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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/3308.rdf" xlink:actuate="onRequest">Sulphur Hexafluoride (SF6) from Station/Niskin bottle sort from NOAA Ship Ronald H. Brown RB-08-02 in the Southwest Atlantic sector of the Southern Ocean near South Georgia Island in 2008 (SO_GasEx project)</gmx:Anchor>
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                <gco:Date>2010-02-16</gco:Date>
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                <gmx:Anchor xlink:href="http://orcid.org/0000-0002-0944-6952" xlink:title="ORCID" xlink:actuate="onRequest">David T. Ho</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Ho, D. T. (2010) Sulphur Hexafluoride (SF6) from Station/Niskin bottle sort from NOAA Ship Ronald H. Brown RB-08-02 in the Southwest Atlantic sector of the Southern Ocean near South Georgia Island in 2008 (SO_GasEx project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 16 Feb 2010) Version Date 2010-02-16 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/3308 [access date]</gco:CharacterString>
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      <gmd:abstract>
        <gco:CharacterString>SF6 Discrete - Station/Niskin Sort Dataset Description: &amp;lt;p&amp;gt;SF6 Discrete - Station/Niskin Sort&amp;lt;br /&amp;gt;
Analysis of discrete samples for SF6&amp;lt;br /&amp;gt;
Samples collected from CTD casts, from underway scientific&amp;lt;br /&amp;gt;
seawater line, and from submerged water pump&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;b&amp;gt;See: &amp;lt;/b&amp;gt;&amp;lt;a href=&amp;quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Cruise_Report.pdf&amp;quot;&amp;gt;SO-GasEx cruise report, Section 5.3.3 ppgs 19-20&amp;lt;/a&amp;gt; &amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;Operation description:&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Sampling times and locations:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Sampled all CTD casts where Niskin bottles were tripped.&amp;lt;br /&amp;gt;
One deep cast to 4600m, two mid-depth casts to 1500m, four&amp;lt;br /&amp;gt;
shallow casts to 100m, and other casts usually to 500m.&amp;lt;br /&amp;gt;
See CTD cast logs and bottle files for specific times, locations, and bottles for each cast.&amp;lt;br /&amp;gt;
See event log for times and locations when sampled underway seawater line.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Overall sampling strategy:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Normally collected one sample from each depth that might contain&amp;lt;br /&amp;gt;
the released SF6, plus three - six samples deeper.  All available&amp;lt;br /&amp;gt;
depths were sampled on the first four casts and on any later cast&amp;lt;br /&amp;gt;
that was shallower than 500m.  If multiple Niskins were tripped&amp;lt;br /&amp;gt;
at a given depth, hydrography sampled only one of these.  Duplicate&amp;lt;br /&amp;gt;
samples were drawn from a Niskin, normally in the mixed layer, on&amp;lt;br /&amp;gt;
nearly every cast.   The first Niskin of a cast that was sampled&amp;lt;br /&amp;gt;
was the deepest Helium sample, and the sampling continued in order&amp;lt;br /&amp;gt;
to the surface Niskin.  The deeper Niskins for SF6 sampling were&amp;lt;br /&amp;gt;
done next, starting at the deepest.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Sampling technique:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The discrete samples were collected in 550 ml borosilicate glass bottles&amp;lt;br /&amp;gt;
with ground glass stoppers.  A sample bottle was shaken with 30-40 ml of&amp;lt;br /&amp;gt;
water; then inverted and rinsed with 10-20 ml of water.  The bottle was&amp;lt;br /&amp;gt;
filled from the bottom with ~800 ml of bubble free water.  The stopper&amp;lt;br /&amp;gt;
was put in the bottle ensuring that no gas bubble was enclosed.  After&amp;lt;br /&amp;gt;
all the samples were collected from a cast, a rubber band was slipped&amp;lt;br /&amp;gt;
over the stopper.  If the samples were not going to be analyzed within&amp;lt;br /&amp;gt;
10 hours, the glass bottles were stored in water.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Analytical method:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The samples were analyzed on an instrument patterned after Law et.al. [1998]&amp;lt;br /&amp;gt;
and built in 1998 at AOML.  About 269 ml of sample water was sucked into an&amp;lt;br /&amp;gt;
evacuated chamber through a showerhead.  The SF6 that entered the headspace&amp;lt;br /&amp;gt;
during filling and the SF6 that remained dissolved in the water were stripped&amp;lt;br /&amp;gt;
with ultra high purity nitrogen onto a Carboxen 1000 trap held at -68 C.&amp;lt;br /&amp;gt;
After a little more than 3 minutes of purging, the trap was isolated and heated&amp;lt;br /&amp;gt;
to 150 C.  The trapped gases were swept onto a 1.5 m x 0.3 cm OD molecular sieve&amp;lt;br /&amp;gt;
5A column.  The SF6 was separated from oxygen and other gases and was measured&amp;lt;br /&amp;gt;
with an electron capture detector (ECD).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The detector was calibrated using six standards:&amp;lt;br /&amp;gt;
- cyl#CA2071- 5.7 pptrillion (v/v)&amp;lt;br /&amp;gt;
- cyl#CA2089- 55.1 pptr&amp;lt;br /&amp;gt;
- cyl#CA3452- 112.3 pptr&amp;lt;br /&amp;gt;
- cyl#CA2060- 166.6 pptr&amp;lt;br /&amp;gt;
- cyl#CA2056- 345.0 pptr&amp;lt;br /&amp;gt;
- cyl#CA2093- 1109.0 pptr&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The custom software includes a chromatography package from WillStein Software,&amp;lt;br /&amp;gt;
which is used for acquisition of the ECD output and to reintegrate peaks.&amp;lt;br /&amp;gt;
The SF6 peaks were reintegrated for all blank analyses, water analyses and the&amp;lt;br /&amp;gt;
analyses of 5.5 pptr standard.  The larger standards had very favorable signal&amp;lt;br /&amp;gt;
to noise ratios.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The pattern of analyses include initial and final groups of standards bracketing&amp;lt;br /&amp;gt;
groups of water analyses.  The water samples from each cast were typically split&amp;lt;br /&amp;gt;
into two groups, each covering the entire water column.  Within a group, the&amp;lt;br /&amp;gt;
deepest water samples were analyzed before the more concentrated surface water&amp;lt;br /&amp;gt;
samples.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The Typical Analyses Sequence:&amp;lt;br /&amp;gt;
- 2-3 gas blanks&amp;lt;br /&amp;gt;
- 15-20 gas standards spanning the entire range&amp;lt;br /&amp;gt;
- gas blank&amp;lt;br /&amp;gt;
- 1-2 stripper blanks&amp;lt;br /&amp;gt;
- 7-9 water analyses&amp;lt;br /&amp;gt;
- stripper blank&amp;lt;br /&amp;gt;
- 1 analysis of 166.6 pptr standard&amp;lt;br /&amp;gt;
- stripper blank&amp;lt;br /&amp;gt;
- 7-9 water analyses&amp;lt;br /&amp;gt;
- [repeat analyses of stripper blanks, 166.p pptr std, and water samples two or three times]&amp;lt;br /&amp;gt;
