http://lod.bco-dmo.org/id/dataset/522939
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2014-08-13
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
Experimental seawater chemical properties for larval mussel shell study from SIO, UCSD from 2012-2013 (OA_Proxies project)
2014-08-14
publication
2014-08-14
revision
Marine Biological Laboratory/Woods Hole Oceanographic Institution Library (MBLWHOI DLA)
2020-10-01
publication
https://doi.org/10.26008/1912/bco-dmo.522939.1
Lisa A. Levin
University of California-San Diego Scripps
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
Cite this dataset as: Levin, L. A. (2020) Experimental seawater chemical properties for larval mussel shell study from SIO, UCSD from 2012-2013 (OA_Proxies project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2014-08-14 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.522939.1 [access date]
Experimental seawater chemical properties for larval mussel shell study Dataset Description: <p>Experimental seawater chemical properties for larval mussel shell study from SIO, UCSD from 2012 and 2013. This table has been modified from tables in Frieder et al. 2014 GCB and Frieder et al. 2014 ES&amp;T; see those publications for additional corresponding salinity and other carbonate chemistry variables.</p> Methods and Sampling: <p>Mass flow controllers were used to deliver a gas mixture of N2, O2, and CO2 to gas membrane contactors (Liqui-Cel Part No. G501), which in turn delivered the gas mixture to the seawater to maintain the desired CO2 and O2 concentrations in each treatment replicate (Bockmon et al. 2013, Biogeosciences).</p>
<p>A pH sensor (Honeywell Durafet III) and Aanderaa oxygen optode were used to continuously record from one replicate per treatment, per day. Along with daily discrete samples measured for pH and [O2], this sensor monitoring confirmed the stability of conditions, with the average offset of replicates to be 0.01 pH units and 3µmol O2 kg-1 (Frieder et al. 2014, GCB). Discrete pH measurements were determined spectrophotometrically and the discrete [O2] values were determined using a Winkler Titration method (as described in Frieder et al. 2014, GCB).</p>
<p>Discrete samples were taken at the beginning and end of each experiment for the determination of total alkalinity and salinity. Total alkalinity measurements were determined using an open-cell, potentiometric titration with an accuracy of +- 2 µmol kg-1 (Dickson et al., 2007). Salinity was calculated from density measured at 20°C on a Density Meter (Mettler Toledo DE45) with an accuracy of 0.05 salinity units. HOBO Pendant temperature data loggers with an accuracy of +-0.5°C continuously measured temperature every 5 min in all replicates.</p>
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1401349 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1401349
completed
Lisa A. Levin
University of California-San Diego Scripps
858-534-3579
9500 Gilman Drive Mail Code: 0218
La Jolla
CA
92093-0218
USA
llevin@ucsd.edu
pointOfContact
asNeeded
Dataset Version: 1
Unknown
date
species
exp_id
treatment
pH
O2
temp
AT
sal
pCO2
omega_ar
omega_calc
CO3
AOO
density meter
ICP Mass Spec
MFC
pH Sensor
Water Temp Sensor
theme
None, User defined
date
species scientific name (binomial)
experiment id
treatment
pH
dissolved Oxygen
water temperature at measurement depth
total alkalinity (TA)
salinity
Partial pressure of CO2
Aragonite Saturation State
Calcite Saturation State
Carbonate concentration [CO3]2-
featureType
BCO-DMO Standard Parameters
Aanderaa Oxygen Optodes
density meter
Inductively Coupled Plasma Mass Spectrometer
Mass Flow Controller
pH Sensor
Water Temperature Sensor
instrument
BCO-DMO Standard Instruments
Levin_mussels
service
Deployment Activity
Kaplan Experimental Aquarium at Scripps Institution of Oceanography, UCSD
place
Locations
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
Science, Engineering and Education for Sustainability NSF-Wide Investment (SEES): Ocean Acidification (formerly CRI-OA)
https://www.nsf.gov/funding/pgm_summ.jsp?pims_id=503477
Science, Engineering and Education for Sustainability NSF-Wide Investment (SEES): Ocean Acidification (formerly CRI-OA)
NSF Climate Research Investment (CRI) activities that were initiated in 2010 are now included under Science, Engineering and Education for Sustainability NSF-Wide Investment (SEES). SEES is a portfolio of activities that highlights NSF's unique role in helping society address the challenge(s) of achieving sustainability. Detailed information about the SEES program is available from NSF (https://www.nsf.gov/funding/pgm_summ.jsp?pims_id=504707).
