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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/3060.rdf" xlink:actuate="onRequest">Bio-optical spar data from R/V Oceanus OC404-01, OC404-04, OC415-01, OC415-03 cruises in the Sargasso Sea, 2004-2005 (EDDIES project)</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Siegel, D. (2008) Bio-optical spar data from R/V Oceanus OC404-01, OC404-04, OC415-01, OC415-03 cruises in the Sargasso Sea, 2004-2005 (EDDIES project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 12 March 2008) Version Date 2008-03-12 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/3060 [access date]</gco:CharacterString>
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        <gco:CharacterString>Bio-optical spar data Dataset Description: &amp;lt;p&amp;gt;Bio-optical spar buoy data collected from the UCSB SPAR buoy configured with ECO-FLNTU Chlorophyll a and Optical Backscatter sensors. Data from both sensor types (chl a and optical backscatter) were compared with data from other sensors measuring similar data and the offsets were determined to be unacceptably large, combined with too short a sampling interval. Therefore, the data will not be published.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;A schematic of the UCSB SPAR buoy configuration (as deployed during OC404-1 cruise) is available as a &amp;lt;a href=&amp;quot;http://ocb.whoi.edu/EDDIES/PI-NOTES/orig_data/UCSB_SPAR_buoy/UCSB_Buoy1.pdf&amp;quot;&amp;gt;PDF file&amp;lt;/a&amp;gt;.&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;Please refer to descriptions for each cruise (deployment). &amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Calibration of instruments:&amp;lt;/strong&amp;gt; &amp;lt;br /&amp;gt;
SBE-39s and SBE-37 were calibrated by SeaBird. &amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;ECO-FLNTU Chl a and Optical Backscatter sensors were compared to the Oceanus CTD fluorometer during 
comparison casts for each cruise. &amp;lt;/p&amp;gt;</gco:CharacterString>
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                  <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/project/2048.rdf" xlink:title="Project" xlink:actuate="onRequest">Eddies Dynamics, Mixing, Export, and Species composition</gmx:Anchor>
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                            <gco:CharacterString>&lt;p&gt;The original title of this project from the NSF award is: Collaborative Research: Impacts of Eddies and Mixing on Plankton Community Structure and Biogeochemical Cycling in the Sargasso Sea&quot;.&lt;/p&gt;
&lt;p&gt;Prior results have documented eddy-driven transport of nutrients into the euphotic zone and the associated accumulation of chlorophyll. However, several key aspects of mesoscale upwelling events remain unresolved by the extant database, including: (1) phytoplankton physiological response, (2) changes in community structure, (3) impact on export out of the euphotic zone, (4) rates of mixing between the surface mixed layer and the base of the euphotic zone, and (5) implications for biogeochemistry and differential cycling of carbon and associated bioactive elements. This leads to the following hypotheses concerning the complex, non-linear biological regulation of elemental cycling in the ocean:&lt;/p&gt;