- stripper blank&amp;lt;br /&amp;gt;
- gas blank&amp;lt;br /&amp;gt;
- 5-15 standards&amp;lt;br /&amp;gt;
- 2 gas blanks&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The stripping chamber was evacuated and flushed with nitrogen before the first use.&amp;lt;br /&amp;gt;
If the stripping chamber was not going to used for more than 6 hours, it was rinsed&amp;lt;br /&amp;gt;
with fresh water and then evacuated and flushed.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Instrument details:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The ECD gas chromatograph is a Shimadzu Mini 2.&amp;lt;br /&amp;gt;
The custom software was written with LabView 5.1 in 1998 and revised in 2002.&amp;lt;br /&amp;gt;
The reference for a description of the instrument is: Law, C.S, A.J. Watson,&amp;lt;br /&amp;gt;
M.J. Liddicoat, and T. Stanton, Sulphur hexafluoride as a tracer of biogeochemical&amp;lt;br /&amp;gt;
and physical processes in an open-ocean iron fertilization experiment,&amp;lt;br /&amp;gt;
Deep Sea Research II, 45, 977-994, 1998.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;Operation Log  - During Cruise&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;5 - 6 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Attempts were made to use this discrete instrument to quantitate the amount of&amp;lt;br /&amp;gt;
SF6 in water actively being bubbled in the dosing tank.  All attempts resulted&amp;lt;br /&amp;gt;
in peaks much larger than full scale for the ECD.  The excessive amounts of SF6&amp;lt;br /&amp;gt;
were easily swept out of the instrument.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 3&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
one sample of a duplicate pair is stored for 23 hours before analyses - precision&amp;lt;br /&amp;gt;
of duplicates was good&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 5&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
one sample of a duplicate pair is stored for 24 hours before analyses,&amp;lt;br /&amp;gt;
another sample of a different duplicate pair is stored for 52 hours.&amp;lt;br /&amp;gt;
Precision of the 52-hour duplicates was poorer than normal.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 8&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
These samples were stored overnight before analyses as were some earlier&amp;lt;br /&amp;gt;
stations and many later stations.  This was the first station for which&amp;lt;br /&amp;gt;
some outgassing bubbles in some samples was noticed.  These tiny bubbles&amp;lt;br /&amp;gt;
(&amp;amp;lt;0.1 ml total volume) were not present when the bottle was sealed and&amp;lt;br /&amp;gt;
did not seem to bias the SF6 results.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 10&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The sampling order was more discontinuous than normal to accommodate noble&amp;lt;br /&amp;gt;
gas sampling.  For the collection of samples from the underway system after&amp;lt;br /&amp;gt;
station 10, the outflow tube of the MicroTSG in the hydro lab sink was put&amp;lt;br /&amp;gt;
in the bottom of a sample bottle and left to overfill the bottle for at least&amp;lt;br /&amp;gt;
2 minutes (flow at 1.3 liter/min).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;13 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottle 15 (stn 9, N 22) the Labview program was in its&amp;lt;br /&amp;gt;
'pause and prompt' state longer than usual.  The analytical system evacuates the&amp;lt;br /&amp;gt;
stripping chamber and then presents a prompt screen until a &amp;amp;quot;start&amp;amp;quot; button is&amp;lt;br /&amp;gt;
pushed by the analyst.  The analyst has to draw some of the sample through the&amp;lt;br /&amp;gt;
inlet tube and solenoid valve before pushing the &amp;amp;quot;start&amp;amp;quot; button.  If the 'pause&amp;lt;br /&amp;gt;
and prompt' state is long, the chance of outside air leaking into the chamber is&amp;lt;br /&amp;gt;
greater (potential higher blank).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;15 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
In an effort to have comparable results from the underway and discrete SF6 analytical&amp;lt;br /&amp;gt;
systems, the single SF6 gaseous standard for the underway system (58.2 pptr) was run&amp;lt;br /&amp;gt;
on the discrete system and three of the discrete standards (166.6, 55.1, and 5.7 pptr)&amp;lt;br /&amp;gt;
were run on the underway system.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;18 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Both system and stripper blanks are significantly higher.  The second dosing tank is&amp;lt;br /&amp;gt;
being bubbled on the afterdeck, and the lab air was enriched in SF6.  No leaky fittings&amp;lt;br /&amp;gt;
could be found on the analytical system despite a day of searching.  After ~48 hrs the&amp;lt;br /&amp;gt;
blanks decreased, but remained higher than at the start of the cruise.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;22 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Last night was the first station (16) on the second patch.  I took a sample from the&amp;lt;br /&amp;gt;
underway system to quickly check the strength of ECD signal.  When the sample was run,&amp;lt;br /&amp;gt;
the peak went offscale.  The ECD was set for 2nAmp standing current through station 14.&amp;lt;br /&amp;gt;
I decreased the setting to 1 nAmp.     To span the largest peak from the water analyses&amp;lt;br /&amp;gt;
of station 16, I had to trap 6 regular gas loops (1.606 ml) of the most concentrated&amp;lt;br /&amp;gt;
standard (1109 pptr).  I am concerned about peak shape changes while trapping that many&amp;lt;br /&amp;gt;
loops sequentially, so I put the second gas sample loop valve back on the system.&amp;lt;br /&amp;gt;
[it was taken off during a previous experiment.]  I made a large loop (~7 ml) and created&amp;lt;br /&amp;gt;
new analytical methods to adequately flush the loop while and after filling it with&amp;lt;br /&amp;gt;
standard or blank gas.  I will have to determine the exact volume of the new gas loop&amp;lt;br /&amp;gt;
back at AOML.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;25 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Try again to locate the source of the elevated blanks, especially the stripper blanks.&amp;lt;br /&amp;gt;
Still, could not find any fitting that leaked.  At the end of a day of analyses,&amp;lt;br /&amp;gt;
the chamber is rinsed with fresh water to reduce the corrosion on the solenoid valves&amp;lt;br /&amp;gt;
attached to the drain and vacuum connections.  I stripped a sample of the fresh water&amp;lt;br /&amp;gt;
on the ship and discovered that it was as concentrated as the surface 'in-patch' water&amp;lt;br /&amp;gt;
(&amp;amp;gt;200 fmole/liter).  The chamber will continue to be rinsed with fresh water, but it&amp;lt;br /&amp;gt;
will go through a couple evacuate-and-purge cycles before being left for the night.&amp;lt;br /&amp;gt;
