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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/2373.rdf" xlink:actuate="onRequest">Nutrient data from RVIB Nathaniel B. Palmer cruises NBP0103, NBP0104, NBP0202, and NBP0204 in the Southern Ocean from 2001-2002 (SOGLOBEC project)</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Fanning, K. (2010) Nutrient data from RVIB Nathaniel B. Palmer cruises NBP0103, NBP0104, NBP0202, and NBP0204 in the Southern Ocean from 2001-2002 (SOGLOBEC project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2010-01-01 [if applicable, indicate subset used]. doi:10.1575/1912/bco-dmo.2373.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Nutrient data for the NB Palmer 2001-2002 cruises Dataset Description: &amp;lt;h2&amp;gt;Nutrients from Bottle Casts&amp;lt;/h2&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;h3&amp;gt;Methods&amp;lt;/h3&amp;gt;

&amp;lt;p&amp;gt;Analytical methods used for silica, phosphate, nitrite, and nitrate follow the recommendations of Gordon et al. (1993) for the WOCE WHP project.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The analytical system we employ is a five-channel Technicon Autoanalyzer II upgraded with new heating baths, proportional pumps, colorimeters, improved optics, and an analog to digital conversion system (New Analyzer Program v. 2.40 by Labtronics, Inc.) This Technicon is designed for shipboard as well as laboratory use.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Silica is determined by forming the heteropoly acid of dissolved orthosilicic acid and ammonium molybdate, reducing it with stannous chloride, and then measuring its optical transmittance.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Phosphate is determined by creating the phosphomolybdate heteropoly acid in much the same way as with the silica method. However, its reducing agent is dihydrazine sulfate, after which its transmittance is also measured. A heating bath is required to maximize the color yield.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Nitrite is determined essentially by the Bendschneider and Robinson (1952) technique in which nitrite is reacted with sulfanilamide (SAN) to form a diazotized derivative that is then reacted with a substituted ethylenediamine compound (NED) to form a rose pink azo dye which is measured colorimetrically.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Nitrate is determined by difference after a separate aliquot of a sample is passed through a Cd reduction column to convert its nitrate to nitrite, followed by the measurement of the &amp;quot;augmented&amp;quot; nitrite concentration using the same method as in the nitrite analysis.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;In the analytical ammonia method, ammonium reacts with alkaline phenol and hypochlorite to form indophenolblue. Sodium nitroferricyanide intensifies the blue color formed, which is then measured in a colorimeter of our nutrient-analyzer. Precipitation of calcium and magnesium hydroxides is eliminated by the addition of sodium citrate complexing reagent. A heating bath is required. Our version of this technique is based on modifications of published methods such as the article by F. Koroleff in Grasshoff (1976). These modifications were made at Alpkem (now Astoria-Pacific International, Inc.) and at L.Gordon's nutrient laboratory at Oregon State University.&amp;lt;/p&amp;gt;

&amp;lt;h3&amp;gt;Data&amp;lt;/h3&amp;gt;

