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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/3638.rdf" xlink:actuate="onRequest">Temperature, salinity, dissolved O2, and pH from SeapHOx_Kelp_A, SeapHOx_Kelp_B, SeapHOx_Kelp_C, and SeapHOx_Kelp_D kelp moorings in the La Jolla Kelp Forest, San Diego CA, from 2010-2011 (SeapHOx project)</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Levin, L. A., Martz, T. R. (2013) Temperature, salinity, dissolved O2, and pH from SeapHOx_Kelp_A, SeapHOx_Kelp_B, SeapHOx_Kelp_C, and SeapHOx_Kelp_D kelp moorings in the La Jolla Kelp Forest, San Diego CA, from 2010-2011 (SeapHOx project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 10 October 2013) Version Date 2013-10-10 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/3638 [access date]</gco:CharacterString>
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        <gco:CharacterString>Temperature, Salinity, dissolved O2 and pH from SeapHOx Moorings Dataset Description: &amp;lt;p&amp;gt;These data are from SeapHOx deployments from in and around the La Jolla Kelp Forest and include pH, dissolved oxygen, temperature, and salinity. The data were collected using two &amp;quot;SeapHOx&amp;quot; instrument packages. The SeapHOx consists of a Honeywell Durafet III pH sensor (Martz et al. 2010), an Aanderaa 3835 oxygen optode, and an SBE-37 MicroCAT CTD. The sensors were attached to a mooring line at a given water depth below the surface (e.g. 7 m).&amp;amp;nbsp; There are four moorings utilized in this study and there is one data file which accompanies each mooring.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Related publication:&amp;lt;/strong&amp;gt; Frieder, C. A., Nam, S. H., Martz, T. R., and Levin, L. A.: High temporal and spatial variability of dissolved oxygen and pH in a nearshore California kelp forest, Biogeosciences., 9, 4099-4132, doi:10.5194/bgd-9-4099-2012, 2012.&amp;lt;br /&amp;gt;
&amp;lt;a href=&amp;quot;http://www.biogeosciences.net/9/3917/2012/bg-9-3917-2012.html&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;Abstract Page&amp;lt;/a&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;a href=&amp;quot;http://www.biogeosciences.net/9/3917/2012/bg-9-3917-2012.pdf&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;Manuscript&amp;lt;/a&amp;gt;&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;To calibrate the pH sensors, discrete water samples were taken during each SeapHOx deployment for the determination of total alkalinity (TA) and total dissolved inorganic carbon (DIC). The calibration samples were collected via SCUBA next to the sensor with a 5L niskin bottle. The collected seawater was transferred to a 500 ml clean borosilicate glass bottle with a ground glass neck and stopper. The samples were poisoned with a saturated mercuric chloride solution. TA measurements were determined using an open-cell, potentiometric titration (Dickson et al. 2007).&amp;amp;nbsp; DIC measurements were determined by acid extraction and coulometric detection of CO2 (Dickson et al. 2007). pH was calculated from TA and DIC using the Matlab version of CO2SYS (van Heuven et al. 2011) as recommended by Dickson et al. 2007. The calculated pH at in situ temperature from the calibration sample was used to determine the electrode-specific calibration coefficients. The calibration sample produced a pH accuracy of 0.01 units for each SeapHOx instrument. The oxygen sensors were factory calibrated by Aanderaa and before each deployment a two-point (0% and 100% saturation) offset was applied as recommended in the manual.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;References:&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Martz, T. R., Connery, J. G., and Johnson, K. S.: Testing the Honeywell Durafet® for seawater pH applications, Limnol. Oceanogr. Methods, 8, 172-184, 2010.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Dickson, A. G., Sabine, C. L., and Christian, J. R.: Guide to Best Practices for Ocean CO2 5 Measurements, Vol. 3, 374 PICES Spec. Publ., Sidney, British Columbia, 2007.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;van Heuven et al. 2011. Matlab version of CO2SYS.&amp;lt;/p&amp;gt;</gco:CharacterString>
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&lt;p&gt;The objectives of this study are to measure the impact of key coastal habitats on natural pH variance, and to evaluate the implications these pH regimes have for developing invertebrate larvae. To achieve these objectives the investigators will characterize temporal and spatial carbonate chemistry variability inside and outside kelp forests in San Diego, California. With discrete water samples for the determination of total alkalinity and dissolved inorganic carbon, and continuous autonomous instruments which measure pH, dissolved oxygen, salinity, and temperature, a statistical characterization of carbonate chemistry variability will identify diurnal, seasonal and spatial trends as well as frequencies of maximum variation, rates of change, lowest potential pH (extreme statistics), and biologically-significant thresholds. Subsequently, prominent macrophyte-induced pH regimes will be mimicked in laboratory experiments and incorporated with ocean acidification predictions to test effects of (a) decreased pH, (b) varying pH about the mean, (c) changing variance about mean pH, and (c) pulsed exposure to extreme low pH, on larval survivorship, growth, and calcification responses of multiple species. Together, these laboratory and field studies will offer a mechanistic understanding of the effects of natural variance of carbonate chemistry in the context of ocean acidification for marine invertebrate larvae.&lt;/p&gt;