[no reduction in the blanks developed, but the procedure was continued.]&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;25 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analyses of sample bottles 202 (stn 25, N 3), 206 (stn 25, N 9) and 10&amp;lt;br /&amp;gt;
(stn 26, N 18) the Labview program was in its 'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;26 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottles 203 (stn 27, N 8) the Labview program was in its&amp;lt;br /&amp;gt;
'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;28 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottles 2 (stn 32, submerged pump) the Labview program was&amp;lt;br /&amp;gt;
in its 'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;29 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analyses of sample bottles 2 (stn 35, N 7) and 17 (stn 35, underway system)&amp;lt;br /&amp;gt;
the Labview program was in its 'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;30 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottles 202 (stn 37, N 6) the Labview program was in its&amp;lt;br /&amp;gt;
'pause and prompt' state longer than usual.    During analysis of sample bottles 206&amp;lt;br /&amp;gt;
(stn 37, N 10) there seemed to be air in the inlet line and the water level in the&amp;lt;br /&amp;gt;
stripping chamber seemed lower than usual.  Maybe the inlet tube was not submerged&amp;lt;br /&amp;gt;
as low as it should have been [but how would the Pt wire water sensors stop the water&amp;lt;br /&amp;gt;
flow automatically - splashes with gas going in?].&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;31 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During sampling, the stopper on bottle 203 (stn 41, N 3) was removed ~3 minutes after&amp;lt;br /&amp;gt;
sampling so some more a little more water from the niskin was gently added to the very&amp;lt;br /&amp;gt;
top of the bottle and the stopper reinserted.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;03 April 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During sampling, the stopper on bottle 203 (stn 41, N 3) was removed ~3 minutes after&amp;lt;br /&amp;gt;
sampling so some more a little more water from the niskin was gently added to the very&amp;lt;br /&amp;gt;
top of the bottle and the stopper reinserted.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;For Blanks and Cals See: &amp;lt;/b&amp;gt;&amp;lt;a href=&amp;quot;http://bcodata.whoi.edu/SO-GasEx/MDR_13_discrete_SF6_Blanks_and_Cals.pdf&amp;quot;&amp;gt;SO-GasEx Discrete SF6 Blanks and Calibration Curves&amp;lt;/a&amp;gt;&amp;lt;/p&amp;gt;</gco:CharacterString>
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Â» International SOLAS Web site
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&lt;li&gt;What is the effect of fetch on the gas transfer?&lt;/li&gt;
&lt;li&gt;How do other non-direct wind effects influence gas transfer?&lt;/li&gt;
&lt;li&gt;How do changing pCO2 and DMS levels affect the air-sea CO2 and DMS flux, respectively in the same locale?&lt;/li&gt;
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&lt;li&gt;Do the different disparate estimates of fluxes agree, and if not why?&lt;/li&gt;
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&lt;p&gt; &lt;/p&gt;
&lt;h3&gt;Related files&lt;/h3&gt;
&lt;p&gt;&lt;a href=&quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Cruise_Report.pdf&quot;&gt;SO-GasEx cruise report&lt;/a&gt;&lt;br /&gt;
&lt;a href=&quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Science_Plan.pdf&quot;&gt;SO-GasEx Science Plan&lt;/a&gt;&lt;br /&gt;
&lt;a href=&quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Implementation_Plan.pdf&quot;&gt;SO-GasEx Implementation Plan&lt;/a&gt;&lt;/p&gt;
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	Description: &lt;p&gt;Precision percentage: For 2 analyses percentage is difference divided by average; For &amp;gt;2 analyses percentage is standard deviation divided by average&lt;/p&gt; 
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	Name: station
	Units: integer
	Description: &lt;p&gt;SO-GasEx CTD Station Id&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21112.rdf
	Name: niskin
	Units: integer
	Description: &lt;p&gt;niskin bottle number&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21113.rdf
	Name: year_day_collected
	Units: decimal day
	Description: &lt;p&gt;year day collected&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21114.rdf
	Name: pres
	Units: decibars
	Description: &lt;p&gt;pressure from CTD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21115.rdf
	Name: temp
	Units: degrees celcius
	Description: &lt;p&gt;temperature from CTD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21116.rdf
	Name: sal
	Units: dimensionless
	Description: &lt;p&gt;salinity from CTD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21117.rdf
	Name: sigma_t
	Units: kilograms/meter^3
	Description: &lt;p&gt;sigma_t (density) from CTD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21118.rdf
	Name: o2
	Units: umol/kg
	Description: &lt;p&gt;dissolved Oxygen&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21119.rdf
	Name: lon_collection
	Units: decimal degrees
	Description: &lt;p&gt;Collection longitude in decimal degrees (West is negative)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21120.rdf
	Name: lat_collection
	Units: decimal degrees
	Description: &lt;p&gt;Collection latitude in decimal degrees (South is negative)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21121.rdf
	Name: DrawT_minus_C
	Units: (tbd)
	Description: &lt;p&gt;DrawT-C&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21122.rdf
	Name: O2_discrete
	Units: umol/kg
	Description: &lt;p&gt;Oxygen discrete&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/21123.rdf
	Name: O2_satur
	Units: milliliters/liter
	Description: &lt;p&gt;Oxygen saturated&lt;/p&gt; 
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                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;lt;b&amp;gt;See: &amp;lt;/b&amp;gt;&amp;lt;a href=&amp;quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Cruise_Report.pdf&amp;quot;&amp;gt;SO-GasEx cruise report, Section 5.3.3 ppgs 19-20&amp;lt;/a&amp;gt; &amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;Operation description:&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Sampling times and locations:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Sampled all CTD casts where Niskin bottles were tripped.&amp;lt;br /&amp;gt;
One deep cast to 4600m, two mid-depth casts to 1500m, four&amp;lt;br /&amp;gt;
shallow casts to 100m, and other casts usually to 500m.&amp;lt;br /&amp;gt;
See CTD cast logs and bottle files for specific times, locations, and bottles for each cast.&amp;lt;br /&amp;gt;