&lt;p&gt;H1: Eddy-induced upwelling, in combination with diapycnal mixing in the upper ocean, introduces new nutrients into the euphotic zone.&lt;/p&gt;
&lt;p&gt;H2: The increase in inorganic nutrients stimulates a physiological response within the phytoplankton community.&lt;/p&gt;
&lt;p&gt;H3: Differing physiological responses of the various species bring about a shift in community structure.&lt;/p&gt;
&lt;p&gt;H4: Changes in community structure lead to increases in export from, and changes in biogeochemical cycling within, the upper ocean.&lt;/p&gt;
&lt;h4&gt;Publications&lt;/h4&gt;
&lt;p&gt;Andrews, J.E., Hartin, C., and Buesseler, K.O.. &quot;7Be Analyses in Seawater by Low Background Gamma-Spectroscopy.,&quot; Journal of Radioanalytical and Nuclear Chemistry, v.277, 2008, p. 253.&lt;/p&gt;
&lt;p&gt;Andrews, J.E., Hartin, C., Buesseler, K.O.. &quot;7Be Analyses in Seawater by Low Background Gamma-Spectroscopy,&quot; Journal of Radioanalytical and Nuclear Chemistry, v.277, 2008, p. 253.&lt;/p&gt;
&lt;p&gt;Benitez-Nelson, C.R. and McGillicuddy, D.J.. &quot;Mesoscale Physical-Biological-Biogeochemical Linkages in the Open Ocean: An Introduction to the Results of the E-Flux and EDDIES Programs.,&quot; Deep Sea Research II, v.55, 2008, p. 1133.&lt;/p&gt;
&lt;p&gt;Benitez-Nelson, C.R. and McGillicuddy, D.J.. &quot;Mesoscale Physical-Biological-Biogeochemical Linkages in the Open Ocean: An Introduction to the Results of the E-Flux and EDDIES Programs,&quot; Deep-Sea Research II, v.55, 2008, p. 1133.&lt;/p&gt;
&lt;p&gt;Bibby, T.S., Gorbunov, M.Y., Wyman, K.W., Falkowski, P.G.. &quot;Photosynthetic community responses to upwelling in mesoscale eddies in the subtropical North Atlantic and Pacific Oceans,&quot; Deep-Sea Research Part II: Topical Studies in Oceanography, v.55, 2008, p. 1310.&lt;/p&gt;
&lt;p&gt;Buesseler, K.O., Lamborg, C., Cai, P., Escoube, R., Johnson, R., Pike, S., Masque, P., McGillicuddy, D.J., Verdeny, E.. &quot;Particle Fluxes Associated with Mesoscale Eddies in the Sargasso Sea,&quot; Deep Sea Research II, v.55, 2008, p. 1426.&lt;/p&gt;
&lt;p&gt;Carlson, C.A., del Giorgio, P., Herdl, G.. &quot;Microbes and the dissipation of energy and respiration: From cells to ecosystems,&quot; Oceanography, v.20, 2007, p. 89.&lt;/p&gt;
&lt;p&gt;Davis, C.S., and McGillicuddy, D.J.. &quot;Transatlantic Abundance of the N2-Fixing Colonial Cyanobacterium Trichodesmium,&quot; Science, v.312, 2006, p. 1517.&lt;/p&gt;
&lt;p&gt;Ewart, C.S., Meyers, M.K., Wallner, E., McGillicuddy, D.J., Carlson, C.A.. &quot;Microbial Dynamics in Cyclonic and Anticyclonic Mode-Water Eddies in the Northwestern Sargasso Sea,&quot; Deep Sea Research II, v.55, 2008, p. 1334.&lt;/p&gt;
&lt;p&gt;Ewart, C.S., Meyers, M.K., Wallner, E., McGillicuddy, D.J., Carlson, C.A.. &quot;Microbial Dynamics in Cyclonic and Anticyclonic Mode-Water Eddies in the Northwestern Sargasso Sea,&quot; Deep-Sea Research II, v.55, 2008, p. 1334.&lt;/p&gt;
&lt;p&gt;Goldthwait, S.A. and Steinberg, D.K.. &quot;Elevated biomass of mesozooplankton and enhanced fecal pellet flux in cyclonic and mode-water eddies in the Sargasso Sea,&quot; Deep-Sea Research Part II: Topical Studies in Oceanography, v.55, 2008, p. 1360.&lt;/p&gt;