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	Name: Mooring_Id
	Units: text
	Description: &lt;p&gt;Mooring Id&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27280.rdf
	Name: Longitude
	Units: decimal degrees
	Description: &lt;p&gt;Mooring Longitude Position (West is negative)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27281.rdf
	Name: Latitude
	Units: decimal degrees
	Description: &lt;p&gt;Mooring Latitude Position (South is negative)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27282.rdf
	Name: Start_Date
	Units: YYYYMMDD
	Description: &lt;p&gt;Start Date of Data Collection&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27283.rdf
	Name: End_Date
	Units: YYYYMMDD
	Description: &lt;p&gt;End Date of Data Collection&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27284.rdf
	Name: Site_Description
	Units: text
	Description: &lt;p&gt;Site description of mooring&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27285.rdf
	Name: Water_Depth
	Units: meters
	Description: &lt;p&gt;Depth of water.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27286.rdf
	Name: Sensor_ID
	Units: text
	Description: &lt;p&gt;There are two sensors - SP001 and SP002&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27287.rdf
	Name: Deployment_No
	Units: text
	Description: &lt;p&gt;The deployment number of the respective sensor&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27288.rdf
	Name: Date
	Units: YYYYMMDD
	Description: &lt;p&gt;Date (UTC)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27289.rdf
	Name: Time
	Units: HHMM
	Description: &lt;p&gt;Time (UTC)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27290.rdf
	Name: Temperature
	Units: degrees Celsius
	Description: &lt;p&gt;Temperature from SBE-37 MicroCAT&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27291.rdf
	Name: Salinity
	Units: PSU
	Description: &lt;p&gt;Salinity from SBE-37 MicroCAT&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27292.rdf
	Name: Oxygen
	Units: micro mole/kg
	Description: &lt;p&gt;Oxygen&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/27293.rdf
	Name: pH
	Units: dimensionless
	Description: &lt;p&gt;pH (total hydrogen scale)&lt;/p&gt; 
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				    <gco:CharacterString>02543</gco:CharacterString>
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				    <gco:CharacterString>USA</gco:CharacterString>
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				    <gco:CharacterString>info@bco-dmo.org</gco:CharacterString>
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		    <gco:CharacterString>For questions regarding this resource, please contact BCO-DMO via the email address provided.</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;To calibrate the pH sensors, discrete water samples were taken during each SeapHOx deployment for the determination of total alkalinity (TA) and total dissolved inorganic carbon (DIC). The calibration samples were collected via SCUBA next to the sensor with a 5L niskin bottle. The collected seawater was transferred to a 500 ml clean borosilicate glass bottle with a ground glass neck and stopper. The samples were poisoned with a saturated mercuric chloride solution. TA measurements were determined using an open-cell, potentiometric titration (Dickson et al. 2007).&amp;amp;nbsp; DIC measurements were determined by acid extraction and coulometric detection of CO2 (Dickson et al. 2007). pH was calculated from TA and DIC using the Matlab version of CO2SYS (van Heuven et al. 2011) as recommended by Dickson et al. 2007. The calculated pH at in situ temperature from the calibration sample was used to determine the electrode-specific calibration coefficients. The calibration sample produced a pH accuracy of 0.01 units for each SeapHOx instrument. The oxygen sensors were factory calibrated by Aanderaa and before each deployment a two-point (0% and 100% saturation) offset was applied as recommended in the manual.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;References:&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Martz, T. R., Connery, J. G., and Johnson, K. S.: Testing the Honeywell Durafet® for seawater pH applications, Limnol. Oceanogr. Methods, 8, 172-184, 2010.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Dickson, A. G., Sabine, C. L., and Christian, J. R.: Guide to Best Practices for Ocean CO2 5 Measurements, Vol. 3, 374 PICES Spec. Publ., Sidney, British Columbia, 2007.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;van Heuven et al. 2011. Matlab version of CO2SYS.&amp;lt;/p&amp;gt;</gco:CharacterString>
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                      <gmd:date gco:nilReason="unknown"/>
