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            <gco:CharacterString>Cite this dataset as: Saito, M. (2020) Nutrients, cobalt, dissolved iron, and dissolved manganese from trace metal bottles from R/V Knorr cruise KN192-05 in the South Atlantic subtropical gyre and Benguela upwelling region in 2007 (CoFeMUG project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 2) Version Date 2013-03-20 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.3233.2 [access date]</gco:CharacterString>
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        <gco:CharacterString>Analysis of nutrients,  Cobalt (total and labile), dissolved Iron, and dissolved Manganese from TM bottle samples. Dataset Description: &amp;lt;p&amp;gt;Analysis of nutrients, Cobalt (total and labile), dissolved Iron, and dissolved Manganese of water samples drawn from Trace Metal Rosette (TMR) bottle casts.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;See Related Publications: Noble et al. (2012) and Sohm et al. (2011)&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;Three transects were sampled using the Trace Metal Rosette (TMR) on the CoFeMUG cruise aboard R/V Knorr in 2007. Refer to Noble et al. (2012) for detailed information on acquisition and processing.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Nutrient Analyses&amp;lt;/strong&amp;gt;: Technicon AutoAnalyzer II components were used to measure phophate and ammonium. Alpkem rapid flow analyzer (RFA) 300 components were used to measure silicic acid, nitrate+nitrite, and nitrite.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;Cobalt Analyses&amp;lt;/strong&amp;gt;: Total dissolved and labile cobalt concentrations were determined using cathodic stripping voltammetry, previously described by Saito and Moffet (2001) and Saito et al. (2004). Measurements were made using Eco-Chemie uAutolab-III systems connected to Metrohm 663 VA Stands with hanging mercury drop electrodes and Teflon sampling cups.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Iron and Manganese Analyses&amp;lt;/strong&amp;gt;: Total dissolved iron and manganese concentrations were measured using inductively coupled plasma mass spectrometry (ICP-MS). SAFe seawater intercalibration standards were analyzed at the beginning of each analysis day with iron concentrations of 0.96 ± 0.095 nmol L-1 for D2 and 0.125 ± 0.046 nmol L-1 for S1 (n = 10), which are within the reported ranges of 0.91 + 0.17 nmol L-1 and 0.097 + 0.043 nmol L-1 (Johnson et al. 2007).&amp;lt;/p&amp;gt;</gco:CharacterString>
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                            <gco:CharacterString>&lt;p&gt;The geochemistries of dissolved cobalt (Co) and iron (Fe) in the oceanic water column share several characteristics such as extremely low concentrations, redox chemistry, low solubility,and utilization as micronutrients by marine microbes. Iron has been the subject of considerable research focus in recent years due to its role in limiting phytoplankton productivity in oceanic and coastal upwelling environments. Cobalt has been much less studied, but recent data show it may be important in influencing primary productivity or phytoplankton community composition in certain geographical areas.&lt;/p&gt;
&lt;p&gt;The CoFeMUG project predated GEOTRACES, so while it is not formally recognized as a GEOTRACES section, it is considered a GEOTRACES-related project and the CoFeMUG data are GEOTRACES compliant.&lt;/p&gt;
&lt;p&gt;State-of-the-art geochemical and molecular biological techniques were used to address biogeochemical questions in the South Atlantic, and focus especially on the two trace metals, cobalt and iron. The 27-day cruise in November and December 2007 to the South Atlantic was designed to study cobalt and iron biogeochemistry and focus on four major hypotheses.&lt;/p&gt;
&lt;p&gt;(1) Large fluxes of labile cobalt are associated with upwelling systems even in Aeolian dominated environments.&lt;br /&gt;
(2) Cobalt and phosphate show correlations in (and only in) surface waters due to micronutrient utilization and rapid remineralization. The slope of the correlation is dependent on the chemical speciation of cobalt.&lt;br /&gt;
(3) The absence of Trichodesmium populations in the subtropical and tropical South Atlantic is caused by iron limitation.&lt;br /&gt;
(4) Based on work from the California and Peru Upwelling regimes, primary productivity in the Benguela upwelling regime off of South West Africa may be iron limited or iron-cobalt colimited.&lt;/p&gt;
