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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/3113.rdf" xlink:actuate="onRequest">Iron and nutrients from underway samples from RVIB Nathaniel B. Palmer NBP0601, NBP0608 cruises in the Ross Sea Southern Ocean (CORSACS project)</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Sedwick, P. N. (2009) Iron and nutrients from underway samples from RVIB Nathaniel B. Palmer NBP0601, NBP0608 cruises in the Ross Sea Southern Ocean (CORSACS project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version September, 2009) Version Date 2009-09-01 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/3113 [access date]</gco:CharacterString>
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        <gco:CharacterString>iron and nutrients from underway samples Dataset Description: &amp;lt;p&amp;gt;dissolved iron, total iron, and nutrients from underway samples taken from the ship's underway sampling system&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;pre&amp;gt;

&amp;lt;h3&amp;gt;Sampling and Analytical Methodology&amp;lt;/h3&amp;gt;
Near-surface seawater samples were collected from ~3 m depth while
underway at ~5 knots, using a towed, trace-metal clean pumping
system developed by Ken Bruland and Geoffrey Smit (University
of California, Santa Cruise).  Briefly, seawater was collected
through the intake of a 'towfish' deployed at ca. 3 m water depth
and ca. 5 m outboard of the ship, and then pumped though acid-
cleaned low-density polyethylene tubing into a shipboard clean-air
laboratory container, where it was filtered in-line using a 0.2 &amp;amp;micro;m
Supor Acropak filter cartridge (Pall Corp.). The filtered seawater
samples were acidified to pH 1.7 with Seastar Baseline ultrapure
hydrochloric acid, stored for at least 24 hours, then dissolved
iron (dFe) was determined by flow injection analysis modified after
the method of Measures et al. [1995] with analytical figures of
merit as detailed by Sedwick et al. [2005, 2008].  The efficacy of
our analytical method for dissolved iron in seawater has been
verified in the SAFe intercomparison exercise [Johnson et al., 2007].
Our laboratory values for SAFe seawater reference materials are as
follows:
SAFe surface seawater S1: dFe = 0.11 &amp;amp;plusmn; 0.01 nM (n = 15) vs consensus
value of 0.097 &amp;amp;plusmn; 0.043 nM
SAFe deep seawater D2: dFe = 0.97 &amp;amp;plusmn; 0.06 nM (n = 14) vs consensus
value of 0.91 &amp;amp;plusmn; 0.17 nM.
Dissolved macronutrients were measured at sea in 0.2-&amp;amp;micro;m filtered
using JGOFS-standard autoanalyzer methods.

&amp;lt;h3&amp;gt;References&amp;lt;/h3&amp;gt;
Johnson, K. S., et al. (2007), The SAFe iron intercomparison cruise: An
international collaboration, Eos, Trans. Am. Geophys. Un., 88, 131-132.

Sedwick, P. N., T. M. Church, A. R. Bowie, C. M. Marsay, S. J. Ussher,
K. M. Achilles, P. J. Lethaby, R. J. Johnson, M. M. Sarin, and D. J.
McGillicuddy (2005), Iron in the Sargasso Sea (Bermuda Atlantic Time-series
Study region) during summer: Eolian imprint, spatiotemporal variability,
and ecological implications, Global Biogeochemical Cycles, 19,
doi:10.1029/2004GB002445.

Sedwick, P. N., A. R. Bowie, and T. W. Trull (2008), Dissolved iron in the
Australian sector of the Southern Ocean (CLIVAR-SR3 section): meridional
and seasonal trends, Deep-Sea Research I, doi:10.1016/j.dsr.2008.03.011.


