http://lod.bco-dmo.org/id/dataset/646279
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2016-05-20
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
CTD rosette and Bottle data from R/V Hugh R. Sharp cruise HRS1314 in the Chesapeake Bay and coastal Atlantic Ocean in August 2013
2016-05-20
publication
2016-05-20
revision
BCO-DMO Linked Data URI
2016-05-20
creation
http://lod.bco-dmo.org/id/dataset/646279
George W. Luther
University of Delaware
principalInvestigator
Bradley M. Tebo
Oregon Health & Science University
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
Cite this dataset as: Luther, G. W., Tebo, B. M. (2016) CTD rosette and Bottle data from R/V Hugh R. Sharp cruise HRS1314 in the Chesapeake Bay and coastal Atlantic Ocean in August 2013. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 20 May 2016) Version Date 2016-05-20 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/646279 [access date]
CTD data and analyses of bottles from CTD rosette samples in 2013 Dataset Description: <p>Chesapeake Bay 2013 cruise LOG<br />
(R/V Sharp cruise HRS1314 - 130809GL)<br />
Chesapeake Bay / Offshore August&nbsp; 9 – August 16, 2013</p>
<p><strong>Methods papers used in this project</strong><br />
<strong>Dissolved Mn speciation parameters</strong><br />
Madison, A., B. M. Tebo, G. W. Luther, III. 2011. Simultaneous determination of soluble manganese(III), manganese(II) and total manganese in natural (pore)waters. <em>Talanta</em> 84, 374-381. <a class="western" href="http://dx.doi.org/10.1016/j.talanta.2011.01.025"><u>http://dx.doi.org/10.1016/j.talanta.2011.01.025</u></a></p>
<p>Madison, A. S, B. M. Tebo, A. Mucci, B. Sundby<sup> </sup>and G. W. Luther, III. 2013. Abundant Mn(III) in porewaters is a major component of the sedimentary redox system. <em>Science</em> 341, 875-878. <a class="western" href="http://dx.doi.org/10.1126/science.1241396"><u>http://dx.doi.org/10.1126/science.1241396</u></a></p>
<p>Oldham, V. O., S. M. Owings, M. Jones, B. M. Tebo and G. W. Luther, III. 2015. Evidence for the presence of strong Mn(III)-binding ligands in the water column of the Chesapeake Bay. <em>Marine Chemistry</em> 171, 58-66. <a class="western" href="http://dx.doi.org/10.1016/j.marchem.2015.02.008"><u>http://dx.doi.org/10.1016/j.marchem.2015.02.008</u></a></p>
<p><strong>MnO</strong><sub><strong>X</strong></sub><strong> solids</strong><br />
Altmann, H.H., 1972. Bestimmung von inWasser gelöstem Sauerstoffmit Leukoberbelinblau I. Fresenius' Z. Anal. Chem. 6, 97–99.</p>
<p>Krumbein, W. E., and H. J. Altmann. 1973. ‘A New Method for the Detection and Enumeration of Manganese Oxidizing and Reducing Microorganisms’. Helgoländer Wissenschaftliche Meeresuntersuchungen 25 (2-3): 347–56. doi:10.1007/BF01611203.</p>
<p><strong>Dissolved Fe speciation parameters</strong><br />
Stookey L.L. 1970. Ferrozine- A New Spectrophotometric Reagent for Iron. Anal. Chem. 42, 779-781.</p>
<p>Lewis, B. L., B. T. Glazer, P. J. Montbriand, G. W. Luther, III, D. B. Nuzzio, T. Deering, S. Ma, and S. Theberge. 2007. Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay. <em>Marine </em>Chemistry 105, 296-308.</p>
<p><strong>O</strong><sub><strong>2</strong></sub><strong> and H</strong><sub><strong>2</strong></sub><strong>S, polysulfides</strong><br />
Luther, III, G. W., B. T. Glazer, S. Ma, R. E. Trouwborst, T. S. Moore, E. Metzger, C. Kraiya, T. J. Waite, G. Druschel, B. Sundby, M. Taillefert, D. B. Nuzzio, T. M. Shank, B. L. Lewis and P. J. Brendel. 2008. Use of voltammetric solid-state (micro)electrodes for studying biogeochemical processes: laboratory measurements to real time measurements with an <em>in situ</em> electrochemical analyzer (ISEA). <em>Marine Chemistry</em> 108, 221-235. <a class="western" href="http://dx.doi.org/10.1016/j.marchem.2007.03.002"><u>http://dx.doi.org/10.1016/j.marchem.2007.03.002</u></a></p>