In recognition of the need for basic research concerning the nature, extent and impact of ocean acidification on oceanic environments in the past, present and future, the goal of the SEES: OA program is to understand (a) the chemistry and physical chemistry of ocean acidification; (b) how ocean acidification interacts with processes at the organismal level; and (c) how the earth system history informs our understanding of the effects of ocean acidification on the present day and future ocean.
Solicitations issued under this program:
NSF 10-530, FY 2010-FY2011
NSF 12-500, FY 2012
NSF 12-600, FY 2013
NSF 13-586, FY 2014
NSF 13-586 was the final solicitation that will be released for this program.
PI Meetings:
1st U.S. Ocean Acidification PI Meeting(March 22-24, 2011, Woods Hole, MA)
2nd U.S. Ocean Acidification PI Meeting(Sept. 18-20, 2013, Washington, DC)
3rd U.S. Ocean Acidification PI Meeting (June 9-11, 2015, Woods Hole, MA – Tentative)
NSF media releases for the Ocean Acidification Program:
Press Release 10-186 NSF Awards Grants to Study Effects of Ocean Acidification
Discovery Blue Mussels "Hang On" Along Rocky Shores: For How Long?
Discovery nsf.gov - National Science Foundation (NSF) Discoveries - Trouble in Paradise: Ocean Acidification This Way Comes - US National Science Foundation (NSF)
Press Release 12-179 nsf.gov - National Science Foundation (NSF) News - Ocean Acidification: Finding New Answers Through National Science Foundation Research Grants - US National Science Foundation (NSF)
Press Release 13-102 World Oceans Month Brings Mixed News for Oysters
Press Release 13-108 nsf.gov - National Science Foundation (NSF) News - Natural Underwater Springs Show How Coral Reefs Respond to Ocean Acidification - US National Science Foundation (NSF)
Press Release 13-148 Ocean acidification: Making new discoveries through National Science Foundation research grants
Press Release 13-148 - Video nsf.gov - News - Video - NSF Ocean Sciences Division Director David Conover answers questions about ocean acidification. - US National Science Foundation (NSF)
Press Release 14-010 nsf.gov - National Science Foundation (NSF) News - Palau's coral reefs surprisingly resistant to ocean acidification - US National Science Foundation (NSF)
Press Release 14-116 nsf.gov - National Science Foundation (NSF) News - Ocean Acidification: NSF awards $11.4 million in new grants to study effects on marine ecosystems - US National Science Foundation (NSF)
SEES-OA
largerWorkCitation
program
Development of geochemical proxies to evaluate larval pH-exposure history
https://osprey.bco-dmo.org/project/2212
Development of geochemical proxies to evaluate larval pH-exposure history
<p>This research is funded as part of NSF CRI Ocean Acidification Category 2. The investigators will develop a new interdisciplinary partnership between connectivity ecology (Levin at SIO), metal isotope geochemistry (Anbar and Gordon at ASU), and paleoclimatology (Herrmann at ASU/LSU) to identify new proxies for ocean acidification that can be used to assess pH exposures in living organisms and, potentially to interpret the geologic record. The investigators hypothesize that the isotopic composition of larval calcium carbonates reflects changes in seawater chemistry driven by ocean acidification and, in some instances, with associated decline in oxygen levels. The large extent to which these two parameters vary in concert in the modern and past ocean (and thus have joint influence), and the extent to which they may be uncoupled by anthropogenic CO2 inputs, merits considerable attention. Thus, the integration of pH and oxygen in proxy development would be an important advance.</p>
<p>The focus of this project is on proxy development to determine pH exposure history for living organisms in their larval state, and will center on calcium, boron, and uranium isotopes as well as multi-elemental fingerprints. For this project, the investigators will target open coast, front bay and backbay mytilid mussel species, each living naturally under a different pH regime, and statoliths of encapsulated market squid larvae from the open shelf. Larvae with known pH, oxygen and temperature exposure histories will be obtained from (1) laboratory larval rearing experiments that manipulate pH and oxygen and (2) in situ out planting of lab-spawned larvae in larval homes onto existing moorings where pH, T and oxygen are being monitored. Analyses will employ SIMS (for del 11B), multicollector (for del 44Ca, del 238 U), and laser ablation ICP-MS (targeting B, Cu, U, Pb, Mo, and