&lt;p&gt;Greenan, B.J.W.. &quot;Shear and Richardson number in a mode-water eddy,&quot; Deep-Sea Research Part II: Topical Studies in Oceanography, v.55, 2008, p. 1161.&lt;/p&gt;
&lt;p&gt;Jenkins, W.J., McGillicuddy, D.J., and Lott III, D.E.. &quot;The Distributions of, and Relationship Between 3 He and Nitrate in Eddies,&quot; Deep Sea Research II, v.55, 2008, p. 1389.&lt;/p&gt;
&lt;p&gt;Jenkins, W.J., McGillicuddy, D.J., Lott III, D.E.. &quot;The Distributions of, and Relationship Between 3 He and Nitrate in Eddies,&quot; Deep-Sea Research II, v.55, 2008, p. 1389.&lt;/p&gt;
&lt;p&gt;Ledwell, J.R., McGillicuddy, D.J., and Anderson, L.A.. &quot;Nutrient Flux into an Intense Deep Chlorophyll Layer in a Mode-water Eddy.,&quot; Deep Sea Research II, v.55, 2008, p. 1139.&lt;/p&gt;
&lt;p&gt;Ledwell, J.R., McGillicuddy, D.J., Anderson, L.A.. &quot;Nutrient Flux into an Intense Deep Chlorophyll Layer in a Mode-water Eddy,&quot; Deep-Sea Research II, v.55, 2008, p. 1139.&lt;/p&gt;
&lt;p&gt;Li, Q.P. and Hansell, D.A.. &quot;Intercomparison and coupling of MAGIC and LWCC techniques for trace analysis of phosphate in seawater,&quot; Analytical Chemica Acta, v.611, 2008, p. 68.&lt;/p&gt;
&lt;p&gt;Li, Q.P., Hansell, D.A., McGillicuddy, D.J., Bates, N.R., Johnson, R.J.. &quot;Tracer-based assessment of the origin and biogeochemical transformation of a cyclonic eddy in the Sargasso Sea,&quot; Journal of Geophysical Research, v.113, 2008, p. 10006.&lt;/p&gt;
&lt;p&gt;Li, Q.P., Hansell, D.A., Zhang, J.-Z.. &quot;Underway monitoring of nanomolar nitrate plus nitrite and phosphate in oligotrophic seawater,&quot; Limnology and Oceanography: Methods, v.6, 2008, p. 319.&lt;/p&gt;
&lt;p&gt;Li, Q.P., Zhang, J.-Z., Millero, F.J., Hansell, D.A.. &quot;Continuous colorimetric determination of trace ammonium in seawater with a long-path liquid waveguide capillary cell,&quot; Marine Chemistry, v.96, 2005, p. 73.&lt;/p&gt;
&lt;p&gt;McGillicuddy, D.J., et. al.. &quot;Eddy/Wind Interactions Stimulate Extraordinary Mid-Ocean Plankton Blooms,&quot; Science, v.316, 2007, p. 1021.&lt;/p&gt;
&lt;p&gt;McGillicuddy, D.J., Ledwell, J.R., and Anderson, L.A.. &quot;Response to Comment on &quot;Eddy/Wind Interactions Stimulate Extraordinary Mid-Ocean Plankton Bloom&quot;.,&quot; Science, v.320, 2008.&lt;/p&gt;
&lt;p&gt;McGillicuddy, D.J., Ledwell, J.R., Anderson, L.A.. &quot;Response to Comment on &quot;Eddy/Wind Interactions Stimulate Extraordinary Mid-Ocean Plankton Bloom&quot;,&quot; Science, v.320, 2008.&lt;/p&gt;
&lt;p&gt;McGillicuddy, et. al.. &quot;Eddy/Wind Interactions Stimulate Extraordinary Mid-Ocean Plankton Blooms.,&quot; Science, v.316, 2007, p. 1021.&lt;/p&gt;
&lt;p&gt;Mourino B., and McGillicuddy, D.J.. &quot;Mesoscale Variability in the Metabolic Balance of the Sargasso Sea,&quot; Limnology &amp;amp; Oceanography, v.51, 2006, p. 2675.&lt;/p&gt;</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;Please refer to descriptions for each cruise (deployment). &amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Calibration of instruments:&amp;lt;/strong&amp;gt; &amp;lt;br /&amp;gt;
SBE-39s and SBE-37 were calibrated by SeaBird. &amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;ECO-FLNTU Chl a and Optical Backscatter sensors were compared to the Oceanus CTD fluorometer during 
comparison casts for each cruise. &amp;lt;/p&amp;gt;