&amp;lt;/pre&amp;gt;</gco:CharacterString>
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&lt;p&gt;From the information previously available from both field observations and experiments, the investigators formulated the following specific hypotheses regarding the interactive role of iron, light and CO2 in regulating algal composition in the Ross Sea: diatoms bloom in the southern Ross Sea only under optimum conditions of high iron, light and pCO2; colonial Phaeocystis dominate under conditions of high iron with either (or both) low light or low pCO2; and solitary Phaeocystis are predominant under conditions of low iron with either (or both) low light or low pCO2.&lt;/p&gt;
&lt;h4&gt;References:&lt;/h4&gt;
&lt;p&gt;Fitzwater, S.E., K.S. Johnson, R.M. Gordon, K.H. Coale, and W.O. Smith, Jr. (2000). Trace metal concentrations in the Ross Sea and their relationship with nutrients and growth. Deep-Sea Research II, 47: 3159-3179.&lt;/p&gt;
&lt;p&gt;Martin JH, Gordon RM, Fitzwater SE. Iron in Antarctic waters. Nature 1990 ;345(6271):156-158. Martin JH. 1990. Glacial-interglacial CO2 change: The iron hypothesis. Paleoceanography 5(1):1-13&lt;/p&gt;
&lt;p&gt;P. N. Sedwick, G. R. DiTullio, and D. J. Mackey, Iron and manganese in the Ross Sea, Antarctica: Seasonal iron limitation in Antarctic shelf waters, Journal of Geophysical Research, 105 (C5), 11,321-11,336, 2000.&lt;/p&gt;
&lt;p&gt;Sweeney, C. K. Arrigo, and G. van Gijken (2001). Prediction of seasonal changes in surface pCO2 in the Ross Sea, Antarctica using ocean color satellite data. 2001 Annual AGU meeting, San Fransisco, CA Dec. 10-15.&lt;/p&gt;
&lt;p&gt;IPCC, 2001: Climate Change 2001: Synthesis Report. A Contribution of Working Groups I, II, and III to the Third Assessment Report of theIntegovernmental Panel on Climate Change [Watson, R.T. and the Core Writing Team (eds.)]. Cambridge University Press, Cambridge,United Kingdom, and New York, NY, USA, 398 pp.&lt;/p&gt;
&lt;p&gt;&lt;strong&gt;Publications&lt;/strong&gt;&lt;/p&gt;
&lt;p&gt;Saito, M. A., Goepfert, T. J., Noble, A. E., Bertrand, E. M., Sedwick, P. N., and DiTullio, G. R.: A seasonal study of dissolved cobalt in the Ross Sea, Antarctica: micronutrient behavior, absence of scavenging, and relationships with Zn, Cd, and P, Biogeosciences, 7, 4059-4082, doi:10.5194/bg-7-4059-2010, 2010 (&lt;a href=&quot;http://www.biogeosciences.net/7/4059/2010/bg-7-4059-2010.html&quot;&gt;http://www.biogeosciences.net/7/4059/2010/bg-7-4059-2010.html&lt;/a&gt;)&lt;/p&gt;
&lt;p&gt;Bertrand EM, Saito MA, Lee PA, Dunbar RB, Sedwick PN and DiTullio GR (2011) Iron limitation of a springtime bacterial and phytoplankton community in the Ross Sea: implications for vitamin B12 nutrition. Front. Microbio. 2:160. doi: 10.3389/fmicb.2011.00160 (&lt;a href=&quot;http://www.frontiersin.org/Aquatic_Microbiology/10.3389/fmicb.2011.00160/abstract&quot;&gt;http://www.frontiersin.org/Aquatic_Microbiology/10.3389/fmicb.2011.00160/abstract&lt;/a&gt;)&lt;/p&gt;</gco:CharacterString>
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&amp;lt;h3&amp;gt;Sampling and Analytical Methodology&amp;lt;/h3&amp;gt;
Near-surface seawater samples were collected from ~3 m depth while
underway at ~5 knots, using a towed, trace-metal clean pumping
system developed by Ken Bruland and Geoffrey Smit (University
of California, Santa Cruise).  Briefly, seawater was collected
through the intake of a 'towfish' deployed at ca. 3 m water depth
and ca. 5 m outboard of the ship, and then pumped though acid-
cleaned low-density polyethylene tubing into a shipboard clean-air
laboratory container, where it was filtered in-line using a 0.2 &amp;amp;micro;m
Supor Acropak filter cartridge (Pall Corp.). The filtered seawater
samples were acidified to pH 1.7 with Seastar Baseline ultrapure
hydrochloric acid, stored for at least 24 hours, then dissolved
iron (dFe) was determined by flow injection analysis modified after
the method of Measures et al. [1995] with analytical figures of
merit as detailed by Sedwick et al. [2005, 2008].  The efficacy of
our analytical method for dissolved iron in seawater has been
verified in the SAFe intercomparison exercise [Johnson et al., 2007].
Our laboratory values for SAFe seawater reference materials are as
follows:
SAFe surface seawater S1: dFe = 0.11 &amp;amp;plusmn; 0.01 nM (n = 15) vs consensus
value of 0.097 &amp;amp;plusmn; 0.043 nM
SAFe deep seawater D2: dFe = 0.97 &amp;amp;plusmn; 0.06 nM (n = 14) vs consensus
value of 0.91 &amp;amp;plusmn; 0.17 nM.
Dissolved macronutrients were measured at sea in 0.2-&amp;amp;micro;m filtered
using JGOFS-standard autoanalyzer methods.

&amp;lt;h3&amp;gt;References&amp;lt;/h3&amp;gt;
Johnson, K. S., et al. (2007), The SAFe iron intercomparison cruise: An
international collaboration, Eos, Trans. Am. Geophys. Un., 88, 131-132.

Sedwick, P. N., T. M. Church, A. R. Bowie, C. M. Marsay, S. J. Ussher,
K. M. Achilles, P. J. Lethaby, R. J. Johnson, M. M. Sarin, and D. J.
McGillicuddy (2005), Iron in the Sargasso Sea (Bermuda Atlantic Time-series
Study region) during summer: Eolian imprint, spatiotemporal variability,
and ecological implications, Global Biogeochemical Cycles, 19,
doi:10.1029/2004GB002445.

Sedwick, P. N., A. R. Bowie, and T. W. Trull (2008), Dissolved iron in the
Australian sector of the Southern Ocean (CLIVAR-SR3 section): meridional
and seasonal trends, Deep-Sea Research I, doi:10.1016/j.dsr.2008.03.011.


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&amp;lt;h3&amp;gt;Data Processing&amp;lt;/h3&amp;gt;
An acid blank (to account for iron present in acid added to samples)
has been subtracted from raw dFe and TDFe concentrations.  For the
CORSACS-1 cruise, this blank was determined as 0.007 nM; for the
CORSACS-2 samples, the blank was below the limit of quantification
(i.e., negligible).

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