Sediment cores were obtained by a MC-800 multi-corer and profiled immediately with voltammetric Hg/Au microelectrodes deployed on a computer-controlled micromanipulator (Beckler et al., 2016). Sediment pore waters were then extracted from the same core and either preserved until analysis or analyzed immediately onboard ship. Sampling and analyses were conducted immediately after sediment collection to minimize artifacts from exposure to the atmosphere.
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After profiling, sediments were immediately sliced under N\u2082 atmosphere and pore waters extracted by centrifugation at 3000 rpm under N\u2082 atmosphere. Finally, pore waters were immediately filtered (0.2 \u00b5M PSE Puradisc syringe filters, Whatman) under N\u2082 atmosphere and either preserved at -20C until analysis (SO\u2084\u00b2\u207b), dispensed directly into reagents for analysis (SPO\u2084\u00b3\u207b), or analyzed immediately (DIC). SO\u2084\u00b2\u207b was measured by non-suppressed HPLC with UV detection (Beckler et al., 2014). SPO\u2084\u00b3\u207b was measured spectrophotometrically using the molybdate-blue method after natural color correction to avoid interferences from dissolved silica and sulfides (Murphy and Riley, 1962). Finally, DIC was measured by flow injection analysis with conductivity detection after spiking samples with 10 mM ZnCl\u2082 to prevent dissolved sulfide interferences (Hall and Aller, 1992). All errors reported for the electrochemical measurements represent the standard deviation of at least triplicate measurements. Errors of all other parameters represent the analytical error propagated from calibration curves, dilution, and instrumental drift
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Problem report: Some of the data are missing because pore water volumes were too low to make all the measurements.
Chromatographic data were processed using Voltint (Bristow and Taillefert, 2008), a MatlabTM-based software developed for these applications. Spectrophotometric measurements were processed manually.
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BCO-DMO Processing:
\n- added date column using original year, month, and day columns.