See event log for times and locations when sampled underway seawater line.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Overall sampling strategy:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Normally collected one sample from each depth that might contain&amp;lt;br /&amp;gt;
the released SF6, plus three - six samples deeper.  All available&amp;lt;br /&amp;gt;
depths were sampled on the first four casts and on any later cast&amp;lt;br /&amp;gt;
that was shallower than 500m.  If multiple Niskins were tripped&amp;lt;br /&amp;gt;
at a given depth, hydrography sampled only one of these.  Duplicate&amp;lt;br /&amp;gt;
samples were drawn from a Niskin, normally in the mixed layer, on&amp;lt;br /&amp;gt;
nearly every cast.   The first Niskin of a cast that was sampled&amp;lt;br /&amp;gt;
was the deepest Helium sample, and the sampling continued in order&amp;lt;br /&amp;gt;
to the surface Niskin.  The deeper Niskins for SF6 sampling were&amp;lt;br /&amp;gt;
done next, starting at the deepest.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Sampling technique:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The discrete samples were collected in 550 ml borosilicate glass bottles&amp;lt;br /&amp;gt;
with ground glass stoppers.  A sample bottle was shaken with 30-40 ml of&amp;lt;br /&amp;gt;
water; then inverted and rinsed with 10-20 ml of water.  The bottle was&amp;lt;br /&amp;gt;
filled from the bottom with ~800 ml of bubble free water.  The stopper&amp;lt;br /&amp;gt;
was put in the bottle ensuring that no gas bubble was enclosed.  After&amp;lt;br /&amp;gt;
all the samples were collected from a cast, a rubber band was slipped&amp;lt;br /&amp;gt;
over the stopper.  If the samples were not going to be analyzed within&amp;lt;br /&amp;gt;
10 hours, the glass bottles were stored in water.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Analytical method:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The samples were analyzed on an instrument patterned after Law et.al. [1998]&amp;lt;br /&amp;gt;
and built in 1998 at AOML.  About 269 ml of sample water was sucked into an&amp;lt;br /&amp;gt;
evacuated chamber through a showerhead.  The SF6 that entered the headspace&amp;lt;br /&amp;gt;
during filling and the SF6 that remained dissolved in the water were stripped&amp;lt;br /&amp;gt;
with ultra high purity nitrogen onto a Carboxen 1000 trap held at -68 C.&amp;lt;br /&amp;gt;
After a little more than 3 minutes of purging, the trap was isolated and heated&amp;lt;br /&amp;gt;
to 150 C.  The trapped gases were swept onto a 1.5 m x 0.3 cm OD molecular sieve&amp;lt;br /&amp;gt;
5A column.  The SF6 was separated from oxygen and other gases and was measured&amp;lt;br /&amp;gt;
with an electron capture detector (ECD).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The detector was calibrated using six standards:&amp;lt;br /&amp;gt;
- cyl#CA2071- 5.7 pptrillion (v/v)&amp;lt;br /&amp;gt;
- cyl#CA2089- 55.1 pptr&amp;lt;br /&amp;gt;
- cyl#CA3452- 112.3 pptr&amp;lt;br /&amp;gt;
- cyl#CA2060- 166.6 pptr&amp;lt;br /&amp;gt;
- cyl#CA2056- 345.0 pptr&amp;lt;br /&amp;gt;
- cyl#CA2093- 1109.0 pptr&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The custom software includes a chromatography package from WillStein Software,&amp;lt;br /&amp;gt;
which is used for acquisition of the ECD output and to reintegrate peaks.&amp;lt;br /&amp;gt;
The SF6 peaks were reintegrated for all blank analyses, water analyses and the&amp;lt;br /&amp;gt;
analyses of 5.5 pptr standard.  The larger standards had very favorable signal&amp;lt;br /&amp;gt;
to noise ratios.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The pattern of analyses include initial and final groups of standards bracketing&amp;lt;br /&amp;gt;
groups of water analyses.  The water samples from each cast were typically split&amp;lt;br /&amp;gt;
into two groups, each covering the entire water column.  Within a group, the&amp;lt;br /&amp;gt;
deepest water samples were analyzed before the more concentrated surface water&amp;lt;br /&amp;gt;
samples.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The Typical Analyses Sequence:&amp;lt;br /&amp;gt;
- 2-3 gas blanks&amp;lt;br /&amp;gt;
- 15-20 gas standards spanning the entire range&amp;lt;br /&amp;gt;
- gas blank&amp;lt;br /&amp;gt;
- 1-2 stripper blanks&amp;lt;br /&amp;gt;
- 7-9 water analyses&amp;lt;br /&amp;gt;
- stripper blank&amp;lt;br /&amp;gt;
- 1 analysis of 166.6 pptr standard&amp;lt;br /&amp;gt;
- stripper blank&amp;lt;br /&amp;gt;
- 7-9 water analyses&amp;lt;br /&amp;gt;
- [repeat analyses of stripper blanks, 166.p pptr std, and water samples two or three times]&amp;lt;br /&amp;gt;
- stripper blank&amp;lt;br /&amp;gt;
- gas blank&amp;lt;br /&amp;gt;
- 5-15 standards&amp;lt;br /&amp;gt;
- 2 gas blanks&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The stripping chamber was evacuated and flushed with nitrogen before the first use.&amp;lt;br /&amp;gt;
If the stripping chamber was not going to used for more than 6 hours, it was rinsed&amp;lt;br /&amp;gt;
with fresh water and then evacuated and flushed.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Instrument details:&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The ECD gas chromatograph is a Shimadzu Mini 2.&amp;lt;br /&amp;gt;
The custom software was written with LabView 5.1 in 1998 and revised in 2002.&amp;lt;br /&amp;gt;
The reference for a description of the instrument is: Law, C.S, A.J. Watson,&amp;lt;br /&amp;gt;
M.J. Liddicoat, and T. Stanton, Sulphur hexafluoride as a tracer of biogeochemical&amp;lt;br /&amp;gt;
and physical processes in an open-ocean iron fertilization experiment,&amp;lt;br /&amp;gt;
Deep Sea Research II, 45, 977-994, 1998.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;Operation Log  - During Cruise&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;5 - 6 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Attempts were made to use this discrete instrument to quantitate the amount of&amp;lt;br /&amp;gt;
SF6 in water actively being bubbled in the dosing tank.  All attempts resulted&amp;lt;br /&amp;gt;
in peaks much larger than full scale for the ECD.  The excessive amounts of SF6&amp;lt;br /&amp;gt;
were easily swept out of the instrument.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 3&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
one sample of a duplicate pair is stored for 23 hours before analyses - precision&amp;lt;br /&amp;gt;
of duplicates was good&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 5&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
one sample of a duplicate pair is stored for 24 hours before analyses,&amp;lt;br /&amp;gt;
another sample of a different duplicate pair is stored for 52 hours.&amp;lt;br /&amp;gt;
Precision of the 52-hour duplicates was poorer than normal.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 8&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
These samples were stored overnight before analyses as were some earlier&amp;lt;br /&amp;gt;
stations and many later stations.  This was the first station for which&amp;lt;br /&amp;gt;