from Cruise: OC404-01 &lt;pre&gt;
Details of the UCSB Spar buoy deployed during EDDIES 2004 Survey 1.
    Due to the cancellation of the EDDIES Tracer 1 cruise, 
    the mooring was recovered at the end of Survey 1.

Calibration of instruments:
    SBE-39s and SBE-37 were calibrated by SeaBird.

    ECO-FLNTU Chl a and Optical Backscatter sensors were compared to the Oceanus 
CTD fluorometer during a comparison cast (oc404-4 053) during EDDIES 2004 
Survey 2.  Using the factory Chl a slope values, yielded Chl a values that 
were about twice that of the CTD fluorometer.  The comparison of the  
extracted Chl a and Phae a samples to the CTD fluorometer also showed the 
CTD fluorometer to be reading too low.  Therefore, the ECO-FLNTU readings
of all 3 profiles were matched with corrected CTD fluorometer values rather 
than factory calibrated CTD fluorometer values for oc404-4 053. There was 
significant differences in the Chl offset count for all 3 ECO-FLNTU sensors.  
The ECO-FL sensor failed to log during the comparison cast, so no adjustment 
to the factory calibration factors could be determined for this sensor.

    The Optical Backscatter channel of the ECO-FLNTU was too insensitive for 
optimal use in these clean waters.  

Therefore these data are not reported in the final report.



Drogue Mooring details:
DateGMTLatitudeLongitude
Launch:25-Jun-04152630 30.17 N64 54.96 W
Recovery:30-Jun-04133830 57.00 N65 25.99 W


Buoy Instruments 
DepthSampling interval  Data Recovery   s/n
SurfaceARGOS/GPS positions  every hour100%
10temp, pressure1min100%SBE39-376

40temp1min100%SBE39-497

70temp1min100%SBE39-499

80temp1min100%SBE39-500
80Chl fl, turbidity4min100%ECO-FLNTU 085

90temp1min100%SBE39-501
90Chl fl, turbidity4min100%ECO-FLNTU 086

100temp, cond, pressure1min100%SBE37SM-406
100Chl fl, turbidity4min100%ECO-FLNTU 087

110temp1min100%SBE39-502
110Chl fl4min100%ECO-FL 055

120-138Holey Sock Droguenone

&lt;/pre&gt;


from Cruise: OC404-04 &lt;p&gt;&lt;h4&gt;Details of the UCSB Spar buoy deployed during EDDIES 2004 Survey 2. &lt;/h4&gt;&lt;/p&gt;

&lt;p&gt;Due to the cancellation of the EDDIES Tracer 1 cruise, the deployment during 
the Survey 1 leg was recovered prior to the end of Survey 1.  During Survey 2 
(oc404-4), the UCSB spar bouy was again deployed after determination of the eddy 
center position.  The second  mooring was recovered near the end of Survey 2.
&lt;/p&gt;

&lt;h4&gt;Calibration of instruments: &lt;/h4&gt;
&lt;p&gt;SBE-39s and SBE-37 were calibrated by SeaBird.  &lt;/p&gt;

&lt;p&gt;ECO-FLNTU Chl a and Optical Backscatter sensors were compared to the Oceanus 
CTD fluorometer during a comparison cast (oc404-4 053) during EDDIES 2004 Survey 
2.  Using the facory Chl a slope values, yielded Chl a values that were about 
twice that of the CTD fluorometer.  The comparison of the extracted Chl a and 
Phae a samples to the CTD fluorometer also showed the CTD fluorometer to be 
reading too low.  Therefore, the ECO-FLNTU readings of all 3 profiles were 
matched with corrected CTD fluorometer values rather than factory calibrated CTD 
fluorometer values for oc404-4 053. There was significant differences in the Chl 
offset count for all 3 ECO-FLNTU sensors.  The ECO-FL sensor failed to log 
during the comparison cast, so no adjustment to the factory calibration factors 
could be determined for this sensor. &lt;/p&gt;

&lt;p&gt;The Optical Backscatter channel of the ECO-FLNTU was too insensitive for 
optimal use in these clean waters.  Therefore the data is not reported in our 
report. &lt;/p&gt;


&lt;pre&gt;
Drogue Mooring details:
DateGMTLatitudeLongitude
Launch:26-Jul-04101630 40.57 N65 20.56 W
Recovery:4-Aug-04202830 46.23 N65 46.92 W



Buoy Instruments: 
Depth:Sampling interval  Data Recovery    s/n
SurfaceARGOS/GPS positions  every hour82%
10temp, pressure1min100%SBE39-376