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                <gco:CharacterString>&amp;lt;p&amp;gt;Extreme salinity outliers (= 3 SD) were removed and salinity data was smoothed with a 1-hr moving average. Oxygen was logged with factory settings. This assumes a salinity of 0 and pressure of 0. Salinity corrections (from CTD data) and pressure corrections (water depth) were applied to the oxygen data as suggested by the manufacturer’s manual. pH was calculated at in situ temperature (temperature data from CTD) using calibration coefficients as described above.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;BCO-DMO Processing Notes&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Generated from original files &amp;quot;SeapOHx_Mooring [A-D].txt&amp;quot; contributed by Christina Frieder&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;BCO-DMO Edits&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
- Time column spilt into Date and Time and reformatted as YYYYMMDD and HHMM&amp;lt;br /&amp;gt;
- Temp, Sal, O2 and pH data values reported to appropriate decimal places&amp;lt;br /&amp;gt;
- &amp;quot;NaN&amp;quot; values converted to &amp;quot;nd&amp;quot; (no data)&amp;lt;br /&amp;gt;
- Parameter names modified to conform to BCO-DMO convention&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;lt;/p&amp;gt;</gco:CharacterString>
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				    <gco:CharacterString>02543</gco:CharacterString>
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				    <gco:CharacterString>info@bco-dmo.org</gco:CharacterString>
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                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/563.rdf" xlink:title="Aanderaa Oxygen Optodes" xlink:actuate="onRequest">Aanderaa 3835 Oxygen Optode</gmx:Anchor>
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          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: Aanderaa 3835 Oxygen Optode PI Supplied Instrument Description:The SeapHOx consists of a Honeywell Durafet III pH sensor (Martz et al.  2010), an Aanderaa 3835 oxygen optode, and an SBE-37 MicroCAT CTD. The  sensors were attached to a mooring line at a given water depth below the  surface (e.g. 7 m). Instrument Name: Aanderaa Oxygen Optodes Instrument Short Name:AOO   Instrument Description: Aanderaa Oxygen Optodes are instrument for monitoring oxygen in the environment. For instrument information see the Aanderaa Oxygen Optodes Product Brochure. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/351/</gco:CharacterString>
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      <gmi:instrument>
        <gmi:MI_Instrument>
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              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/478.rdf" xlink:title="CTD Sea-Bird MicroCAT 37" xlink:actuate="onRequest">CTD Sea-Bird MicroCAT 37</gmx:Anchor>
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            <gco:CharacterString>PI Supplied Instrument Name: CTD Sea-Bird MicroCAT 37 PI Supplied Instrument Description:The SeapHOx consists of a Honeywell Durafet III pH sensor (Martz et al.  2010), an Aanderaa 3835 oxygen optode, and an SBE-37 MicroCAT CTD. The  sensors were attached to a mooring line at a given water depth below the  surface (e.g. 7 m). Instrument Name: CTD Sea-Bird MicroCAT 37 Instrument Short Name:CTD MicroCAT 37   Instrument Description: The Sea-Bird MicroCAT CTD unit is a high-accuracy conductivity and temperature recorder based on the Sea-Bird SBE 37 MicroCAT series of products.  It can be configured with optional pressure sensor, internal batteries, memory, built-in Inductive Modem, integral Pump, and/or SBE-43 Integrated Dissolved Oxygen sensor. Constructed of titanium and other non-corroding materials for long life with minimal maintenance, the MicroCAT is designed for long duration on moorings.  

In a typical mooring, a modem module housed in the buoy communicates with underwater instruments and is interfaced to a computer or data logger via serial port. The computer or data logger is programmed to poll each instrument on the mooring for its data, and send the data to a telemetry transmitter (satellite link, cell phone, RF modem, etc.). The MicroCAT saves data in memory for upload after recovery, providing a data backup if real-time telemetry is interrupted. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/350/</gco:CharacterString>
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              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/674.rdf" xlink:title="pH Sensor" xlink:actuate="onRequest">Honeywell Durafet III pH sensor</gmx:Anchor>
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            <gco:CharacterString>PI Supplied Instrument Name: Honeywell Durafet III pH sensor PI Supplied Instrument Description:The SeapHOx consists of a Honeywell Durafet III pH sensor (Martz et al.  2010), an Aanderaa 3835 oxygen optode, and an SBE-37 MicroCAT CTD. The  sensors were attached to a mooring line at a given water depth below the  surface (e.g. 7 m).
Honeywell Durafet III pH sensor Instrument Name: pH Sensor Instrument Short Name:pH Sensor   Instrument Description: An instrument that measures the hydrogen ion activity in solutions.

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