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Please see the related methods papers for all methodology details\u00a0(Measures et al., 2008 and Milne et al., 2010).

\n

In brief, samples were collected using a rosette system, described in Measures et al. (2008), comprised of a Seabird SBE 911+ CTD, SBE 443 dissolved oxygen sensor,\u00a0Wet Labs FL 1 fluorometer, and 12-L Teflon coated GO-FLO bottles. See Measures et al. (2008) for sampling procedures/protocols.

\n

Milne et al. (2010) describes the methods used\u00a0for the simultaneous determination of eight trace metals (Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb) in seawater using the commercially available Toyopearl AF-Chelate-650M chelating resin. Isotope dilution (ID) was employed for the determination of Fe, Ni, Cu, Zn, Cd and Pb whereas the method of standard addition was used for the mono-isotopic elements Mn and Co. The method was verified through the analysis of certified reference material (NASS-5) and the SAFe inter-comparison samples (S1 and D2).

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Profiles of dissolved trace elements collected using a trace-metal clean rosette from surface to 1000m depth.

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Missing data are coded -999. This occurs when the ICPMS data for an extracted sample is unreliable. All data reduction was done using Excel.

\n

The WHP flag code scheme was used with this data set. The WHP bottle parameter data quality codes are:
\n1 = Sample for this measurement was drawn from water bottle but analysis not received. Note that if water is drawn for any measurement from a water bottle, the quality flag for that parameter must be set equal to 1 initially to ensure that all water samples are accounted for.
\n2 = Acceptable measurement.
\n3 = Questionable measurement.
\n4 = Bad measurement.
\n5 = Not reported.
\n6 = Mean of replicate measurements (Number of replicates should be specified in the -.DOC file and replicate data tabulated).
\n7 = Manual chromatographic peak measurement.
\n8 = Irregular digital chromatographic peak integration.
\n9 = Sample not drawn for this measurement from this bottle.

\n

BCO-DMO Processing:
\n- formatted TIME column to HHMM;
\n- replaced \"<LOD\" with \"BDL\";
\n- filled empty cells with \"nd\";
\n- made corrections to EXPOCODE numbers: changed P16N_3250TT192 to P16N_3250TT191 and \"33RR20050\" to \"33RR200501\";
\n- added date/time field in ISO8601 format using the original DATE and TIME fields provided.

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