<p>Luther, G. W., III, and A. S. Madison. 2013. Determination of Dissolved Oxygen, Hydrogen Sulfide, Iron(II), and Manganese(II) in Wetland Pore Waters. In: Methods in Biogeochemistry of Wetlands, R.D. DeLaune, K.R. Reddy, C.J. Richardson, and J.P. Megonigal, editors. SSSA Book Series, no. 10. SSSA, Madison, WI. p. 87-106. <a class="western" href="http://dx.doi.org/10.2136/sssabookser10.c6"><u>http://dx.doi.org/10.2136/sssabookser10.c6</u></a></p>
<p><strong>S</strong><sub><u><strong>8</strong></u></sub><strong> </strong><br />
Yücel, M., S. K. Konovalov, T. S. Moore, C. P. Janzen and G. W. Luther, III. 2010. Sulfur speciation in the upper Black Sea sediments. <em>Chemical Geology</em> 269, 364-375. <a class="western" href="http://dx.doi.org/10.1016/j.chemgeo.2009.10.010"><u>http://dx.doi.org/10.1016/j.chemgeo.2009.10.010</u></a></p>
<p><strong>pH and inorganic carbon parameters</strong><br />
Gran G. 1952. Determination of the equivalence point in potentiometric titrations, Part II. <em>Analyst</em>, 77: 661-671.</p>
<p>Huang W.-J., Wang Y., and Cai W.-J. 2012. Assessment of sample storage techniques for total alkalinity and dissolved inorganic carbon in seawater. <em>Limnology and Oceanography: Methods</em>, 10: 711-717.</p>
<p><strong>Field Papers published as a result of this project (methods included)</strong><br />
Madison, A. S, B. M. Tebo, A. Mucci, B. Sundby<sup> </sup>and G. W. Luther, III. 2013. Abundant Mn(III) in porewaters is a major component of the sedimentary redox system. <em>Science</em> 341, 875-878. <a class="western" href="http://dx.doi.org/10.1126/science.1241396"><u>http://dx.doi.org/10.1126/science.1241396</u></a></p>
<p>MacDonald, D. J., A. J. Findlay, S. M. McAllister, J. M. Barnett, P. Hredzak-Showalter, S. T. Krepski, S. G. Cone, J. Scott, S. K. Bennett, C. S. Chan, D. Emerson and G.W. Luther III. 2014. Using <em>in situ</em> voltammetry as a tool to search for iron oxidizing bacteria: from fresh water wetlands to hydrothermal vent sites. <em>Environmental Science: Processes &amp; Impacts</em> 16, 2117-2126. <a class="western" href="http://dx.DOI.org/10.1039/c4em00073k"><u>http://dx.DOI.org/10.1039/c4em00073k</u></a></p>
<p>Findlay, A. J., A. Gartman, D. J. MacDonald, T. E. Hanson, T. J. Shaw and G. W. Luther, III. 2014. Distribution and size fractionation of elemental sulfur in aqueous environments: The Chesapeake Bay and Mid-Atlantic Ridge. <em>Geochimica Cosmochimica Acta</em> 142, 334-348. <a class="western" href="http://dx.doi.org/10.1016/j.gca.2014.07.032"><u>http://dx.doi.org/10.1016/j.gca.2014.07.032</u></a></p>
<p>Oldham, V. O., S. M. Owings, M. Jones, B. M. Tebo and G. W. Luther, III. 2015. Evidence for the presence of strong Mn(III)-binding ligands in the water column of the Chesapeake Bay. <em>Marine Chemistry</em> 171, 58-66. <a class="western" href="http://dx.doi.org/10.1016/j.marchem.2015.02.008"><u>http://dx.doi.org/10.1016/j.marchem.2015.02.008</u></a></p>
<p>Luther, G.W. III, A.S. Madison, A. Mucci, B. Sundby and V. E. Oldham. 2015. A kinetic approach to assess the strengths of ligands bound to soluble Mn(III). <em>Marine Chemistry</em> 173, 93-99. <a class="western" href="http://dx.doi.org/10.1016/j.marchem.2014.09.006"><u>http://dx.doi.org/10.1016/j.marchem.2014.09.006</u></a></p>
<p>Findlay, A. J., A. J. Bennet, T. E. Hanson and G. W. Luther, III. 2015. Light-dependent sulfide oxidation in the anoxic zone of the Chesapeake Bay can be explained by small populations of phototrophic bacteria. <em>Applied and Environmental Microbiology</em> 81(21), 7560-7569. <a class="western" href="http://dx.doi.org/10.1128/AEM.02062-15"><u>http://dx.doi.org/10.1128/AEM.02062-15</u></a>.</p>
<p>Findlay, A. J., A. Gartman, D. J. MacDonald, T. E. Hanson, T. J. Shaw and G. W. Luther, III. 2014. Distribution and size fractionation of elemental sulfur in aqueous environments: The Chesapeake Bay and Mid-Atlantic Ridge. <em>Geochimica Cosmochimica Acta</em> 142, 334-348. <a class="western" href="http://dx.doi.org/10.1016/j.gca.2014.07.032"><u>http://dx.doi.org/10.1016/j.gca.2014.07.032</u></a></p> Methods and Sampling: <p><strong>Parameters Measured</strong><br />
<strong>C parameters</strong> performed by Dr. Wei-Jun Cai’s group for<br />
