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            <gco:CharacterString>Cite this dataset as: Monosson, E. (2006) Comparison of Environmental Contaminants on Georges Bank and Stellwagon Bank: Metals from F/V Skimmer NEC-EM2001-1 in the Stellwagen Bank, Georges Bank, Wilkinson Basin from 2002-2004 (NEC-CoopRes project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version final) Version Date 2006-01-01 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/2787 [access date]</gco:CharacterString>
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        <gco:CharacterString>Comparison of Environmental Contaminants on Georges Bank and Stellwagon Bank: Metals Dataset Description: &amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Comparison of Environmental Contaminants on Georges Bank and Stellwagon Bank - Metals&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;Project Leader: &amp;lt;/strong&amp;gt;&amp;lt;em&amp;gt;Emily Monosson,&amp;lt;/em&amp;gt; Mt. Holyoke College&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;Additional Participants:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;em&amp;gt;David Lincoln, &amp;lt;/em&amp;gt;Commonwealth Corporation&amp;lt;br /&amp;gt;
&amp;lt;em&amp;gt;Angela Sanfilippo, &amp;lt;/em&amp;gt;Gloucester Fishermen's Wives Association&amp;lt;br /&amp;gt;
and over 14 commerical fisherman&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;quot;This project investigated the potential for contaminant-induced effects on reproduction and development in both nearshore and offshore cod. Heavy metals, polychlorinated biphenyls (PCBs), and oganochlorine pesticides (including DDTs) were measured in cod livers and gonads and sediments from Stellwagen Bank, Georges Bank, and Wilkinson Basin. In general, concentrations of most contaminants were found to be near or below detection limits in cod gonads. Several contaminants were detected in the cod liver including PCBs and DDTs. However, concentrations from Georges Bank were drastically lower than previously published data and below concentrations linked with reproductive or developmental toxicity in fish. Analysis of heavy metals suggests that the concentrations of metals measured in this study are within range of those previously reported in cod except for cadmium. The vast majority of polycyclic aromatic hydrocarbons (PAHs) and metals detected in sediments were below NOAA's Threshold Effects Levels and chlorinated pesticides were below detection limits in the sediments. No one chemical was consistently detected at concentrations suspected of causing adverse effects in cod or their offspring. It would appear that levels of exposure to the chemical contaminants measured are unlikely to have had a considerable impact on the nearshore or offshore cod fishery.&amp;quot;&amp;lt;em&amp;gt;extracted from: Summary of Completed Cooperative Research Projects Funded by the Northeast Consortium, January 2006&amp;lt;/em&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Data Elements&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Parameter Names and Descriptions:&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Female fish were targeted where a sufficient number of females could be collected, otherwise males were included in the collection. All data on fish tissues are reported as fresh weight or wet weight.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;For more detailed information see: &amp;lt;/strong&amp;gt;&amp;lt;a href=&amp;quot;http://northeastconsortium.org/ProjectFileDownload.pm?report_id=267&amp;amp;amp;table=project_report&amp;quot;&amp;gt;Final Report&amp;lt;/a&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Questions concerning these data should be directed to:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Emily Monosson&amp;lt;br /&amp;gt;
Mt. Holoyoke College&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Phone: 413 367-0052&amp;lt;br /&amp;gt;