&amp;lt;p&amp;gt;Nitrate, nitrite, phosphate, ammonia, and silica were measured from every niskin bottle tripped from all hydrocasts on this cruise. All concentrations are reported in micromoles per liter.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;References&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Gordon, L.I., J.C. Jennings, Jr., A.A. Ross, and J.M. Krest, A Suggested Protocol For Continuous Flow Automated Analysis of Seawater Nutrients, in WOCE Operation Manual, WHP Office Report 90-1, &amp;lt;strong&amp;gt;WOCE Report 77 No. 68/91, 1-52, 1993.&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Grasshoff, K. 1976. &amp;lt;strong&amp;gt;Methods of Seawater Analysis&amp;lt;/strong&amp;gt;, Verlag Chemie, Weinheim, Germany, and New York, NY, 317 pp.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Data Contributed By:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Kent Fanning&amp;lt;br /&amp;gt;
Dept. of Marine Science&amp;lt;br /&amp;gt;
University of South Florida&amp;lt;br /&amp;gt;
140 Seventh Avenue, South&amp;lt;br /&amp;gt;
St. Petersburg, FL 33701&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
phone: 727 553 1594&amp;lt;br /&amp;gt;
e-mail: &amp;lt;a href=&amp;quot;mailto: kaf@seas.marine.usf.edu&amp;quot;&amp;gt; kaf@seas.marine.usf.edu &amp;lt;/a&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;em&amp;gt;Last updated January 13, 2006; gfh&amp;lt;/em&amp;gt;&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;Nitrate, nitrite, phosphate, ammonia, and silica were measured from every niskin bottle tripped from all hydrocasts on this cruise. All concentrations are reported in micromoles per liter.&amp;lt;/p&amp;gt;</gco:CharacterString>
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	Name: cruiseid
	Units: unknown
	Description: &lt;p&gt;cruise identification &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7812.rdf
	Name: year
	Units: unknown
	Description: &lt;p&gt; year   &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7813.rdf
	Name: station_desc
	Units: unknown
	Description: &lt;p&gt;standard station number&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7814.rdf
	Name: station
	Units: dimensionless
	Description: &lt;p&gt; station identification per event log &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7815.rdf
	Name: cast
	Units: dimensionless
	Description: &lt;p&gt; CTD rosette cast number  &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7816.rdf
	Name: lat
	Units: DD.D
	Description: &lt;p&gt; latitude, negative = South &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7817.rdf
	Name: lon
	Units: DDD.D
	Description: &lt;p&gt; longitude, negative = West &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7818.rdf
	Name: yrday_gmt
	Units: YYY
	Description: &lt;p&gt; year day GMT based on Julian calendar &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7819.rdf
	Name: day_gmt
	Units: unknown
	Description: &lt;p&gt; day of month, GMT (01-31) &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7820.rdf
	Name: month_gmt
	Units: unknown
	Description: &lt;p&gt; month of year, GMT (01-12) &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7821.rdf
	Name: depth
	Units: meters
	Description: &lt;p&gt;  depth of sample  &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7822.rdf
	Name: bottle
	Units: unknown
	Description: &lt;p&gt; bottle number   &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7823.rdf
	Name: NO3_NO2
	Units: micromoles/liter
	Description: &lt;p&gt; nitrate + nitrite &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7824.rdf
	Name: NO2
	Units: micromoles/liter
	Description: &lt;p&gt; nitrite    &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7825.rdf
	Name: SiOH_4
	Units: micromoles/liter
	Description: &lt;p&gt; silicate   &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7826.rdf
	Name: NH4
	Units: micromoles/liter
	Description: &lt;p&gt; ammonium   &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7827.rdf
	Name: PO4
	Units: micromoles/liter
	Description: &lt;p&gt; phosphate  &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7828.rdf
	Name: NO3
	Units: micromoles/liter
	Description: &lt;p&gt; nitrate    &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/7829.rdf
	Name: Comments
	Units: unknown
	Description: &lt;p&gt;comments&lt;/p&gt; 
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                <gco:CharacterString>&amp;lt;p&amp;gt;Nitrate, nitrite, phosphate, ammonia, and silica were measured from every niskin bottle tripped from all hydrocasts on this cruise. All concentrations are reported in micromoles per liter.&amp;lt;/p&amp;gt;

from Cruise: NBP0103 Nitrate, nitrite, phosphate, ammonia, and silica were measured from every niskin bottle tripped from all hydrocasts on this cruise. All concentrations are reported in micromoles per liter.

from Cruise: NBP0104 Nitrate, nitrite, phosphate, ammonia, and silica were measured from every niskin bottle tripped from all hydrocasts on this cruise. All concentrations are reported in micromoles per liter.

from Cruise: NBP0202 Nitrate, nitrite, phosphate, ammonia, and silica were measured from every niskin bottle tripped from all hydrocasts on this cruise. All concentrations are reported in micromoles per liter.