TA - Open cell Gran titration with semi-automatic&nbsp;AS-ALK2 Apollo Scitech titrator<br />
pH - glass electrode, NBS buffers<br />
DIC - infrared CO<sub>2</sub> analyzer (AS-C3, Apollo Scitech)<br />
<br />
Use Dickson CRM for calibration. DIC/TA samples were filtered (0.45um) and fixed with 100 ul of saturated mercury bichloride.<br />
Use the methods of Gran (1952) and Huang, et al. (2012).</p>
<p><strong>Fe parameters</strong><br />
The method of Stookey (1972) is used to determine dissolved Fe(II) and on addition if hydroxylamine Fe total. Fe(III) is determined by difference. Modified and calibrated by many including Lewis et al (2007) and MacDonald et al (2014). Typically, triplicate measurements performed.</p>
<p><strong>Dissolved Mn parameters</strong><br />
The porphyrin spectrophotometric method of Madison et al (2011) measures dissolved Mn(II), Mn(III) bound to weaker ligands and total Mn. Method includes calibration and intercomparison of totals with other instrumentation (ICP, AA). Detection limit is 0.050 micromolar. Detection limit (DL) is 50 micromolar with a 1 cm path length cell.</p>
<p>Modification of Madison for Mn(III) bound to strong ligands by adding a reducing agent to a separate subsample with the porphyrin to obtain total Mn. Mn(III) bound to strong ligand complexes is determined by difference. Typically, triplicate measurements performed. Detection limit is 0.669 micromolar.</p>
<p><strong>MnO</strong><sub><strong>x</strong></sub><strong> on unfiltered samples</strong><br />
The leucoberbelein blue method is that of Altmann (1972) and Krumblein and Altmann (1973) in 1 cm cells, but can be modified for longer path length cells.</p>
<p><strong>S parameters</strong><br />
O<sub>2</sub>, H<sub>2</sub>S and polysulfides by the voltammetry method of Luther et al (2008).<br />
A flow cell was also used to collect in situ O<sub>2</sub> and H<sub>2</sub>S data as well as some additional samples. Analysis by voltammetry (Luther et al, 2008).</p>
<p>Solid and nanoparticulate S<sub>8</sub> (Yücel et al 2010 and Findlay et al 2014).<br />
Typically, triplicate measurements performed.</p>
<p><em><strong>In situ </strong></em><strong>refers</strong><em><strong> </strong></em><strong>to profiling with a pump profiler for O</strong><sub><strong>2</strong></sub><strong> and H</strong><sub><strong>2</strong></sub><strong>S using solid state gold-amalgam electrodes for voltammetry (Luther et al, 2008; Analytical Instrument Systems DLK-60) along with a temperature and salinity sensor from YSI.</strong></p>
<p><strong>Data Parameters - Glossary:</strong><br />
<strong>DL</strong> = detection limit in micromolar (uM); DL for soluble Mn is 0.050 micromolar<br />
<strong>BDL</strong> = below detection limit<br />
<strong>RSD</strong> = relative standard deviation<br />
<strong>NA</strong> = not analyzed<br />
<strong>ND</strong> = not detected<br />
<strong>nd</strong> = no data; inserted into blank cells by BCO-DMO</p>
<p><strong>Note</strong>: duplicate bottles at each depth</p>
Funding provided by NSF Division of Biological Infrastructure (NSF DBI) Award Number: DBI-0424599 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=0424599
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1155385 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1155385
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1154307 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1154307
Funding provided by Simons Foundation (Simons) Award Number: unknown SCOPE Simons Award URL: https://www.simonsfoundation.org/
completed
George W. Luther
University of Delaware
302-645-4208
700 Pilottown Road School of Marine Science and Policy
Lewes
DE
19958
USA
luther@udel.edu
pointOfContact
Bradley M. Tebo
Oregon Health & Science University
503-346-3438
Division of Environmental and Biomolecular Systems 20000 NW Walker Road
Beaverton
OR
97006
USA
tebob@ohsu.edu
pointOfContact
asNeeded
Dataset Version: 20 May 2016
Unknown
Cast
Station
Bottle_Num
Local_Date
Local_time
Latitude
Longitude