some outgassing bubbles in some samples was noticed.  These tiny bubbles&amp;lt;br /&amp;gt;
(&amp;amp;lt;0.1 ml total volume) were not present when the bottle was sealed and&amp;lt;br /&amp;gt;
did not seem to bias the SF6 results.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;Station 10&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
The sampling order was more discontinuous than normal to accommodate noble&amp;lt;br /&amp;gt;
gas sampling.  For the collection of samples from the underway system after&amp;lt;br /&amp;gt;
station 10, the outflow tube of the MicroTSG in the hydro lab sink was put&amp;lt;br /&amp;gt;
in the bottom of a sample bottle and left to overfill the bottle for at least&amp;lt;br /&amp;gt;
2 minutes (flow at 1.3 liter/min).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;13 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottle 15 (stn 9, N 22) the Labview program was in its&amp;lt;br /&amp;gt;
'pause and prompt' state longer than usual.  The analytical system evacuates the&amp;lt;br /&amp;gt;
stripping chamber and then presents a prompt screen until a &amp;amp;quot;start&amp;amp;quot; button is&amp;lt;br /&amp;gt;
pushed by the analyst.  The analyst has to draw some of the sample through the&amp;lt;br /&amp;gt;
inlet tube and solenoid valve before pushing the &amp;amp;quot;start&amp;amp;quot; button.  If the 'pause&amp;lt;br /&amp;gt;
and prompt' state is long, the chance of outside air leaking into the chamber is&amp;lt;br /&amp;gt;
greater (potential higher blank).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;15 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
In an effort to have comparable results from the underway and discrete SF6 analytical&amp;lt;br /&amp;gt;
systems, the single SF6 gaseous standard for the underway system (58.2 pptr) was run&amp;lt;br /&amp;gt;
on the discrete system and three of the discrete standards (166.6, 55.1, and 5.7 pptr)&amp;lt;br /&amp;gt;
were run on the underway system.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;18 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Both system and stripper blanks are significantly higher.  The second dosing tank is&amp;lt;br /&amp;gt;
being bubbled on the afterdeck, and the lab air was enriched in SF6.  No leaky fittings&amp;lt;br /&amp;gt;
could be found on the analytical system despite a day of searching.  After ~48 hrs the&amp;lt;br /&amp;gt;
blanks decreased, but remained higher than at the start of the cruise.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;22 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Last night was the first station (16) on the second patch.  I took a sample from the&amp;lt;br /&amp;gt;
underway system to quickly check the strength of ECD signal.  When the sample was run,&amp;lt;br /&amp;gt;
the peak went offscale.  The ECD was set for 2nAmp standing current through station 14.&amp;lt;br /&amp;gt;
I decreased the setting to 1 nAmp.     To span the largest peak from the water analyses&amp;lt;br /&amp;gt;
of station 16, I had to trap 6 regular gas loops (1.606 ml) of the most concentrated&amp;lt;br /&amp;gt;
standard (1109 pptr).  I am concerned about peak shape changes while trapping that many&amp;lt;br /&amp;gt;
loops sequentially, so I put the second gas sample loop valve back on the system.&amp;lt;br /&amp;gt;
[it was taken off during a previous experiment.]  I made a large loop (~7 ml) and created&amp;lt;br /&amp;gt;
new analytical methods to adequately flush the loop while and after filling it with&amp;lt;br /&amp;gt;
standard or blank gas.  I will have to determine the exact volume of the new gas loop&amp;lt;br /&amp;gt;
back at AOML.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;25 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
Try again to locate the source of the elevated blanks, especially the stripper blanks.&amp;lt;br /&amp;gt;
Still, could not find any fitting that leaked.  At the end of a day of analyses,&amp;lt;br /&amp;gt;
the chamber is rinsed with fresh water to reduce the corrosion on the solenoid valves&amp;lt;br /&amp;gt;
attached to the drain and vacuum connections.  I stripped a sample of the fresh water&amp;lt;br /&amp;gt;
on the ship and discovered that it was as concentrated as the surface 'in-patch' water&amp;lt;br /&amp;gt;
(&amp;amp;gt;200 fmole/liter).  The chamber will continue to be rinsed with fresh water, but it&amp;lt;br /&amp;gt;
will go through a couple evacuate-and-purge cycles before being left for the night.&amp;lt;br /&amp;gt;
[no reduction in the blanks developed, but the procedure was continued.]&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;25 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analyses of sample bottles 202 (stn 25, N 3), 206 (stn 25, N 9) and 10&amp;lt;br /&amp;gt;
(stn 26, N 18) the Labview program was in its 'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;26 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottles 203 (stn 27, N 8) the Labview program was in its&amp;lt;br /&amp;gt;
'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;28 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottles 2 (stn 32, submerged pump) the Labview program was&amp;lt;br /&amp;gt;
in its 'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;29 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analyses of sample bottles 2 (stn 35, N 7) and 17 (stn 35, underway system)&amp;lt;br /&amp;gt;
the Labview program was in its 'pause and prompt' state longer than usual.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;30 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During analysis of sample bottles 202 (stn 37, N 6) the Labview program was in its&amp;lt;br /&amp;gt;
'pause and prompt' state longer than usual.    During analysis of sample bottles 206&amp;lt;br /&amp;gt;
(stn 37, N 10) there seemed to be air in the inlet line and the water level in the&amp;lt;br /&amp;gt;
stripping chamber seemed lower than usual.  Maybe the inlet tube was not submerged&amp;lt;br /&amp;gt;
as low as it should have been [but how would the Pt wire water sensors stop the water&amp;lt;br /&amp;gt;
flow automatically - splashes with gas going in?].&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;31 March 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During sampling, the stopper on bottle 203 (stn 41, N 3) was removed ~3 minutes after&amp;lt;br /&amp;gt;
sampling so some more a little more water from the niskin was gently added to the very&amp;lt;br /&amp;gt;
top of the bottle and the stopper reinserted.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;i&amp;gt;03 April 2008&amp;lt;/i&amp;gt;&amp;lt;br /&amp;gt;
During sampling, the stopper on bottle 203 (stn 41, N 3) was removed ~3 minutes after&amp;lt;br /&amp;gt;
sampling so some more a little more water from the niskin was gently added to the very&amp;lt;br /&amp;gt;