from Cruise: NBP0204 Nitrate, nitrite, phosphate, ammonia, and silica were measured from every niskin bottle tripped from all hydrocasts on this cruise. All concentrations are reported in micromoles per liter.</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;Analytical methods used for silica, phosphate, nitrite, and nitrate follow the recommendations of Gordon et al. (1993) for the WOCE WHP project.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The analytical system we employ is a five-channel Technicon Autoanalyzer II upgraded with new heating baths, proportional pumps, colorimeters, improved optics, and an analog to digital conversion system (New Analyzer Program v. 2.40 by Labtronics, Inc.) This Technicon is designed for shipboard as well as laboratory use.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Silica is determined by forming the heteropoly acid of dissolved orthosilicic acid and ammonium molybdate, reducing it with stannous chloride, and then measuring its optical transmittance.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Phosphate is determined by creating the phosphomolybdate heteropoly acid in much the same way as with the silica method. However, its reducing agent is dihydrazine sulfate, after which its transmittance is also measured. A heating bath is required to maximize the color yield.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Nitrite is determined essentially by the Bendschneider and Robinson (1952) technique in which nitrite is reacted with sulfanilamide (SAN) to form a diazotized derivative that is then reacted with a substituted ethylenediamine compound (NED) to form a rose pink azo dye which is measured colorimetrically.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Nitrate is determined by difference after a separate aliquot of a sample is passed through a Cd reduction column to convert its nitrate to nitrite, followed by the measurement of the &amp;quot;augmented&amp;quot; nitrite concentration using the same method as in the nitrite analysis.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;In the analytical ammonia method, ammonium reacts with alkaline phenol and hypochlorite to form indophenolblue. Sodium nitroferricyanide intensifies the blue color formed, which is then measured in a colorimeter of our nutrient-analyzer. Precipitation of calcium and magnesium hydroxides is eliminated by the addition of sodium citrate complexing reagent. A heating bath is required. Our version of this technique is based on modifications of published methods such as the article by F. Koroleff in Grasshoff (1976). These modifications were made at Alpkem (now Astoria-Pacific International, Inc.) and at L.Gordon's nutrient laboratory at Oregon State University.&amp;lt;/p&amp;gt;

from Cruise: NBP0103 &lt;p&gt;Analytical methods used for silica, phosphate, nitrite, and nitrate follow
the recommendations of Gordon et al. (1993) for the WOCE WHP project.  &lt;/p&gt;

&lt;p&gt;The analytical system we employ is a five-channel Technicon Autoanalyzer II 
upgraded with new heating baths, proportional pumps, colorimeters, improved
optics, and an analog to digital conversion system (New Analyzer 
Program v. 2.40 by Labtronics, Inc.)  This Technicon is designed for 
shipboard as well as laboratory use. &lt;/p&gt; 


&lt;p&gt;Silica is determined by forming 
the heteropoly acid of dissolved orthosilicic acid and ammonium molybdate, 
reducing it with stannous chloride, and then measuring its optical 
transmittance.&lt;/p&gt;  

&lt;p&gt;Phosphate is determined by creating the phosphomolybdate 
heteropoly acid in much the same way as with the silica method.  However, its
reducing agent is dihydrazine sulfate, after which its transmittance is also 
measured.  A heating bath is required to maximize the color yield. &lt;/p&gt; 

&lt;p&gt;Nitrite is determined essentially by the Bendschneider and Robinson (1952) 
technique in which nitrite is reacted with sulfanilamide (SAN) to form a 
diazotized derivative that is then reacted with a substituted 
ethylenediamine compound (NED) to form a rose pink azo dye which is measured 
colorimetrically. &lt;/p&gt;

&lt;p&gt;Nitrate is determined by difference after a separate 
aliquot of a sample is passed through a Cd reduction column to convert its 
nitrate to nitrite, followed by the measurement of the &quot;augmented&quot; nitrite
concentration using the same method as in the nitrite analysis. &lt;/p&gt;