E-mail: emonosson@forwild.umass.edu&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;em&amp;gt;revised Sept 01, 2006; gfh &amp;lt;/em&amp;gt;&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;The heavy metals As, Cu, Se, Zn, were detected in most fish at all sites, while Hg, Cd, and Ag were detected primarily in cod from the three GB sites. Several metals including Al, Cr, Mn, Tl, and V were detected in only a few fish across all sites or not at all. These metals were dropped from the analysis. Statistical analysis of the four metals detected in all sites reveals a trend in which the concentrations are consistently lower in the SB cod compared to the GB cod. This is interesting, since the sediment trends suggest slightly higher concentrations of metals in SB and WB, compared to GB, although as noted earlier, the sediment data are limited to only two samples and thus can only be considered as a very limited data set. Comparing our results for metals to those of Hellou et al., (1992) who measured trace metals in cod livers collected off the coast of Newfoundland, the mean concentration of Cd in fish from GB was roughly 8-10 fold higher than those concentrations reported by Hellou and Cu is up to 3-fold higher. We were unable to compare our data with concentrations recently reported by the USGS National Water Quality Assessment Program, because they report concentrations in fillet rather than in liver (USGS 2002). Interestingly, the concentrations of Cd in GB cod livers from our study were within the range of concentrations found in fresh water fish (measured as whole-bodies) collected from a lake contaminated by an electroplating plant, and are comparable to some of the higher mean concentrations of cadmium (which ranged from 0.1-19.6) in NOAA’s 1987 Status and Trends report (NOAA 1987). The Cd concentrations measured in the GB cod are also within range of cadmium concentrations reported in tilefish livers from several deep sea canyons located in the Middle Atlantic Bight, including one location (Lydonia Canyon) on Georges Bank (Steimle et al., 1996; Steimle et al., 1990). Cadmium and copper are known reproductive and developmental toxicants in fish (reviewed in Sorensen 1991; Jarvinen and Ankley 1999). However, the potential for adverse reproductive or developmental effects in cod caused by Cd at the concentrations measured in this study remain unclear, because the majority of toxicity data relate either exposure concentrations to toxicity, rather than tissue concentrations, or were designed to evaluate life stages and endpoints other than those of interest in this current study. In the gonads, the only metals consistently detected were Fe, Na, Se, K and Zn. Both selenium and Zn were higher in gonads compared to livers, which is in agreement with an earlier study by Hellou et al. (1992), who noted their importance for the normal functioning of certain enzymes.&amp;lt;/p&amp;gt;</gco:CharacterString>
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		    <gco:CharacterString>For questions regarding this resource, please contact BCO-DMO via the email address provided.</gco:CharacterString>
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              <gco:Real>51141</gco:Real>
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              <gmd:linkage><gmd:URL>https://datadocs.bco-dmo.org/file/yppz4gxh287RRk/contaminants_M.csv</gmd:URL></gmd:linkage>              <gmd:name>
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                  <gco:CharacterString>Primary data file for dataset ID 2787</gco:CharacterString>
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        <gmd:MD_DigitalTransferOptions>
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                <gmd:URL>https://osprey.bco-dmo.org/dataset/2787/data/download</gmd:URL>
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                <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
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          <gmd:processStep xlink:title="Methods and Sampling">
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              <gmd:description>
                <gco:CharacterString>&amp;lt;p&amp;gt;The heavy metals As, Cu, Se, Zn, were detected in most fish at all sites, while Hg, Cd, and Ag were detected primarily in cod from the three GB sites. Several metals including Al, Cr, Mn, Tl, and V were detected in only a few fish across all sites or not at all. These metals were dropped from the analysis. Statistical analysis of the four metals detected in all sites reveals a trend in which the concentrations are consistently lower in the SB cod compared to the GB cod. This is interesting, since the sediment trends suggest slightly higher concentrations of metals in SB and WB, compared to GB, although as noted earlier, the sediment data are limited to only two samples and thus can only be considered as a very limited data