a suite of additional pH- and redox-sensitive trace elements). Multivariate statistical tools will define ability to detect pH-induced signatures and to determine species or taxon-specific vital effects. The investigators are exploring proxies for invertebrate larvae that are untested in the context of acidification geochemistry. Targeting larvae is critical as many marine organisms produce larval carbonate structures and these stages may be most affected by ocean acidification. The retention of larval shell and statoliths after recruitment may ultimately allow us to test the importance of larval pH and O2 exposure to survival and population persistence. An ability to assess past exposures through geochemical proxies will provide information about relative pH tolerances and ecosystem-level change in response to changes in the ocean's carbonate chemistry.</p>
<p><strong>NOTE</strong>: A series of laboratory experiments were run in which <em>Mytilus</em> spp. larvae (<em>Mytilus californianus</em> and <em>Mytilus galloprovincialis</em>) and <em>Doryteuthis opalescens</em> (market squid) embryos were reared under controlled temperature, pH and oxygen conditions. Experimental conditions are given in <a href="http://bcodata.whoi.edu/OA_Proxy_Development/BCO-DMO_Table1_Experimental_Seawater_Conditions_Mussels_v2_2014-08-27.jpg" target="_blank">Table 1</a> (for mussel larvae) and <a href="http://bcodata.whoi.edu/OA_Proxy_Development/Table2_Levin_OCE1041062.pdf" target="_blank">Table 2</a> (for squid embryos). Geochemistry data in the form of Metal:Ca ratios for mussels has been uploaded to BCO-DMO as "Mussel shell trace element ratios" and squid statolith geochemistry data are available on request.</p>
OA_Proxies
largerWorkCitation
project
eng; USA
oceans
Kaplan Experimental Aquarium at Scripps Institution of Oceanography, UCSD
-119.842
-117.203
32.725
34.4128
2012-05-05
2013-01-23
Southern California, 32 N 117 W
0
BCO-DMO catalogue of parameters from Experimental seawater chemical properties for larval mussel shell study from SIO, UCSD from 2012-2013 (OA_Proxies project)
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/522963.rdf
Name: date
Units: yyyy/mm/dd
Description: <p>date of analysis</p>
http://lod.bco-dmo.org/id/dataset-parameter/522964.rdf
Name: species
Units: unitless
Description: <p>taxonomic name of experimental species</p>
http://lod.bco-dmo.org/id/dataset-parameter/522965.rdf
Name: exp_id
Units: unitless
Description: <p>experiment code: A = high pH/high O2 = high pHOx; B = low pH/low O2 = low; pHOx; C = high pH/low O2; D = low pH/high O2</p>
http://lod.bco-dmo.org/id/dataset-parameter/522966.rdf
Name: treatment
Units: unitless
Description: <p>high and low pH and oxygen concentration</p>
http://lod.bco-dmo.org/id/dataset-parameter/522967.rdf
Name: pH
Units: pH scale
Description: <p>pH: The measure of the acidity or basicity of an aqueous solution</p>
http://lod.bco-dmo.org/id/dataset-parameter/522968.rdf
Name: O2
Units: mol kg-1
Description: <p>dissolved oxygen concentration</p>
http://lod.bco-dmo.org/id/dataset-parameter/522969.rdf
Name: temp
Units: degrees Celsius
Description: <p>temperature</p>
http://lod.bco-dmo.org/id/dataset-parameter/522971.rdf
Name: AT
Units: mol kg-1
Description: <p>total alkalinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/522972.rdf
Name: sal
Units: unitless
Description: <p>salinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/522973.rdf
Name: pCO2
Units: micro-atmospheres
Description: <p>partial pressure of carbon dioxide for each treatment; CO2 treatments are ambient vs. elevated (45 vs 85 Pa pCO2)</p>
http://lod.bco-dmo.org/id/dataset-parameter/522974.rdf
Name: omega_ar
Units: unitless
Description: <p>aragonite saturation state</p>
http://lod.bco-dmo.org/id/dataset-parameter/522975.rdf
Name: omega_calc
Units: unitless
Description: <p>calcite saturation state</p>
http://lod.bco-dmo.org/id/dataset-parameter/522976.rdf
Name: CO3
Units: mol kg-1
Description: <p>concentration of carbonate ion ([CO3]2-) in seawater</p>
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2127
https://darchive.mblwhoilibrary.org/bitstream/1912/26263/1/dataset-522939_experimental-seawater-chemistry__v1.tsv
download
https://doi.org/10.26008/1912/bco-dmo.522939.1
download
onLine
dataset
<p>Mass flow controllers were used to deliver a gas mixture of N2, O2, and CO2 to gas membrane contactors (Liqui-Cel Part No. G501), which in turn delivered the gas mixture to the seawater to maintain the desired CO2 and O2 concentrations in each treatment replicate (Bockmon et al. 2013, Biogeosciences).</p>