&lt;p&gt;In the analytical ammonia method, ammonium reacts with alkaline phenol and 
hypochlorite to form indophenolblue. Sodium nitroferricyanide intensifies the
blue color formed, which is then measured in a colorimeter of our 
nutrient-analyzer.  Precipitation of calcium and magnesium hydroxides is 
eliminated by the addition of sodium citrate complexing reagent.  A heating 
bath is required.  Our version of this technique is based on 
modifications of published methods such as the article by F. Koroleff in 
Grasshoff (1976).  These modifications were made at Alpkem (now 
Astoria-Pacific International, Inc.) and at L.Gordon's nutrient laboratory at 
Oregon State University.&lt;/p&gt;

from Cruise: NBP0104 &lt;p&gt;Analytical methods used for silica, phosphate, nitrite, and nitrate follow
the recommendations of Gordon et al. (1993) for the WOCE WHP project.  &lt;/p&gt;

&lt;p&gt;The analytical system we employ is a five-channel Technicon Autoanalyzer II 
upgraded with new heating baths, proportional pumps, colorimeters, improved
optics, and an analog to digital conversion system (New Analyzer 
Program v. 2.40 by Labtronics, Inc.)  This Technicon is designed for 
shipboard as well as laboratory use. &lt;/p&gt; 


&lt;p&gt;Silica is determined by forming 
the heteropoly acid of dissolved orthosilicic acid and ammonium molybdate, 
reducing it with stannous chloride, and then measuring its optical 
transmittance.&lt;/p&gt;  

&lt;p&gt;Phosphate is determined by creating the phosphomolybdate 
heteropoly acid in much the same way as with the silica method.  However, its
reducing agent is dihydrazine sulfate, after which its transmittance is also 
measured.  A heating bath is required to maximize the color yield. &lt;/p&gt; 

&lt;p&gt;Nitrite is determined essentially by the Bendschneider and Robinson (1952) 
technique in which nitrite is reacted with sulfanilamide (SAN) to form a 
diazotized derivative that is then reacted with a substituted 
ethylenediamine compound (NED) to form a rose pink azo dye which is measured 
colorimetrically. &lt;/p&gt;

&lt;p&gt;Nitrate is determined by difference after a separate 
aliquot of a sample is passed through a Cd reduction column to convert its 
nitrate to nitrite, followed by the measurement of the &quot;augmented&quot; nitrite
concentration using the same method as in the nitrite analysis. &lt;/p&gt;

&lt;p&gt;In the analytical ammonia method, ammonium reacts with alkaline phenol and 
hypochlorite to form indophenolblue. Sodium nitroferricyanide intensifies the
blue color formed, which is then measured in a colorimeter of our 
nutrient-analyzer.  Precipitation of calcium and magnesium hydroxides is 
eliminated by the addition of sodium citrate complexing reagent.  A heating 
bath is required.  Our version of this technique is based on 
modifications of published methods such as the article by F. Koroleff in 
Grasshoff (1976).  These modifications were made at Alpkem (now 
Astoria-Pacific International, Inc.) and at L.Gordon's nutrient laboratory at 
Oregon State University.&lt;/p&gt;

from Cruise: NBP0202 &lt;p&gt;Analytical methods used for silica, phosphate, nitrite, and nitrate follow
the recommendations of Gordon et al. (1993) for the WOCE WHP project.  &lt;/p&gt;

&lt;p&gt;The analytical system we employ is a five-channel Technicon Autoanalyzer II 
upgraded with new heating baths, proportional pumps, colorimeters, improved
optics, and an analog to digital conversion system (New Analyzer 
Program v. 2.40 by Labtronics, Inc.)  This Technicon is designed for 
shipboard as well as laboratory use. &lt;/p&gt; 


&lt;p&gt;Silica is determined by forming 
the heteropoly acid of dissolved orthosilicic acid and ammonium molybdate, 
reducing it with stannous chloride, and then measuring its optical 
transmittance.&lt;/p&gt;  

