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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/4059.rdf" xlink:actuate="onRequest">Underway O2 Argon (Ar) from NOAA Ship Ronald H. Brown cruise RB-08-02 in the Southwest Atlantic sector of the Southern Ocean near South Georgia Island in 2008 (SO_GasEx project)</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Hamme, R. C., Cassar, N., Bender, M. L. (2013) Underway O2 Argon (Ar) from NOAA Ship Ronald H. Brown cruise RB-08-02 in the Southwest Atlantic sector of the Southern Ocean near South Georgia Island in 2008 (SO_GasEx project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 14 October 2013) Version Date 2013-10-14 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/4059 [access date]</gco:CharacterString>
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        <gco:CharacterString>Underway O2 Ar Dataset Description: &amp;lt;p&amp;gt;&amp;lt;b&amp;gt;Dataset Description:&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
Final Underway Oxygen/Argon, Oxygen concentration, and associated productivity calculations&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
&amp;lt;b&amp;gt;Operation Description:&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
Continuous analysis of oxygen/argon ratios by equilibrator inlet mass spectrometry (EIMS) and oxygen concentrations by optode on the underway seawater line.&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;b&amp;gt;Overall Sampling Strategy:&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
Plan was to collect mass spectrometry and optode data continuously from the underway seawater system, except for tracer injection and brief service intervals.&amp;amp;nbsp; Calibration was to be performed vs. discrete samples from the surface on every CTD cast and from the underway system at other times to create a calibration point ever 6-12 hours.&amp;lt;/p&amp;gt;
&amp;lt;p&amp;gt;&amp;lt;b&amp;gt;Continuous Sample Collection:&amp;lt;/b&amp;gt;&amp;lt;br /&amp;gt;
Flow of seawater to the EIMS and optode was controlled by a small ball valve to about 3-5 L/min.&amp;amp;nbsp; Seawater flowed through a coarse filter and into a 1L plastic graduated cylinder.&amp;amp;nbsp; A flow of 100mL/min was withdrawn from the graduated cylinder through a fine sock-shaped filter using a small pump.&amp;amp;nbsp; The rest of the seawater flow exited through holes in the side of the graduated cylinder into a bucket the cylinder was immersed in.&amp;amp;nbsp; This bucket drained from its halfway point to a sink draining directly into the sea.&amp;amp;nbsp; The smaller flow was pumped through a small Liquicel equilibrator cartridge and then through a flow meter and finally discharged to the bucket.&amp;amp;nbsp; The equilibrator cartridge was immersed in the bucket to provide temperature stabilization.&amp;amp;nbsp; A capillary picked off gas from the equilibrator cartrige and sent it through a valco switching valve to the quadrupole mass spectrometer for analysis.&amp;amp;nbsp; The switching valve allowed for direct sampling of lab air by a second capillary of similar length.&amp;amp;nbsp; The optode was immersed at the top of the graduated cylinder near the overflow holes.&amp;amp;nbsp; Seven thermistors measured water and air temperatures.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/55043.rdf" xlink:title="unknown SO_GasEx NOAA" xlink:actuate="onRequest">Funding provided by National Oceanic and Atmospheric Administration (NOAA) Award Number: unknown SO_GasEx NOAA</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/55070.rdf" xlink:title="PLR-0636744" xlink:actuate="onRequest">Funding provided by NSF Antarctic Sciences (NSF ANT) Award Number: PLR-0636744 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=0636744</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/55078.rdf" xlink:title="NNX08AF12G" xlink:actuate="onRequest">Funding provided by National Aeronautics &amp; Space Administration (NASA) Award Number: NNX08AF12G</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/55213.rdf" xlink:title="328290-2006" xlink:actuate="onRequest">Funding provided by National Sciences and Engineering Research Council of Canada (NSERC) Award Number: 328290-2006 Award URL: http://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=332959</gmx:Anchor>
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Â» International SOLAS Web site
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&lt;li&gt;How do other non-direct wind effects influence gas transfer?&lt;/li&gt;
&lt;li&gt;How do changing pCO2 and DMS levels affect the air-sea CO2 and DMS flux, respectively in the same locale?&lt;/li&gt;
&lt;li&gt;Are there better predictors of gas exchange in the Southern Ocean other than wind?&lt;/li&gt;
&lt;li&gt;What is the near surface horizontal and vertical variability in turbulence, pCO2, and other relevant biochemical and physical parameters?&lt;/li&gt;
&lt;li&gt;How do biological processes influence pCO2 and gas exchange?&lt;/li&gt;
&lt;li&gt;Do the different disparate estimates of fluxes agree, and if not why?&lt;/li&gt;
&lt;li&gt;With the results from Southern Ocean GasEx, can we reconcile the current discrepancy between model based CO2 flux estimates and observation based estimates?&lt;/li&gt;
&lt;/ul&gt;
&lt;p&gt; &lt;/p&gt;
&lt;h3&gt;Related files&lt;/h3&gt;
&lt;p&gt;&lt;a href=&quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Cruise_Report.pdf&quot;&gt;SO-GasEx cruise report&lt;/a&gt;&lt;br /&gt;
&lt;a href=&quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Science_Plan.pdf&quot;&gt;SO-GasEx Science Plan&lt;/a&gt;&lt;br /&gt;
&lt;a href=&quot;http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Implementation_Plan.pdf&quot;&gt;SO-GasEx Implementation Plan&lt;/a&gt;&lt;/p&gt;
&lt;p&gt;The SO-GasEx cruise report and Science and Implementation plans, may also be available at &lt;a href=&quot;http://so-gasex.org/science.html&quot; target=&quot;_blank&amp;quot;&quot;&gt;the SO-GasEx science Web page&lt;/a&gt;.&lt;/p&gt;</gco:CharacterString>
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O2/Ar ion currents during each 10-min air standard sampling were averaged together and then interpolated to each water sample time.  O2/Ar sat was calculated as the ratio of the ion current for the equilibrator divided by that for the air standard (minus one, and times 100). Data was then binned on one-minute intervals. O2/Ar saturations were corrected for observed offsets from the discrete samples based on an average offset derived for each equilibrator. Optode O2 values were calibrated against discrete O2 detemined by Winkler titration following Uchida et al. (2008).  Note that timestamp is only accurate within ~2 minutes as computer clock drifted badly and had to be continually reset to ship's timeserver.  Net community oxygen production is calculated from the O2/Arsat data, T, S, and a weighted gas exchange rate.  This value approximates the NOP of the mixed layer over 10 days prior to the measurement of O2/Ar.   For gas exchnage, we use the Reuer et al. (2007) wind speed weighting over 60 days prior to the measurement using combined QuikSCAT/NCEP wind speeds and the Ho et al. (2006) gas exchange parameterization.  For more details see Hamme, R. C., et al. (2012), Dissolved O2/Ar and other methods reveal rapid changes in productivity during a Lagrangian experiment in the Southern Ocean, J. Geophys. Res., 117, C00F12, doi:10.1029/2011JC007046.&amp;lt;/p&amp;gt;
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                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/724.rdf" xlink:title="Equilibrator Inlet Mass Spectrometer" xlink:actuate="onRequest">Equilibrator Inlet Mass Spectrometer</gmx:Anchor>
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            <gco:CharacterString>PI Supplied Instrument Name: Equilibrator Inlet Mass Spectrometer PI Supplied Instrument Description:Continuous analysis of oxygen/argon ratios by equilibrator inlet mass spectrometry (EIMS)
Liquicel equilibrator cartridge - Equilibrator cartridge is Membrana  LiquiCel MicroModule G569 with flow-through water but only one air-side  inlet/outlet. Instrument Name: Equilibrator Inlet Mass Spectrometer Instrument Short Name:EIMS   Instrument Description: Cassar N, Barnett BA, Bender ML, Kaiser J, Hamme RC, Tilbrook B., Continuous high-frequency dissolved O2/Ar measurements by equilibrator inlet mass spectrometry. Anal Chem. 2009 Mar 1;81(5):1855-64. doi: 10.1021/ac802300u. 