top of the bottle and the stopper reinserted.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;For Blanks and Cals See: &amp;lt;/b&amp;gt;&amp;lt;a href=&amp;quot;http://bcodata.whoi.edu/SO-GasEx/MDR_13_discrete_SF6_Blanks_and_Cals.pdf&amp;quot;&amp;gt;SO-GasEx Discrete SF6 Blanks and Calibration Curves&amp;lt;/a&amp;gt;&amp;lt;/p&amp;gt;</gco:CharacterString>
              </gmd:description>
              <gmd:source>
                <gmd:LI_Source>
                  <gmd:sourceCitation>
                    <gmd:CI_Citation>
                      <gmd:title>
                        <gco:CharacterString>Specified by the Principal Investigator(s)</gco:CharacterString>
                      </gmd:title>
                      <gmd:date gco:nilReason="unknown"/>
                    </gmd:CI_Citation>
                  </gmd:sourceCitation>
                </gmd:LI_Source>
              </gmd:source>
            </gmd:LI_ProcessStep>
          </gmd:processStep>
          <gmd:processStep xlink:title="Data Processing Description">
            <gmd:LI_ProcessStep>
              <gmd:description>
                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;lt;b&amp;gt;See: &amp;lt;/b&amp;gt;&amp;lt;a href=&amp;quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Cruise_Report.pdf&amp;quot;&amp;gt;SO-GasEx cruise report, Section 5.3.3 ppgs 19-20&amp;lt;/a&amp;gt; &amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;Data Processing Log  - Post Cruise&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
The first step in the data processing is subtracting the appropriate analytical blank&amp;lt;br /&amp;gt;
from the raw peak areas: gas blank for standard and air analyses, stripper blank for&amp;lt;br /&amp;gt;
the water analyses.  The gas and stripper blanks were plotted and appeared to cluster&amp;lt;br /&amp;gt;
around different values over separate time periods.  This pattern was to be expected&amp;lt;br /&amp;gt;
since there was only one analyst, who typically ran the samples from two casts together.&amp;lt;br /&amp;gt;
Thus, the analytical system was used for ~1/2 a day and then sat unused for ~1/2 a day.&amp;lt;br /&amp;gt;
Nineteen ranges of time were used for blank correction, due primarily to the variability&amp;lt;br /&amp;gt;
of the stripper blanks.  The same gas blank value was applied in sequentially ranges often.&amp;lt;br /&amp;gt;
The applied blank values and a summary of the analytical blank results are provided below.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The analytical blanks showed no systematic trends for all but one range, so a single blank&amp;lt;br /&amp;gt;
value was used for the entire range.  Within one time period, the stripper blank clearly&amp;lt;br /&amp;gt;
increased and then decreased.  Rather than use one value, the applied blank for the water&amp;lt;br /&amp;gt;
analyses was a time-weighted linear interpolation between bracketing analytical stripper&amp;lt;br /&amp;gt;
blanks.  For most of the water and gas analyses, the applied blank was significantly less&amp;lt;br /&amp;gt;
than 1% of the sample signal.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The blank-corrected peak areas for the standard analyses were plotted versus time.  The&amp;lt;br /&amp;gt;
response of the ECD was fairly stable within the setting used for a patch (i.e. 2 nA standing&amp;lt;br /&amp;gt;
current for patch#1; 1 nA standing current for patch#2).  Three time periods were chosen&amp;lt;br /&amp;gt;
for each setting.  Within each time period, a least-squared regression of the standards&amp;lt;br /&amp;gt;
produced a 4th degree polynomial equation relating peak area and femtomole SF6.  The peak&amp;lt;br /&amp;gt;
areas for the seawater analyses were not larger than for the standards; however, there were&amp;lt;br /&amp;gt;
some atypical analyses (e.g. tap water after 26 March) that had peaks larger than the&amp;lt;br /&amp;gt;
standards in that time period.  Since the detector response was similar in the adjoining&amp;lt;br /&amp;gt;
time periods, the data for a couple standard runs were copied to adjoining time periods&amp;lt;br /&amp;gt;
to extend the standard curves for some atypical analyses.    The 4th degree polynomial&amp;lt;br /&amp;gt;
equations were used to convert the blank-corrected peak areas for the water analyses to&amp;lt;br /&amp;gt;
aqueous concentrations (femtomole / liter).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
The results of the water analyses were examined within the context of the surrounding SF6&amp;lt;br /&amp;gt;
analyses, of the titrated oxygen samples, and of the general hydrography.  A quality control&amp;lt;br /&amp;gt;
flag similar to the WOCE protocol were assigned to each water analysis.  There were four&amp;lt;br /&amp;gt;
analyses that were deemed 'bad', two of which had observations during analysis to explain&amp;lt;br /&amp;gt;
the bad result.  There were fifteen analyses that were deemed 'questionable', seven of which&amp;lt;br /&amp;gt;
had observations to explain the poor result.  The remaining 650 seawater analyses were deemed&amp;lt;br /&amp;gt;
'good', though nine analyses had observations that could have explained poor results.  The&amp;lt;br /&amp;gt;
assignment of a 'bad' quality control flag was conservative so that expected results would&amp;lt;br /&amp;gt;
not be excluded from examination by others.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
For the duplicate water samples drawn from niskin bottles, the relative precision was 3.3%&amp;lt;br /&amp;gt;
for all 38 duplicate pairs and was 1.4% for the 31 duplicate pairs definitely above background&amp;lt;br /&amp;gt;
SF6 concentrations (i.e. &amp;amp;gt;8 fmole SF6/Liter).  For the nineteen sets of multiple samples&amp;lt;br /&amp;gt;
collected from the underway sea water line the average precision was 5.3%, which reflects&amp;lt;br /&amp;gt;
analytical variability as well as changes in the water being sampled.    A restrip of a&amp;lt;br /&amp;gt;
concentrated water sample was done on nearly every day.  All 27 restrips of a water sample&amp;lt;br /&amp;gt;
contained 2% or less of the total SF6 extracted from a water sample, so no correction for&amp;lt;br /&amp;gt;
stripping efficiency was done.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;For Blanks and Cals See: &amp;lt;/b&amp;gt;&amp;lt;a href=&amp;quot;http://bcodata.whoi.edu/SO-GasEx/MDR_13_discrete_SF6_Blanks_and_Cals.pdf&amp;quot;&amp;gt;SO-GasEx Discrete SF6 Blanks and Calibration Curves&amp;lt;/a&amp;gt; &amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;BCO-DMO Processing Notes&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
- Generated from original file SO-GasEx08_Disc-SF6_Final.xls, Sheet: stn-nsk&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;BCO-DMO Edits&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
- parameter names modified to conform to BCO-DMO convention&amp;lt;br /&amp;gt;
- event, station, date, time, lon, lat inserted from CTD headers file&amp;lt;br /&amp;gt;