set. Comparing our results for metals to those of Hellou et al., (1992) who measured trace metals in cod livers collected off the coast of Newfoundland, the mean concentration of Cd in fish from GB was roughly 8-10 fold higher than those concentrations reported by Hellou and Cu is up to 3-fold higher. We were unable to compare our data with concentrations recently reported by the USGS National Water Quality Assessment Program, because they report concentrations in fillet rather than in liver (USGS 2002). Interestingly, the concentrations of Cd in GB cod livers from our study were within the range of concentrations found in fresh water fish (measured as whole-bodies) collected from a lake contaminated by an electroplating plant, and are comparable to some of the higher mean concentrations of cadmium (which ranged from 0.1-19.6) in NOAA’s 1987 Status and Trends report (NOAA 1987). The Cd concentrations measured in the GB cod are also within range of cadmium concentrations reported in tilefish livers from several deep sea canyons located in the Middle Atlantic Bight, including one location (Lydonia Canyon) on Georges Bank (Steimle et al., 1996; Steimle et al., 1990). Cadmium and copper are known reproductive and developmental toxicants in fish (reviewed in Sorensen 1991; Jarvinen and Ankley 1999). However, the potential for adverse reproductive or developmental effects in cod caused by Cd at the concentrations measured in this study remain unclear, because the majority of toxicity data relate either exposure concentrations to toxicity, rather than tissue concentrations, or were designed to evaluate life stages and endpoints other than those of interest in this current study. In the gonads, the only metals consistently detected were Fe, Na, Se, K and Zn. Both selenium and Zn were higher in gonads compared to livers, which is in agreement with an earlier study by Hellou et al. (1992), who noted their importance for the normal functioning of certain enzymes.&amp;lt;/p&amp;gt;

from Cruise: NEC-EM2001-1 The heavy metals As, Cu, Se, Zn, were detected in most fish at all sites, while
Hg, Cd, and Ag were detected primarily in cod from the three GB sites. Several metals
including Al, Cr, Mn, Tl, and V were detected in only a few fish across all sites or not at
all. These metals were dropped from the analysis. Statistical analysis of the four metals
detected in all sites reveals a trend in which the concentrations are consistently lower in
the SB cod compared to the GB cod. This is interesting, since the sediment trends suggest
slightly higher concentrations of metals in SB and WB, compared to GB, although as
noted earlier, the sediment data are limited to only two samples and thus can only be
considered as a very limited data set. Comparing our results for metals to those of Hellou
et al., (1992) who measured trace metals in cod livers collected off the coast of
Newfoundland, the mean concentration of Cd in fish from GB was roughly 8-10 fold
higher than those concentrations reported by Hellou and Cu is up to 3-fold
higher. We were unable to compare our data with concentrations recently reported by the
USGS National Water Quality Assessment Program, because they report concentrations
in fillet rather than in liver (USGS 2002).
Interestingly, the concentrations of Cd in GB cod livers from our study were within the
range of concentrations found in fresh water fish (measured as whole-bodies) collected
from a lake contaminated by an electroplating plant, and are comparable to some of the
higher mean concentrations of cadmium (which ranged from 0.1-19.6) in NOAA’s 1987
Status and Trends report (NOAA 1987). The Cd concentrations measured in the GB cod
are also within range of cadmium concentrations reported in tilefish livers from several
deep sea canyons located in the Middle Atlantic Bight, including one location (Lydonia
Canyon) on Georges Bank (Steimle et al., 1996; Steimle et al., 1990).
Cadmium and copper are known reproductive and developmental toxicants in fish
(reviewed in Sorensen 1991; Jarvinen and Ankley 1999). However, the potential for
adverse reproductive or developmental effects in cod caused by Cd at the concentrations
measured in this study remain unclear, because the majority of toxicity data relate either
exposure concentrations to toxicity, rather than tissue concentrations, or were designed to
evaluate life stages and endpoints other than those of interest in this current study.