Source: Department of Geosciences, Princeton University, Princeton, New Jersey 08544, USA. ncassar@princeton.edu

Abstract
The oxygen (O(2)) concentration in the surface ocean is influenced by biological and physical processes. With concurrent measurements of argon (Ar), which has similar solubility properties as oxygen, we can remove the physical contribution to O(2) supersaturation and determine the biological oxygen supersaturation. Biological O(2) supersaturation in the surface ocean reflects the net metabolic balance between photosynthesis and respiration, i.e., the net community productivity (NCP). We present a new method for continuous shipboard measurements of O(2)/Ar by equilibrator inlet mass spectrometry (EIMS). From these measurements and an appropriate gas exchange parametrization, NCP can be estimated at high spatial and temporal resolution. In the EIMS configuration, seawater from the ship's continuous intake flows through a cartridge enclosing a gas-permeable microporous membrane contactor. Gases in the headspace of the cartridge equilibrate with dissolved gases in the flowing seawater. A fused-silica capillary continuously samples headspace gases, and the O(2)/Ar ratio is measured by mass spectrometry. The ion current measurements on the mass spectrometer reflect the partial pressures of dissolved gases in the water flowing through the equilibrator. Calibration of the O(2)/Ar ion current ratio (32/40) is performed automatically every 2 h by sampling ambient air through a second capillary. A conceptual model demonstrates that the ratio of gases reaching the mass spectrometer is dependent on several parameters, such as the differences in molecular diffusivities and solubilities of the gases. Laboratory experiments and field observations performed by EIMS are discussed. We also present preliminary evidence that other gas measurements, such as N(2)/Ar and pCO(2) measurements, may potentially be performed with EIMS. Finally, we compare the characteristics of the EIMS with the previously described membrane inlet mass spectrometry (MIMS) approach.

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Thermistors differ from resistance temperature detectors (RTD) in that the material used in a thermistor is generally a ceramic or polymer, while RTDs use pure metals. The temperature response is also different; RTDs are useful over larger temperature ranges, while thermistors typically achieve a higher precision within a limited temperature range, typically 90C to 130C.</gco:CharacterString>
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                          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/person/50843.rdf" xlink:actuate="onRequest">Christopher L. Sabine</gmx:Anchor>
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                                <gmd:URL>http://bcodata.whoi.edu/SO-GasEx/SO_GasEx_Cruise_Report.pdf</gmd:URL>
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