40temp1min100%SBE39-497

70temp1min100%SBE39-499

80temp1min100%SBE39-500
80Chl fl, turbidity4min100%ECO-FLNTU 085

90temp1min100%SBE39-501
90Chl fl, turbidity4min100%ECO-FLNTU 086

100temp, cond, pressure1min100%SBE37SM-406
100Chl fl, turbidity4min100%ECO-FLNTU 087

110temp1min100%SBE39-502
110Chl fl4min100%ECO-FL 055

120-138Holey Sock Droguenone

&lt;/pre&gt;


from Cruise: OC415-01 &lt;h4&gt;Details of the UCSB Spar buoy deployed during EDDIES 2005 Survey 1.&lt;/h4&gt;

&lt;p&gt;The Spar buoy was deployed at the center of eddy A4 just before ending 
science work and heading for Bermuda.  It was intended to stay deployed 
throughout the Tracer 1 cruise and to be recovered early in Survey 2 cruise.  
However, due to the threat of Tropical Storm Franklin bearing down on the area, 
the Tracer people pulled the array prior to leaving the area.  Some instruments 
were stopped, or made safe by the Oceanus Science Tech, and data was downloaded 
at the start of Survey 2.  It was determined that the ECO-FL sensor had jammed
just prior to deployment. Therefore, no Chl a data was obtained at 80 meters.
&lt;/p&gt;

&lt;h4&gt;Calibration of instruments:&lt;/h4&gt;
&lt;p&gt;SBE-39s and SBE-37 were calibrated by SeaBird.  &lt;/p&gt;

&lt;p&gt;Between the EDDIES 2004 and 2005 deployments, the ECO-FLNTU units were 
returned to WETLabs and the sensitivity greatly increased in both the Chl a and 
Optical Backscatter channels.  The borrowed ECO-FL unit did not have the 
sensitivity changed. &lt;/p&gt;

&lt;p&gt;ECO-FLNTU Chl a and Optical Backscatter sensors were compared to the Oceanus 
CTD fluorometer during a comparison cast (oc415-1 062) during EDDIES 2005 Survey 
1.  The ECO-FLNTU and ECO-FL readings of all 4 time records were matched with 
the new WETLabs CTD fluorometer factory calibration values for the  cast. There 
was significant differences in the Chl offset count for all 4 ECO sensors.  One 
of the 4 ECO Chl a  factory calibration slopes agreed well with the new CTD 
fluorometer (calibrated also by WETLabs) but the other 3 sensor chl calibrations 
were off by +32%, +46%, and -44%. Without determining this matchup of 
sensitivities, the mooring data would have been very misleading.
 &lt;/p&gt;

&lt;p&gt;If the comparison of the extracted Chl a and Phaeo a descrete samples against 
the new CTD fluorometer readings determine that it is reading significantly 
different from reality, the moored data can be adjusted by using the same 
scaling factor being applied to the CTD data. &lt;/p&gt;

&lt;p&gt;The Optical Backscatter channel of the ECO-FLNTU was more sensitive, but 
still showed mostly noise and sudden shifts that were unrelated to changes in 
Chl fluorescence.  Therefore the data are not reported in our report.
&lt;/p&gt;

&lt;pre&gt;
Drogue Mooring details:
DateGMTLatitudeLongitude
Launch:14-Jul-05140130 41.45 N66 41.47 W
Recovery:23-Jul-05133830 19.87 N67 19.29 W


Buoy Instruments: 
Depth:Sampling interval    Data Recovery  s/n
SurfaceARGOS/GPS positions  every 30 min 96%
10temp, pressure1min100%SBE39-376

50temp1min100%SBE39-497

70temp1min100%SBE39-499

80temp1min100%SBE39-500
80Chl fl4min  0%ECO-FL 055

93temp1min100%SBE39-501
93Chl fl, turbidity4min100%ECO-FLNTU 085

106temp, cond, pressure1min100%SBE37SM-406
106Chl fl, turbidity4min100%ECO-FLNTU 086

120temp1min100%SBE39-502
120Chl fl, turbidity4min100%ECO-FLNTU 087


125-143Holey Sock Droguenone

&lt;/pre&gt;


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