers\u201d were removed from the PNsink d15N samples prior to analysis.\r\n\r\nThese measurements were made as part of project \"VAriability of vertical and tropHIc transfer of diazotroph derived N in the south wEst Pacific\" (VAHINE) to study the fate of fixed nitrogen in the oceanic pelagic food web and its potential impact on carbon export. The field campaign of VAHINE took place in the South West Pacific (New Caledonia) in January and February of 2013 and involved 16 scientists from France, Israel, Germany and the USA.","@language":"en-US"}],"http://purl.org/dc/terms/rights":[{"@id":"https://creativecommons.org/licenses/by/4.0/"}],"http://ocean-data.org/schema/deprecated":[{"@value":"false","@type":"xsd:boolean"}],"http://ocean-data.org/schema/temporalExtent":[{"@id":"urn:bcodmo:dataset:739646:temporalExtent"}],"http://ocean-data.org/schema/spatialCoverage":[{"@id":"urn:bcodmo:dataset:739646:spatialCoverage"}],"http://purl.org/dc/terms/bibliographicCitation":[{"@value":"Knapp, A. (2018) Dissolved and sinking particulate organic nitrogen data from a large volume mesocosm experiment in the Noumea Lagoon, New Caledonia, measured from January to February 2013. Biological and Chemical Oceanography Data Management Office (BCO-DMO). 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