&lt;p&gt;A combination of geochemical and biological/molecular analyses were made across an oligotrophic-upwelling transition to examine how changing metal regimes affect the physiology and growth of the important primary producers Trichodesmium and Synechococcus.&lt;/p&gt;
&lt;p&gt;CoFeMUG project results are published in:&lt;br /&gt;
Noble, Abigail E., Carl H. Lamborg, Dan C. Ohnemus, Phoebe J. Lam, Tyler J. Goepfert, Chris I. Measures, Caitlin H. Frame, Karen L. Casciotti, Giacomo R. DiTullio, Joe Jennings, and Mak A. Saito (2012) Basin-scale inputs of cobalt, iron, and manganese from the Benguela-Angola front to the South Atlantic Ocean. Limnology &amp;amp; Oceanography. Vol. 57(4), July 2012. pgs 989-1010. doi:10.4319/lo.2012.57.4.0989 (&lt;a href=&quot;http://www.aslo.org/lo/toc/vol_57/issue_4/0989.pdf&quot;&gt;www.aslo.org/lo/toc/vol_57/issue_4/0989.pdf&lt;/a&gt;)&lt;/p&gt;</gco:CharacterString>
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http://lod.bco-dmo.org/id/dataset-parameter/19713.rdf
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	Units: DD
	Description: &lt;p&gt;day of month; numeric 1 to 31&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19714.rdf
	Name: time
	Units: hhmm
	Description: &lt;p&gt;time of day; reported in GMT as hhmm &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19715.rdf
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	Units: decimal degrees
	Description: &lt;p&gt;longitude ranging from 0 to 360 degrees&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19716.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/19717.rdf
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	Units: decimal degrees
	Description: &lt;p&gt;latitude; North is positive, South is negative&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19718.rdf
	Name: depth_w
	Units: meters
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http://lod.bco-dmo.org/id/dataset-parameter/19719.rdf
	Name: depth
	Units: meters
	Description: &lt;p&gt;Sample depth&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19720.rdf
	Name: PO4
	Units: micromolar
	Description: &lt;p&gt;Phosphate concentration in uM.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19721.rdf
	Name: NO3_NO2
	Units: micromolar
	Description: &lt;p&gt;Nitrate plus nitrite concentration in uM. (Originally named 'N+N'.)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19722.rdf
	Name: SiO4
	Units: micromolar
	Description: &lt;p&gt;Silicate (Orthosilicic Acid) concentration in uM.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19723.rdf
	Name: NO2
	Units: micromolar
	Description: &lt;p&gt;Nitrite concentration in uM.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/19724.rdf
	Name: NH4
	Units: micromolar
	Description: &lt;p&gt;Ammonium concentration in uM.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/20983.rdf
	Name: run_id
	Units: dimensionless
	Description: &lt;p&gt;run ID of sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/20984.rdf
	Name: ev_code
	Units: dimensionless
	Description: &lt;p&gt;event code; type and number of sampling event; matches cruise event log&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/33353.rdf
	Name: Co_tot
	Units: picomolar
	Description: &lt;p&gt;Total Cobalt concentration in pM. (Originally named 'TCo'.)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/33354.rdf
	Name: Co_labile
	Units: picomolar
	Description: &lt;p&gt;Concentration of labile Cobalt in pM. (Originally named Co'.) Note: lt_0.75 = less than 0.75.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/33355.rdf
	Name: Fe_Td
	Units: nanomolar
	Description: &lt;p&gt;Total dissolved Iron concentration in nM.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/33356.rdf
	Name: Mn_Td
	Units: nanomolar
	Description: &lt;p&gt;Total dissolved Manganese concentration in nM.&lt;/p&gt; 
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	Name: NO3_NO2_flag
	Units: dimensionless
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	Description: &lt;p&gt;Quality flag for SiO4. See 'Processing Description' for code definitions.&lt;/p&gt; 
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	Name: NH4_flag
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	Units: dimensionless
	Description: &lt;p&gt;Quality flag for Co_labile. See 'Processing Description' for code definitions.&lt;/p&gt; 
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	Name: Fe_Td_flag