depth
temp
salinity
sigma_t
CTD_O2
OneHundredPercentO2_sat
percent_O2_sat
fluorescence_chla
transmissometry
TA
DIC
pH_primary
Particulate_Filtered_MnOx
Dissolved_Filtered_Mn2plus
Dissolved_Filtered_Mn2plus_stdev
Dissolved_Filtered_Mn3plus_mean
Dissolved_Filtered_Mn3plus_stdev
Dissolved_Filtered_MnT_mean
Dissolved_Filtered_MnT_stdev
Dissolved_Filtered_H2Splus_Hsminus
Dissolved_Filtered_H2Splus_Hsminus_stdev
Dissolved_Filtered_Fe2plus
Dissolved_Filtered_Fe2plus_stdev
Total_UnFiltered_Fe2plus
Total_UnFiltered_Fe2plus_stdev
Dissolved_Filtered_Fe3plus
Dissolved_Filtered_Fe3plus_stdev
Total_UnFiltered_Fe3plus
Total_UnFiltered_Fe3plus_stdev
pH_secondary
Nanoparticulate_Dissolved_Filtered_S0
Dissolved_Particulate_S0
Total_S0_Filtered_plus_Particulate
AS-C3, Apollo Scitech
pump profiler
SeaBird Electronics 911 plus CTD
Niskin Bottle
In situ pump - West Marine Pump
AS-ALK2 Apollo Scitech titrator
Analytical Instrument Systems DLK-60
YSI temperature and salinity sensor
theme
None, User defined
cast
station
bottle
date_local
time_local
latitude
longitude
depth
water temperature at measurement depth
salinity
sigma-theta potential density
dissolved Oxygen
O2 saturation
chlorophyll-a; fluorometric method
trans_raw
total alkalinity (TA)
dissolved inorganic Carbon
pH
Manganese
No BCO-DMO term
Iron
Fe_unfilt
sulfide
featureType
BCO-DMO Standard Parameters
CO2 Analyzer
CTD - profiler
CTD Sea-Bird SBE 911plus
Niskin bottle
Pump
Titrator
Voltammetry Analyzers
YSI Professional Plus Multi-Parameter Probe
instrument
BCO-DMO Standard Instruments
HRS1314
service
Deployment Activity
Chesapeake Bay and coastal Atlantic Ocean
place
Locations
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
The role of soluble Mn(III) in the biogeochemical coupling of the Mn, Fe and sulfur cycles
https://osprey.bco-dmo.org/project/636520
The role of soluble Mn(III) in the biogeochemical coupling of the Mn, Fe and sulfur cycles
<p><em>Description from NSF award abstract:</em><br />
The research conducted by investigators in the School of Marine Science and Policy at the University of Delaware and within the Department of Environmental and Biomolecular Systems of Oregon Health and Science University will examine the importance of soluble Mn(III) in the biogeochemical cycling of Mn. To date, most studies of Mn in marine environments have not considered Mn(III), the intermediate oxidation state between the soluble reduced state (Mn(II)) and the more insoluble oxidized state (Mn(IV)). The presence and stability of Mn(III) in marine systems, especially those where oxygen levels are reduced, changes the dynamics and stability, solubility and fate and transport of Mn in these locations, and at interfaces between oxic and low oxygen environments. This is not understood at present and the proposed research is poised to provide new information concerning the Mn cycle and is potentially transformative research. The PIs have developed new methods to examine Mn(III) levels in the environment and this capability will bolster the successful accomplishment of the project's goals. The studies will not only focus on understanding the cycling of Mn between its various oxidation states but will determine the concentration and distribution of Mn(III) in stratified coastal ocean waters and in sediment porewaters. The study will also examine the potentially important role of Mn(III) in mediating and influencing the biogeochemical cycling of Mn with that of Fe and S, which are both important components of the major ocean chemical cycles. A better understanding of the biogeochemistry of Mn will inform not only scientists interested in metal cycling in the ocean but also those focused on studies across redox transition zones. The proposed research has an international component and the investigators have developed plans to broadly disseminate their results to students at all levels and to the community. The Principal Investigators have a strong history in education and graduate student and post-doctoral support and mentoring and this will continue under the current grant.</p>