In the gonads, the only metals consistently detected were Fe, Na, Se, K and Zn. Both
selenium and Zn were higher in gonads compared to livers, which is in agreement with an
earlier study by Hellou et al. (1992), who noted their importance for the normal
functioning of certain enzymes.</gco:CharacterString>
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                      <gmd:date gco:nilReason="unknown"/>
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          <gmd:processStep xlink:title="Data Processing Description">
            <gmd:LI_ProcessStep>
              <gmd:description>
                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;quot;This project investigated the potential for contaminant-induced effects on reproduction and development in both nearshore and offshore cod. Heavy metals, polychlorinated biphenyls (PCBs), and oganochlorine pesticides (including DDTs) were measured in cod livers and gonads and sediments from Stellwagen Bank, Georges Bank, and Wilkinson Basin. In general, concentrations of most contaminants were found to be near or below detection limits in cod gonads. Several contaminants were detected in the cod liver including PCBs and DDTs. However, concentrations from Georges Bank were drastically lower than previously published data and below concentrations linked with reproductive or developmental toxicity in fish. Analysis of heavy metals suggests that the concentrations of metals measured in this study are within range of those previously reported in cod except for cadmium. The vast majority of polycyclic aromatic hydrocarbons (PAHs) and metals detected in sediments were below NOAA’s Threshold Effects Levels and chlorinated pesticides were below detection limits in the sediments. No one chemical was consistently detected at concentrations suspected of causing adverse effects in cod or their offspring. It would appear that levels of exposure to the chemical contaminants measured are unlikely to have had a considerable impact on the nearshore or offshore cod fishery.&amp;quot;&amp;lt;/p&amp;gt;

from Cruise: NEC-EM2001-1 &quot;This project investigated the potential for contaminant-induced effects on reproduction and development in both nearshore and offshore cod. Heavy metals, polychlorinated biphenyls (PCBs), and oganochlorine pesticides (including DDTs) were measured in cod livers and gonads and sediments from Stellwagen Bank, Georges Bank, and Wilkinson Basin. In general, concentrations of most contaminants were found to be near or below detection limits in cod gonads. Several contaminants were detected in the cod liver including PCBs and DDTs. However, concentrations from Georges Bank were drastically lower than previously published data and below concentrations linked with reproductive or developmental toxicity in fish. Analysis of heavy metals suggests that the concentrations of metals measured in this study are within range of those previously reported in cod except for cadmium. The vast majority of polycyclic aromatic hydrocarbons (PAHs) and metals detected in sediments were below NOAA’s Threshold Effects Levels and chlorinated pesticides were below detection limits in the sediments. No one chemical was consistently detected at concentrations suspected of causing adverse effects in cod or their offspring. It would appear that levels of exposure to the chemical contaminants measured are unlikely to have had a considerable impact on the nearshore or offshore cod fishery.&quot;</gco:CharacterString>
              </gmd:description>
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                        <gco:CharacterString>Specified by the Principal Investigator(s)</gco:CharacterString>
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                      <gmd:date gco:nilReason="unknown"/>
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        </gmd:LI_Lineage>
      </gmd:lineage>
   </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded" codeSpace="009">asNeeded</gmd:MD_MaintenanceFrequencyCode>
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        <gco:CharacterString>7.x-1.1</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
  <gmd:organisationName>
    <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/affiliation/191.rdf" xlink:actuate="onRequest">Biological and Chemical Oceanography Data Management Office (BCO-DMO)</gmx:Anchor>
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  <gmd:contactInfo>
    <gmd:CI_Contact>
		  <gmd:phone>
		    <gmd:CI_Telephone>
				  <gmd:voice>
				    <gco:CharacterString>Unavailable</gco:CharacterString>
				  </gmd:voice>
				  <gmd:facsimile>
				    <gco:CharacterString>508-289-2009</gco:CharacterString>
				  </gmd:facsimile>
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		  </gmd:phone>
		  <gmd:address>
		    <gmd:CI_Address>
				  <gmd:deliveryPoint>
				    <gco:CharacterString>WHOI MS#36</gco:CharacterString>
				  </gmd:deliveryPoint>
				  <gmd:city>
				    <gco:CharacterString>Woods Hole</gco:CharacterString>
				  </gmd:city>
				  <gmd:administrativeArea>
				    <gco:CharacterString>MA</gco:CharacterString>
				  </gmd:administrativeArea>
				  <gmd:postalCode>
				    <gco:CharacterString>02543</gco:CharacterString>
				  </gmd:postalCode>
				  <gmd:country>
				    <gco:CharacterString>USA</gco:CharacterString>
				  </gmd:country>
				  <gmd:electronicMailAddress>