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	Description: &lt;p&gt;Quality flag for Fe_Td. See 'Processing Description' for code definitions.&lt;/p&gt; 
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&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Nutrient Analyses&amp;lt;/strong&amp;gt;: Technicon AutoAnalyzer II components were used to measure phophate and ammonium. Alpkem rapid flow analyzer (RFA) 300 components were used to measure silicic acid, nitrate+nitrite, and nitrite.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;Cobalt Analyses&amp;lt;/strong&amp;gt;: Total dissolved and labile cobalt concentrations were determined using cathodic stripping voltammetry, previously described by Saito and Moffet (2001) and Saito et al. (2004). Measurements were made using Eco-Chemie uAutolab-III systems connected to Metrohm 663 VA Stands with hanging mercury drop electrodes and Teflon sampling cups.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Iron and Manganese Analyses&amp;lt;/strong&amp;gt;: Total dissolved iron and manganese concentrations were measured using inductively coupled plasma mass spectrometry (ICP-MS). SAFe seawater intercalibration standards were analyzed at the beginning of each analysis day with iron concentrations of 0.96 ± 0.095 nmol L-1 for D2 and 0.125 ± 0.046 nmol L-1 for S1 (n = 10), which are within the reported ranges of 0.91 + 0.17 nmol L-1 and 0.097 + 0.043 nmol L-1 (Johnson et al. 2007).&amp;lt;/p&amp;gt;</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;Asterisks next to some values for Fe and Mn denote samples where contamination is suspected. Quality flags indicate values below detection limits and potentially erroneous data according to the codes below.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Quality Flag Codes:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;0&amp;lt;/strong&amp;gt; = no quality control = No quality control procedures have been applied to the data value. This is the initial status for all data values entering the working archive.&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;1&amp;lt;/strong&amp;gt; = good value = Good quality data value that is not part of any identified malfunction and has been verified as consistent with real phenomena during the quality control process.&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;2&amp;lt;/strong&amp;gt; = probably good value = Data value that is probably consistent with real phenomena but this is unconfirmed or data value forming part of a malfunction that is considered too small to affect the overall quality of the data object of which it is a part.&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;3&amp;lt;/strong&amp;gt; = probably bad value = Data value recognized as unusual during quality control that forms part of a feature that is probably inconsistent with real phenomena.&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;4&amp;lt;/strong&amp;gt; = bad value = An obviously erroneous data value.&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;5&amp;lt;/strong&amp;gt; = changed value = Data value adjusted during quality control. Best practice strongly recommends that the value before the change be preserved in the data or its accompanying metadata.&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;6&amp;lt;/strong&amp;gt; = value below detection = The level of the measured phenomenon was too small to be quantified by the technique employed to measure it. The accompanying value is the detection limit for the technique or zero if that value is unknown.&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;7&amp;lt;/strong&amp;gt; = missing = Bottle didn't trip or sample wasn't taken.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;BCO-DMO Processing Notes:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
-Modified original parameter names to conform with BCO-DMO naming conventions;&amp;lt;br /&amp;gt;
-Missing values (blank) were replaced with 'nd' to indicate 'no data'.&amp;lt;br /&amp;gt;
History:&amp;lt;br /&amp;gt;
7 October 2009 - nutrients and preliminary Co data submitted to BCO-DMO; awaiting documentation from originating PI.&amp;lt;br /&amp;gt;
February 2010 - units for nutrient data confirmed to be micromolar; Cobalt measurements will be added in the future and are picomolar.&amp;lt;br /&amp;gt;
20 March 2013 - Co, Fe, Mn data submitted and joined to nutrients. Quality flags were also added by investigator.&amp;lt;/p&amp;gt;</gco:CharacterString>
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