Soluble ManganeseIII
largerWorkCitation
project
eng; USA
oceans
Chesapeake Bay and coastal Atlantic Ocean
2016-05-20
Chesapeake Bay and coastal Atlantic Ocean
0
BCO-DMO catalogue of parameters from CTD rosette and Bottle data from R/V Hugh R. Sharp cruise HRS1314 in the Chesapeake Bay and coastal Atlantic Ocean in August 2013
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/646311.rdf
Name: Cast
Units: text
Description: <p>Cast</p>
http://lod.bco-dmo.org/id/dataset-parameter/646312.rdf
Name: Station
Units: text
Description: <p>Station</p>
http://lod.bco-dmo.org/id/dataset-parameter/646313.rdf
Name: Bottle_Num
Units: text
Description: <p>Bottle_Num</p>
http://lod.bco-dmo.org/id/dataset-parameter/646314.rdf
Name: Local_Date
Units: YYYYMMDD
Description: <p>Local_Date</p>
http://lod.bco-dmo.org/id/dataset-parameter/646315.rdf
Name: Local_time
Units: HHMM
Description: <p>Local_time</p>
http://lod.bco-dmo.org/id/dataset-parameter/646316.rdf
Name: Latitude
Units: decimal degrees
Description: <p>Latitude</p>
http://lod.bco-dmo.org/id/dataset-parameter/646317.rdf
Name: Longitude
Units: decimal degrees
Description: <p>Longitude</p>
http://lod.bco-dmo.org/id/dataset-parameter/646318.rdf
Name: depth
Units: meters
Description: <p>depth</p>
http://lod.bco-dmo.org/id/dataset-parameter/646319.rdf
Name: temp
Units: deg C
Description: <p>temp</p>
http://lod.bco-dmo.org/id/dataset-parameter/646320.rdf
Name: salinity
Units: PSU
Description: <p>salinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/646321.rdf
Name: sigma_t
Units: kg/m^3 (??)
Description: <p>sigma_t</p>
http://lod.bco-dmo.org/id/dataset-parameter/646322.rdf
Name: CTD_O2
Units: uM
Description: <p>CTD_O2</p>
http://lod.bco-dmo.org/id/dataset-parameter/646323.rdf
Name: OneHundredPercentO2_sat
Units: umol/l
Description: <p>100%O2 sat</p>
http://lod.bco-dmo.org/id/dataset-parameter/646324.rdf
Name: percent_O2_sat
Units: percentage
Description: <p>% O2 sat</p>
http://lod.bco-dmo.org/id/dataset-parameter/646325.rdf
Name: fluorescence_chla
Units: volts
Description: <p>fluorescence chla; voltage = 0</p>
http://lod.bco-dmo.org/id/dataset-parameter/646326.rdf
Name: transmissometry
Units: volts
Description: <p>transmissometry; voltage = 4</p>
http://lod.bco-dmo.org/id/dataset-parameter/646327.rdf
Name: TA
Units: um/kg
Description: <p>TA</p>
http://lod.bco-dmo.org/id/dataset-parameter/646328.rdf
Name: DIC
Units: um/kg
Description: <p>DIC</p>
http://lod.bco-dmo.org/id/dataset-parameter/646329.rdf
Name: pH_primary
Units: pH units
Description: <p>pH primary</p>
http://lod.bco-dmo.org/id/dataset-parameter/646330.rdf
Name: Particulate_Filtered_MnOx
Units: um
Description: <p>Particulate MnOx, (mM) caught on 0.200 um filter; MnOx DL = 0.669 micromolar; precision typically 2-5% RSD</p>
http://lod.bco-dmo.org/id/dataset-parameter/646331.rdf
Name: Dissolved_Filtered_Mn2plus
Units: um
Description: <p>Dissolved Mn2+ (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646332.rdf
Name: Dissolved_Filtered_Mn2plus_stdev
Units: um
Description: <p>Stdev Dissolved Mn2+ (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646333.rdf
Name: Dissolved_Filtered_Mn3plus_mean
Units: um
Description: <p>Dissolved Mn3+ (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646334.rdf
Name: Dissolved_Filtered_Mn3plus_stdev
Units: um
Description: <p>Stdev Dissolved Mn3+ (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646335.rdf
Name: Dissolved_Filtered_MnT_mean
Units: um
Description: <p>Dissolved MnT (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646336.rdf
Name: Dissolved_Filtered_MnT_stdev
Units: um
Description: <p>Stdev Dissolved MnT (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646337.rdf
Name: Dissolved_Filtered_H2Splus_Hsminus
Units: um
Description: <p>Dissolved H2S+HS- (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646338.rdf
Name: Dissolved_Filtered_H2Splus_Hsminus_stdev
Units: um
Description: <p>Stdev Dissolved H2S+HS- (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646339.rdf