-  blank cells changed to 'nd'&amp;lt;/p&amp;gt;</gco:CharacterString>
              </gmd:description>
              <gmd:source>
                <gmd:LI_Source>
                  <gmd:sourceCitation>
                    <gmd:CI_Citation>
                      <gmd:title>
                        <gco:CharacterString>Specified by the Principal Investigator(s)</gco:CharacterString>
                      </gmd:title>
                      <gmd:date gco:nilReason="unknown"/>
                    </gmd:CI_Citation>
                  </gmd:sourceCitation>
                </gmd:LI_Source>
              </gmd:source>
            </gmd:LI_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
   </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded" codeSpace="009">asNeeded</gmd:MD_MaintenanceFrequencyCode>
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      <gmd:maintenanceNote>
        <gco:CharacterString>7.x-1.1</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
  <gmd:organisationName>
    <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/affiliation/191.rdf" xlink:actuate="onRequest">Biological and Chemical Oceanography Data Management Office (BCO-DMO)</gmx:Anchor>
  </gmd:organisationName>
  <gmd:contactInfo>
    <gmd:CI_Contact>
		  <gmd:phone>
		    <gmd:CI_Telephone>
				  <gmd:voice>
				    <gco:CharacterString>Unavailable</gco:CharacterString>
				  </gmd:voice>
				  <gmd:facsimile>
				    <gco:CharacterString>508-289-2009</gco:CharacterString>
				  </gmd:facsimile>
				</gmd:CI_Telephone>
		  </gmd:phone>
		  <gmd:address>
		    <gmd:CI_Address>
				  <gmd:deliveryPoint>
				    <gco:CharacterString>WHOI MS#36</gco:CharacterString>
				  </gmd:deliveryPoint>
				  <gmd:city>
				    <gco:CharacterString>Woods Hole</gco:CharacterString>
				  </gmd:city>
				  <gmd:administrativeArea>
				    <gco:CharacterString>MA</gco:CharacterString>
				  </gmd:administrativeArea>
				  <gmd:postalCode>
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				  </gmd:postalCode>
				  <gmd:country>
				    <gco:CharacterString>USA</gco:CharacterString>
				  </gmd:country>
				  <gmd:electronicMailAddress>
				    <gco:CharacterString>info@bco-dmo.org</gco:CharacterString>
				  </gmd:electronicMailAddress>
		    </gmd:CI_Address>
		  </gmd:address>
      <gmd:onlineResource>
          <gmd:CI_OnlineResource>
            <gmd:linkage>
              <gmd:URL>http://www.bco-dmo.org</gmd:URL>
            </gmd:linkage>
          </gmd:CI_OnlineResource>
        </gmd:onlineResource>
		  <gmd:hoursOfService>
        <gco:CharacterString>Monday - Friday 8:00am - 5:00pm</gco:CharacterString>
      </gmd:hoursOfService>
		  <gmd:contactInstructions>
		    <gco:CharacterString>For questions regarding this resource, please contact BCO-DMO via the email address provided.</gco:CharacterString>
		  </gmd:contactInstructions>
		</gmd:CI_Contact>
  </gmd:contactInfo>
  <gmd:role>
    <gmd:CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="pointOfContact"  codeSpace="007">pointOfContact</gmd:CI_RoleCode>
  </gmd:role>
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      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation>
    <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/591.rdf" xlink:title="CTD Sea-Bird SBE 911plus" xlink:actuate="onRequest">CTD Seabird 911plus</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>CTD Seabird 911plus</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: CTD Seabird 911plus PI Supplied Instrument Description:Instrument Configuration File for SO-GasEx:
PSA file: C:GasExacqSeasave.psa
Date: 02/23/2008
Instrument configuration file: C:GasExconssec_24_1.con
Configuration report for SBE 911plus/917plus CTD
------------------------------------------------
Frequency channels suppressed : 0
Voltage words suppressed      : 0
Computer interface            : RS-232C
Scans to average              : 1
Surface PAR voltage added     : No
NMEA position data added      : No
Scan time added               : Yes

1) Frequency 0, Temperature
   Serial number : 4211
   Calibrated on : 08-Nov-07
   G             : 4.38706278e-003
   H             : 6.46536683e-004
   I             : 2.23272060e-005
   J             : 1.77872902e-006
   F0            : 1000.000
   Slope         : 1.00000000
   Offset        : 0.0000

2) Frequency 1, Conductivity
   Serial number : 2887
   Calibrated on : 18-Oct-07
   G             : -1.00439325e+001
   H             : 1.36330343e+000
   I             : -2.56289727e-003
   J             : 2.54823008e-004
   CTcor         : 3.2500e-006
   CPcor         : -9.57000000e-008
   Slope         : 1.00000000
   Offset        : 0.00000

3) Frequency 2, Pressure, Digiquartz with TC
   Serial number : 209
   Calibrated on : 09-Jul-07
   C1            : -3.920451e+004
   C2            : 6.234560e-001
   C3            : 1.350570e-002
   D1            : 3.894300e-002
   D2            : 0.000000e+000
   T1            : 3.046303e+001
   T2            : -9.018862e-005
   T3            : 4.528890e-006
   T4            : 3.309590e-009
   T5            : 0.000000e+000
   Slope         : 0.99985000
   Offset        : 1.00090
   AD590M        : 1.144000e-002
   AD590B        : -8.805040e+000

4) Frequency 3, Temperature, 2
   Serial number : 1455
   Calibrated on : 13-Nov-07
   G             : 4.84617647e-003
   H             : 6.77841857e-004
   I             : 2.60561588e-005
   J             : 2.02936086e-006
   F0            : 1000.000
   Slope         : 1.00000000
   Offset        : 0.0000

5) Frequency 4, Conductivity, 2
   Serial number : 2882
   Calibrated on : 18-Oct-07
   G             : -1.02006582e+001
   H             : 1.39961765e+000
   I             : 7.01158866e-004
   J             : 2.20787100e-005
   CTcor         : 3.2500e-006
   CPcor         : -9.57000000e-008
   Slope         : 1.00000000
   Offset        : 0.00000

6) A/D voltage 0, Oxygen, SBE 43
   Serial number : 315
   Calibrated on : 16-Oct-07p
   Equation      : Owens-Millard
   Coefficients for Owens-Millard: 
   Soc           : 3.6150e-001
   Boc           : 0.0000
   Offset        : -0.5838
   Tcor          : -0.0001
   Pcor          : 1.35e-004
   Tau           : 0.0
   Coefficients for Murphy-Larson: 
   Soc           : 0.00000e+000
   Offset        : 0.00000e+000
   A             : 0.00000e+000
   B             : 0.00000e+000
   C             : 0.00000e+000
   E             : 0.00000e+000
   Tau           : 2.00000e+000

7) A/D voltage 1, Free

8) A/D voltage 2, Free

9) A/D voltage 3, User Polynomial
   Serial number : 8756
   Calibrated on : 
   Sensor name   : Metrox
   A0            : 12.00000000
   A1            : 445.60000000
   A2            : 0.00000000
   A3            : 0.00000000

10) A/D voltage 4, Free

11) A/D voltage 5, Free

12) A/D voltage 6, Free

13) A/D voltage 7, Free
---------------------------------------------
Pump Control
   This setting is only applicable to a custom build of the SBE 9plus.