				    <gco:CharacterString>info@bco-dmo.org</gco:CharacterString>
				  </gmd:electronicMailAddress>
		    </gmd:CI_Address>
		  </gmd:address>
      <gmd:onlineResource>
          <gmd:CI_OnlineResource>
            <gmd:linkage>
              <gmd:URL>http://www.bco-dmo.org</gmd:URL>
            </gmd:linkage>
          </gmd:CI_OnlineResource>
        </gmd:onlineResource>
		  <gmd:hoursOfService>
        <gco:CharacterString>Monday - Friday 8:00am - 5:00pm</gco:CharacterString>
      </gmd:hoursOfService>
		  <gmd:contactInstructions>
		    <gco:CharacterString>For questions regarding this resource, please contact BCO-DMO via the email address provided.</gco:CharacterString>
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    <gmd:CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="pointOfContact"  codeSpace="007">pointOfContact</gmd:CI_RoleCode>
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</gmd:CI_ResponsibleParty>
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  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation>
    <gmi:instrument gco:nilReason="unknown"/><gmi:operation>
          <gmi:MI_Operation>
            <gmi:description>
              <gco:CharacterString>Cruise: NEC-EM2001-1</gco:CharacterString>
            </gmi:description>
            <gmi:identifier>
              <gmd:MD_Identifier>
                <gmd:code>
                  <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/deployment/57761.rdf" xlink:title="Cruise" xlink:actuate="onRequest">NEC-EM2001-1</gmx:Anchor>
                </gmd:code>
              </gmd:MD_Identifier>
            </gmi:identifier>
            <gmi:status>
              <gmd:MD_ProgressCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_ProgressCode" codeListValue="completed"/>
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            <gmi:type>
              <gmi:MI_OperationTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MI_OperationTypeCode" codeListValue="real"/>
            </gmi:type>
            <gmi:parentOperation gco:nilReason="inapplicable"/>
            <gmi:platform>
  <gmi:MI_Platform>
    <gmi:identifier>
      <gmd:MD_Identifier>
        <gmd:code>
          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54050.rdf"
           xlink:actuate="onRequest">F/V Skimmer</gmx:Anchor>
        </gmd:code>
      </gmd:MD_Identifier>
    </gmi:identifier>
    <gmi:description>
      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54050.rdf" xlink:title="F/V Skimmer" xlink:actuate="onRequest">vessel</gmx:Anchor>
    </gmi:description>
    <gmi:instrument gco:nilReason="unknown"/>
  </gmi:MI_Platform>
</gmi:platform>
            <gmi:plan>
              <gmi:MI_Plan>
                <gmi:status>
                  <gmd:MD_ProgressCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode" codeListValue="completed"/>
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                <gmi:citation>
                  <gmd:CI_Citation>
                    <gmd:title>
                      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/deployment/57761.rdf" xlink:title="Cruise" xlink:actuate="onRequest">NEC-EM2001-1</gmx:Anchor>
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                    <gmd:date gco:nilReason="unknown"/>
                    <gmd:citedResponsibleParty>
                      <gmd:CI_ResponsibleParty>
                      <gmd:individualName>
                          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/person/50902.rdf" xlink:actuate="onRequest">Emily Monosson</gmx:Anchor>
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                        <gmd:CI_Contact>
                          <gmd:onlineResource>
                            <gmd:CI_OnlineResource>
                              <gmd:linkage>
                                <gmd:URL>http://northeastconsortium.org/ProjectFileDownload.pm?report_id=267&amp;table=project_report</gmd:URL>
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                              <gmd:description>
                                <gco:CharacterString>Report describing NEC-EM2001-1</gco:CharacterString>
                              </gmd:description>
                            </gmd:CI_OnlineResource>
                          </gmd:onlineResource>
                        </gmd:CI_Contact>
                      </gmd:contactInfo>
                      <gmd:role>
                        <gmd:CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="principalInvestigator"/>
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                   </gmd:CI_Citation>
                </gmi:citation>
              </gmi:MI_Plan>
            </gmi:plan>
            </gmi:MI_Operation>
      </gmi:operation><gmi:platform>
  <gmi:MI_Platform>
    <gmi:identifier>
      <gmd:MD_Identifier>
        <gmd:code>
          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54050.rdf"
           xlink:actuate="onRequest">F/V Skimmer</gmx:Anchor>
        </gmd:code>
      </gmd:MD_Identifier>
    </gmi:identifier>
    <gmi:description>
      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54050.rdf" xlink:title="F/V Skimmer" xlink:actuate="onRequest">vessel</gmx:Anchor>
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    <gmi:instrument gco:nilReason="unknown"/>
  </gmi:MI_Platform>
</gmi:platform>
          </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>