Name: Dissolved_Filtered_Fe2plus
Units: um
Description: <p>Dissolved [Fe2+] (mM) filtered through 0.2 um; DL for Fe is 0.100 micromolar</p>
http://lod.bco-dmo.org/id/dataset-parameter/646340.rdf
Name: Dissolved_Filtered_Fe2plus_stdev
Units: um
Description: <p>Stdev Dissolved [Fe2+] (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646341.rdf
Name: Total_UnFiltered_Fe2plus
Units: um
Description: <p>Total UnFiltered [Fe2+] (mM)</p>
http://lod.bco-dmo.org/id/dataset-parameter/646342.rdf
Name: Total_UnFiltered_Fe2plus_stdev
Units: um
Description: <p>Stdev Total UnFiltered [Fe2+] (mM)</p>
http://lod.bco-dmo.org/id/dataset-parameter/646343.rdf
Name: Dissolved_Filtered_Fe3plus
Units: um
Description: <p>Dissolved [Fe3+] (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646344.rdf
Name: Dissolved_Filtered_Fe3plus_stdev
Units: um
Description: <p>Stdev Dissolved [Fe3+] (mM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646345.rdf
Name: Total_UnFiltered_Fe3plus
Units: um
Description: <p>Total UnFiltered [Fe3+] (mM)</p>
http://lod.bco-dmo.org/id/dataset-parameter/646346.rdf
Name: Total_UnFiltered_Fe3plus_stdev
Units: um
Description: <p>Stdev Total UnFiltered [Fe3+] (mM)</p>
http://lod.bco-dmo.org/id/dataset-parameter/646347.rdf
Name: pH_secondary
Units: pH units
Description: <p>pH secondary</p>
http://lod.bco-dmo.org/id/dataset-parameter/646348.rdf
Name: Nanoparticulate_Dissolved_Filtered_S0
Units: um
Description: <p>Nanoparticulate/Dissolved [S(0)] (uM) filtered through 0.2 um</p>
http://lod.bco-dmo.org/id/dataset-parameter/646349.rdf
Name: Dissolved_Particulate_S0
Units: um
Description: <p>Particulate [S(0)] (uM) filtered through 0.2 um; DL 0.1 uM</p>
http://lod.bco-dmo.org/id/dataset-parameter/646350.rdf
Name: Total_S0_Filtered_plus_Particulate
Units: um
Description: <p>Total S(0) filtered + particulate</p>
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
46063
https://datadocs.bco-dmo.org/file/ZZZgKqWFDr5MG0/RosetteSamples_CTD_Bottle.csv
RosetteSamples_CTD_Bottle.csv
Primary data file for dataset ID 646279
download
https://osprey.bco-dmo.org/dataset/646279/data/download
download
onLine
dataset
<p><strong>Parameters Measured</strong><br />
<strong>C parameters</strong> performed by Dr. Wei-Jun Cai’s group for<br />
TA - Open cell Gran titration with semi-automatic&nbsp;AS-ALK2 Apollo Scitech titrator<br />
pH - glass electrode, NBS buffers<br />
DIC - infrared CO<sub>2</sub> analyzer (AS-C3, Apollo Scitech)<br />
<br />
Use Dickson CRM for calibration. DIC/TA samples were filtered (0.45um) and fixed with 100 ul of saturated mercury bichloride.<br />
Use the methods of Gran (1952) and Huang, et al. (2012).</p>
<p><strong>Fe parameters</strong><br />
The method of Stookey (1972) is used to determine dissolved Fe(II) and on addition if hydroxylamine Fe total. Fe(III) is determined by difference. Modified and calibrated by many including Lewis et al (2007) and MacDonald et al (2014). Typically, triplicate measurements performed.</p>
<p><strong>Dissolved Mn parameters</strong><br />
The porphyrin spectrophotometric method of Madison et al (2011) measures dissolved Mn(II), Mn(III) bound to weaker ligands and total Mn. Method includes calibration and intercomparison of totals with other instrumentation (ICP, AA). Detection limit is 0.050 micromolar. Detection limit (DL) is 50 micromolar with a 1 cm path length cell.</p>
<p>Modification of Madison for Mn(III) bound to strong ligands by adding a reducing agent to a separate subsample with the porphyrin to obtain total Mn. Mn(III) bound to strong ligand complexes is determined by difference. Typically, triplicate measurements performed. Detection limit is 0.669 micromolar.</p>
<p><strong>MnO</strong><sub><strong>x</strong></sub><strong> on unfiltered samples</strong><br />
The leucoberbelein blue method is that of Altmann (1972) and Krumblein and Altmann (1973) in 1 cm cells, but can be modified for longer path length cells.</p>
<p><strong>S parameters</strong><br />
O<sub>2</sub>, H<sub>2</sub>S and polysulfides by the voltammetry method of Luther et al (2008).<br />