   Enable pump on / pump off commands: NO
---------------------------------------------
Data Acquisition:
   Archive data:                    YES
   Delay archiving:                 NO
   Data archive:                    C:P18_07data
h21731.hex
   Timeout (seconds) at startup:    20
   Timeout (seconds) between scans: 20
---------------------------------------------
Instrument port configuration:
   Port      = COM1
   Baud rate = 19200
   Parity    = N
   Data bits = 8
   Stop bits = 1
---------------------------------------------
Water Sampler Data:
   Water Sampler Type:   SBE Carousel
   Number of bottles:    24
   Port:                 COM2
   Enable remote firing: NO
   Firing sequence:      Sequential
---------------------------------------------
Header information:
   Header Choice = Prompt for Header Information
      prompt 0 = Cruise:  CLIVAR P18 2007
      prompt 1 = Ship:  NOAA RONALD H. BROWN
      prompt 2 = Station/Cast Number:
      prompt 3 = Nominal Latitude:
      prompt 4 = Nominal Longitude:
---------------------------------------------
TCP/IP - port numbers:
   Data acquisition:
      Data port:            49163
      Status port:          49165
      Command port:         49164
   Remote bottle firing:
      Command port:         49167
      Status port:          49168
   Remote data publishing: 
      Converted data port:  49161
      Raw data port:        49160
---------------------------------------------
Miscellaneous data for calculations
   Depth and Average Sound Velocity
      Latitude when NMEA is not available: 0.00000000
   Average Sound Velocity
      Minimum pressure [db]:               20.00000000
      Minimum salinity [psu]:              20.00000000
      Pressure window size [db]:           20.00000000
      Time window size [s]:                60.00000000
   Descent and Acceleration
      Window size [s]:                     2.00000000
   Plume Anomaly
      Theta-B:                             0.00000000
      Salinity-B                           0.00000000
      Theta-Z / Salinity-Z                 0.00000000
      Reference pressure [db]              0.00000000
   Oxygen
      Window size [s]:                     2.00000000
   Potential Temperature Anomaly
      A0:                                  0.00000000
      A1:                                  0.00000000
      A1 Multiplier:                       Salinity
---------------------------------------------
Serial Data Output:
   Output data to serial port: NO
---------------------------------------------
Mark Variables:
   Variables:
   Digits   Variable Name [units]
   ------   ---------------------
   0        Scan Count
   4        Pressure, Digiquartz [db]
   5        Temperature [ITS-90, deg C]
   5        Salinity [PSU]
   4        Oxygen, SBE 43 [umol/Kg]
   5        Density [sigma-theta, Kg/m^3]
---------------------------------------------
Shared File Output:
   Output data to shared file: NO
---------------------------------------------
TCP/IP Output:
   Raw data:
      Output raw data to socket:              NO
      XML wrapper and settings:               NO
      Seconds between raw data updates:       0.00000000
   Converted data:
      Output converted data to socket:        NO
      XML format:                             NO
---------------------------------------------
SBE 11plus Deck Unit Alarms
   Enable minimum pressure alarm:    NO
   Enable maximum pressure alarm:    NO
   Enable altimeter alarm:           NO
---------------------------------------------
SBE 14 Remote Display
   Enable SBE 14 Remote Display:     NO
---------------------------------------------
Options:
   Prompt to save program setup changes: YES
   Automatically save program setup changes on exit: NO
   Confirm instrument configuration change: YES
   Confirm display setup changes: YES
   Confirm output file overwrite: YES
   Check scan length: YES
   Compare serial numbers: YES
   Maximized plot may cover Seasave: NO Instrument Name: CTD Sea-Bird SBE 911plus Instrument Short Name:CTD SBE 911plus   Instrument Description: The Sea-Bird SBE 911 plus is a type of CTD instrument package for continuous measurement of conductivity, temperature and pressure. The SBE 911 plus includes the SBE 9plus Underwater Unit and the SBE 11plus Deck Unit (for real-time readout using conductive wire) for deployment from a vessel. The combination of the SBE 9 plus and SBE 11 plus is called a SBE 911 plus. The SBE 9 plus uses Sea-Bird's standard modular temperature and conductivity sensors (SBE 3 plus and SBE 4). The SBE 9 plus CTD can be configured with up to eight auxiliary sensors to measure other parameters including dissolved oxygen, pH, turbidity, fluorescence, light (PAR), light transmission, etc.). more information from Sea-Bird Electronics Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0058/</gco:CharacterString>
          </gmi:description>
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            <gmi:description>
              <gco:CharacterString>Cruise: RB-08-02</gco:CharacterString>
            </gmi:description>
            <gmi:identifier>
              <gmd:MD_Identifier>
                <gmd:code>
                  <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/deployment/57846.rdf" xlink:title="Cruise" xlink:actuate="onRequest">RB-08-02</gmx:Anchor>
                </gmd:code>
              </gmd:MD_Identifier>
            </gmi:identifier>
            <gmi:status>
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            <gmi:parentOperation gco:nilReason="inapplicable"/>
            <gmi:platform>
  <gmi:MI_Platform>
    <gmi:citation>
     <gmd:CI_Citation>
       <gmd:title>
         <gmx:Anchor xlink:href="http://vocab.nerc.ac.uk/collection/C17/current/33RO" xlink:actuate="onRequest">Community Standard Description</gmx:Anchor>
       </gmd:title>
       <gmd:date gco:nilReason="unknown"/>
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    <gmi:identifier>
      <gmd:MD_Identifier>
        <gmd:authority>
          <gmd:CI_Citation>
            <gmd:title>
              <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/authority/1.rdf" xlink:actuate="onRequest">International Council for the Exploration of the Sea</gmx:Anchor>
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          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54014.rdf"
           xlink:title="33RO" xlink:actuate="onRequest">NOAA Ship Ronald H. Brown</gmx:Anchor>
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    <gmi:description>
      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54014.rdf" xlink:title="NOAA Ship Ronald H. Brown" xlink:actuate="onRequest">vessel</gmx:Anchor>
    </gmi:description>
    <gmi:instrument gco:nilReason="unknown"/>
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