&lt;p&gt;Phosphate is determined by creating the phosphomolybdate 
heteropoly acid in much the same way as with the silica method.  However, its
reducing agent is dihydrazine sulfate, after which its transmittance is also 
measured.  A heating bath is required to maximize the color yield. &lt;/p&gt; 

&lt;p&gt;Nitrite is determined essentially by the Bendschneider and Robinson (1952) 
technique in which nitrite is reacted with sulfanilamide (SAN) to form a 
diazotized derivative that is then reacted with a substituted 
ethylenediamine compound (NED) to form a rose pink azo dye which is measured 
colorimetrically. &lt;/p&gt;

&lt;p&gt;Nitrate is determined by difference after a separate 
aliquot of a sample is passed through a Cd reduction column to convert its 
nitrate to nitrite, followed by the measurement of the &quot;augmented&quot; nitrite
concentration using the same method as in the nitrite analysis. &lt;/p&gt;

&lt;p&gt;In the analytical ammonia method, ammonium reacts with alkaline phenol and 
hypochlorite to form indophenolblue. Sodium nitroferricyanide intensifies the
blue color formed, which is then measured in a colorimeter of our 
nutrient-analyzer.  Precipitation of calcium and magnesium hydroxides is 
eliminated by the addition of sodium citrate complexing reagent.  A heating 
bath is required.  Our version of this technique is based on 
modifications of published methods such as the article by F. Koroleff in 
Grasshoff (1976).  These modifications were made at Alpkem (now 
Astoria-Pacific International, Inc.) and at L.Gordon's nutrient laboratory at 
Oregon State University.&lt;/p&gt;

from Cruise: NBP0204 &lt;p&gt;Analytical methods used for silica, phosphate, nitrite, and nitrate follow
the recommendations of Gordon et al. (1993) for the WOCE WHP project.  &lt;/p&gt;

&lt;p&gt;The analytical system we employ is a five-channel Technicon Autoanalyzer II 
upgraded with new heating baths, proportional pumps, colorimeters, improved
optics, and an analog to digital conversion system (New Analyzer 
Program v. 2.40 by Labtronics, Inc.)  This Technicon is designed for 
shipboard as well as laboratory use. &lt;/p&gt; 


&lt;p&gt;Silica is determined by forming 
the heteropoly acid of dissolved orthosilicic acid and ammonium molybdate, 
reducing it with stannous chloride, and then measuring its optical 
transmittance.&lt;/p&gt;  

&lt;p&gt;Phosphate is determined by creating the phosphomolybdate 
heteropoly acid in much the same way as with the silica method.  However, its
reducing agent is dihydrazine sulfate, after which its transmittance is also 
measured.  A heating bath is required to maximize the color yield. &lt;/p&gt; 

&lt;p&gt;Nitrite is determined essentially by the Bendschneider and Robinson (1952) 
technique in which nitrite is reacted with sulfanilamide (SAN) to form a 
diazotized derivative that is then reacted with a substituted 
ethylenediamine compound (NED) to form a rose pink azo dye which is measured 
colorimetrically. &lt;/p&gt;

&lt;p&gt;Nitrate is determined by difference after a separate 
aliquot of a sample is passed through a Cd reduction column to convert its 
nitrate to nitrite, followed by the measurement of the &quot;augmented&quot; nitrite
concentration using the same method as in the nitrite analysis. &lt;/p&gt;

&lt;p&gt;In the analytical ammonia method, ammonium reacts with alkaline phenol and 
hypochlorite to form indophenolblue. Sodium nitroferricyanide intensifies the
blue color formed, which is then measured in a colorimeter of our 
nutrient-analyzer.  Precipitation of calcium and magnesium hydroxides is 
eliminated by the addition of sodium citrate complexing reagent.  A heating 
bath is required.  Our version of this technique is based on 
modifications of published methods such as the article by F. Koroleff in 
Grasshoff (1976).  These modifications were made at Alpkem (now 
Astoria-Pacific International, Inc.) and at L.Gordon's nutrient laboratory at 
Oregon State University.&lt;/p&gt;</gco:CharacterString>
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