A flow cell was also used to collect in situ O<sub>2</sub> and H<sub>2</sub>S data as well as some additional samples. Analysis by voltammetry (Luther et al, 2008).</p>
<p>Solid and nanoparticulate S<sub>8</sub> (Yücel et al 2010 and Findlay et al 2014).<br />
Typically, triplicate measurements performed.</p>
<p><em><strong>In situ </strong></em><strong>refers</strong><em><strong> </strong></em><strong>to profiling with a pump profiler for O</strong><sub><strong>2</strong></sub><strong> and H</strong><sub><strong>2</strong></sub><strong>S using solid state gold-amalgam electrodes for voltammetry (Luther et al, 2008; Analytical Instrument Systems DLK-60) along with a temperature and salinity sensor from YSI.</strong></p>
<p><strong>Data Parameters - Glossary:</strong><br />
<strong>DL</strong> = detection limit in micromolar (uM); DL for soluble Mn is 0.050 micromolar<br />
<strong>BDL</strong> = below detection limit<br />
<strong>RSD</strong> = relative standard deviation<br />
<strong>NA</strong> = not analyzed<br />
<strong>ND</strong> = not detected<br />
<strong>nd</strong> = no data; inserted into blank cells by BCO-DMO</p>
<p><strong>Note</strong>: duplicate bottles at each depth</p>
Specified by the Principal Investigator(s)
<p><strong>Data Parameters - Glossary:</strong><br />
<strong>DL</strong> = detection limit in micromolar (uM); DL for soluble Mn is 0.050 micromolar; DL for Fe is 0.100 micromolar<br />
<strong>BDL</strong> = below detection limit<br />
<strong>RSD</strong> = relative standard deviation; precision typically 2-5% RSD<br />
<strong>NA</strong> = not analyzed<br />
<strong>ND</strong> = not detected<br />
<strong>nd</strong> = no data; inserted into blank cells by BCO-DMO</p>
<p><strong>Note</strong>: duplicate bottles at each depth</p>
<p><strong>BCO-DMO Processing Notes</strong><br />
- Generated from original file "LutherTeboCB2013RosetteSamples_CORR.xlsx" contributed by George Luther<br />
- Parameter names edited to conform to BCO-DMO naming convention found at <a href="http://usjgofs.whoi.edu/naming-guidelines.html" target="_blank">Choosing Parameter Name</a><br />
- Date converted to YYYYMMDD<br />
- Blank lines removed<br />
- Lat/Lon converted from degs, decimal minutes to decimal degrees (degs, decimal minutes maintained)<br />
- "nd" (no data) inserted into blank cells<br />
- Stations, Casts, Dates, Times, Lat, Lons reformatted to fit on a single line (record)</p>
Specified by the Principal Investigator(s)
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
AS-C3, Apollo Scitech
AS-C3, Apollo Scitech
PI Supplied Instrument Name: AS-C3, Apollo Scitech PI Supplied Instrument Description:DIC - infrared CO2 analyzer (AS-C3, Apollo Scitech) Instrument Name: CO2 Analyzer Instrument Short Name:CO2 Analyzer Instrument Description: Measures atmospheric carbon dioxide (CO2) concentration. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/382/
pump profiler
pump profiler
PI Supplied Instrument Name: pump profiler PI Supplied Instrument Description:In situ refers to profiling with a pump profiler for O2 and H2S using solid state gold-amalgam electrodes for voltammetry (Luther et al, 2008; Analytical Instrument Systems DLK-60) along with a temperature and salinity sensor from YSI. Instrument Name: CTD - profiler Instrument Short Name: Instrument Description: The Conductivity, Temperature, Depth (CTD) unit is an integrated instrument package designed to measure the conductivity, temperature, and pressure (depth) of the water column. The instrument is lowered via cable through the water column. It permits scientists to observe the physical properties in real-time via a conducting cable, which is typically connected to a CTD to a deck unit and computer on a ship. The CTD is often configured with additional optional sensors including fluorometers, transmissometers and/or radiometers. It is often combined with a Rosette of water sampling bottles (e.g. Niskin, GO-FLO) for collecting discrete water samples during the cast.