<p>A pH sensor (Honeywell Durafet III) and Aanderaa oxygen optode were used to continuously record from one replicate per treatment, per day. Along with daily discrete samples measured for pH and [O2], this sensor monitoring confirmed the stability of conditions, with the average offset of replicates to be 0.01 pH units and 3µmol O2 kg-1 (Frieder et al. 2014, GCB). Discrete pH measurements were determined spectrophotometrically and the discrete [O2] values were determined using a Winkler Titration method (as described in Frieder et al. 2014, GCB).</p>
<p>Discrete samples were taken at the beginning and end of each experiment for the determination of total alkalinity and salinity. Total alkalinity measurements were determined using an open-cell, potentiometric titration with an accuracy of +- 2 µmol kg-1 (Dickson et al., 2007). Salinity was calculated from density measured at 20°C on a Density Meter (Mettler Toledo DE45) with an accuracy of 0.05 salinity units. HOBO Pendant temperature data loggers with an accuracy of +-0.5°C continuously measured temperature every 5 min in all replicates.</p>
Specified by the Principal Investigator(s)
<p><strong>BCO-DMO Processing Notes:</strong><br />
- data submitted in Excel file "Levin_BCO-DMO Table 1. Experimental Seawater Conditions - Mussels.xlsx" sheet "Seawater conditions" extracted to tsv<br />
- added conventional header with dataset name, PI name, version date<br />
- modified parameter names to conform with BCO-DMO naming conventions<br />
- removed special characters<br />
- replaced / with -; replaced space with _<br />
- reordered columns</p>
Specified by the Principal Investigator(s)
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
AOO
AOO
PI Supplied Instrument Name: AOO Instrument Name: Aanderaa Oxygen Optodes Instrument Short Name:AOO Instrument Description: Aanderaa Oxygen Optodes are instrument for monitoring oxygen in the environment. For instrument information see the Aanderaa Oxygen Optodes Product Brochure. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/351/
density meter
density meter
PI Supplied Instrument Name: density meter PI Supplied Instrument Description:Mettler Toledo DE45, accuracy of +-0.5 °C. Instrument Name: density meter Instrument Short Name:density meter Instrument Description: Portable or bench-top instruments to measure density of liquids. [lab]
ICP Mass Spec
ICP Mass Spec
PI Supplied Instrument Name: ICP Mass Spec PI Supplied Instrument Description:LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry): Thermo Element 2 single-collector
ICP-MS operating in low-resolution mode with a New Wave Research UP-213 laser ablation unit (at the University of
California Santa Barbara). Instrument Name: Inductively Coupled Plasma Mass Spectrometer Instrument Short Name:ICP Mass Spec Instrument Description: An ICP Mass Spec is an instrument that passes nebulized samples into an inductively-coupled gas plasma (8-10000 K) where they are atomized and ionized. Ions of specific mass-to-charge ratios are quantified in a quadrupole mass spectrometer. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB15/
MFC
MFC
PI Supplied Instrument Name: MFC PI Supplied Instrument Description:Omega® mass flow controllers (N2: FMA 5418 0–5 SLM; O2: FMA 5411 0–2 SLM; and CO2: FMA 5402 0–10 sccm). See Bockman (2013) for further details. Instrument Name: Mass Flow Controller Instrument Short Name:MFC Instrument Description: Mass Flow Controller (MFC) - A device used to measure and control the flow of fluids and gases
pH Sensor
pH Sensor
PI Supplied Instrument Name: pH Sensor Instrument Name: pH Sensor Instrument Short Name:pH Sensor Instrument Description: An instrument that measures the hydrogen ion activity in solutions.
The overall concentration of hydrogen ions is inversely related to its pH. The pH scale ranges from 0 to 14 and indicates whether acidic (more H+) or basic (less H+).
Water Temp Sensor
Water Temp Sensor
PI Supplied Instrument Name: Water Temp Sensor PI Supplied Instrument Description:HOBO Pendant temperature data loggers with an accuracy of ± 0.5 °C. Instrument Name: Water Temperature Sensor Instrument Short Name:Water Temp Sensor Instrument Description: General term for an instrument that measures the temperature of the water with which it is in contact (thermometer). Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/134/
Deployment: Levin_mussels
Levin_mussels
SIO Levin
SIO Levin
laboratory
Levin_mussels
Lisa A. Levin
University of California-San Diego Scripps
SIO Levin
SIO Levin
laboratory