This term applies to profiling CTDs. For fixed CTDs, see https://www.bco-dmo.org/instrument/869934. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/130/
SeaBird Electronics 911 plus CTD
SeaBird Electronics 911 plus CTD
PI Supplied Instrument Name: SeaBird Electronics 911 plus CTD PI Supplied Instrument Description:CTD System: SeaBird Electronics 911 plus CTD, Rosette is a 12-bottle General Oceanic Model 1015, outfitted with an array of 10 liter bottles. Instrument Name: CTD Sea-Bird SBE 911plus Instrument Short Name:CTD SBE 911plus Instrument Description: The Sea-Bird SBE 911 plus is a type of CTD instrument package for continuous measurement of conductivity, temperature and pressure. The SBE 911 plus includes the SBE 9plus Underwater Unit and the SBE 11plus Deck Unit (for real-time readout using conductive wire) for deployment from a vessel. The combination of the SBE 9 plus and SBE 11 plus is called a SBE 911 plus. The SBE 9 plus uses Sea-Bird's standard modular temperature and conductivity sensors (SBE 3 plus and SBE 4). The SBE 9 plus CTD can be configured with up to eight auxiliary sensors to measure other parameters including dissolved oxygen, pH, turbidity, fluorescence, light (PAR), light transmission, etc.). more information from Sea-Bird Electronics Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0058/
Niskin Bottle
Niskin Bottle
PI Supplied Instrument Name: Niskin Bottle PI Supplied Instrument Description:CTD System: SeaBird Electronics 911 plus CTD, Rosette is a 12-bottle General Oceanic Model 1015, outfitted with an array of 10 liter bottles. Instrument Name: Niskin bottle Instrument Short Name:Niskin bottle Instrument Description: A Niskin bottle (a next generation water sampler based on the Nansen bottle) is a cylindrical, non-metallic water collection device with stoppers at both ends. The bottles can be attached individually on a hydrowire or deployed in 12, 24, or 36 bottle Rosette systems mounted on a frame and combined with a CTD. Niskin bottles are used to collect discrete water samples for a range of measurements including pigments, nutrients, plankton, etc. Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0412/
In situ pump - West Marine Pump
In situ pump - West Marine Pump
PI Supplied Instrument Name: In situ pump - West Marine Pump PI Supplied Instrument Description:In situ pump - West Marine Pump Instrument Name: Pump Instrument Short Name: Instrument Description: A pump is a device that moves fluids (liquids or gases), or sometimes slurries, by mechanical action. Pumps can be classified into three major groups according to the method they use to move the fluid: direct lift, displacement, and gravity pumps
AS-ALK2 Apollo Scitech titrator
AS-ALK2 Apollo Scitech titrator
PI Supplied Instrument Name: AS-ALK2 Apollo Scitech titrator PI Supplied Instrument Description:TA - Open cell Gran titration with semi-automatic AS-ALK2 Apollo Scitech titrator Instrument Name: Titrator Instrument Short Name:Titrator Instrument Description: Titrators are instruments that incrementally add quantified aliquots of a reagent to a sample until the end-point of a chemical reaction is reached. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB12/
Analytical Instrument Systems DLK-60
Analytical Instrument Systems DLK-60
PI Supplied Instrument Name: Analytical Instrument Systems DLK-60 PI Supplied Instrument Description:In situ refers to profiling with a pump profiler for O2 and H2S using solid state gold-amalgam electrodes for voltammetry (Luther et al, 2008; Analytical Instrument Systems DLK-60) along with a temperature and salinity sensor from YSI. Instrument Name: Voltammetry Analyzers Instrument Short Name:Voltammetry Analyzers Instrument Description: Instruments that obtain information about an analyte by applying a potential and measuring the current produced in the analyte. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB35/
YSI temperature and salinity sensor
YSI temperature and salinity sensor
PI Supplied Instrument Name: YSI temperature and salinity sensor PI Supplied Instrument Description:In situ refers to profiling with a pump profiler for O2 and H2S using solid state gold-amalgam electrodes for voltammetry (Luther et al, 2008; Analytical Instrument Systems DLK-60) along with a temperature and salinity sensor from YSI. Instrument Name: YSI Professional Plus Multi-Parameter Probe Instrument Short Name:YSI ProPlus Instrument Description: The YSI Professional Plus handheld multiparameter meter provides for the measurement of a variety of combinations for dissolved oxygen, conductivity, specific conductance, salinity, resistivity, total dissolved solids (TDS), pH, ORP, pH/ORP combination, ammonium (ammonia), nitrate, chloride and temperature. More information from the manufacturer.
Cruise: HRS1314
HRS1314
R/V Hugh R. Sharp
Community Standard Description
International Council for the Exploration of the Sea
R/V Hugh R. Sharp
vessel
HRS1314
George W. Luther
University of Delaware
R/V Hugh R. Sharp
Community Standard Description
International Council for the Exploration of the Sea
R/V Hugh R. Sharp
vessel