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        <gco:CharacterString>Dataset Description: &amp;lt;p&amp;gt;Dataset includes measured values for dO18, and d47&amp;amp;nbsp;generated from phosphoric acid digestion of carbonates in selected coral samples.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Data are published in:&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Tripati, A.K., Hill, P.S., Eagle, R.A., Mosenfelder, J.L., Tang, J., Schauble, E.A., Eiler, J.M., Zeebe, R.E., Uchikawae, J., Coplen, T.B., Ries, J.B., Henry, D., 2015, Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition. Geochimica et Cosmochimica Acta 166: 344-371. DOI:&amp;amp;nbsp;&amp;lt;a href=&amp;quot;http://doi.org/10.1016/j.gca.2015.06.021&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;10.1016/j.gca.2015.06.021&amp;lt;/a&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Please see manuscript for complete methodology.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;lt;/p&amp;gt; Methods and Sampling:</gco:CharacterString>
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&lt;p&gt;Corals and other types of marine calcifiers are thought to begin the mineralization of their calcium carbonate skeletons by actively elevating pH of their calcifying fluid, thereby converting bicarbonate ions (comprising ~90% of seawater dissolved inorganic carbon) to carbonate ions, the form of carbon used in calcification. This project will compare the combined boron isotope, pH microelectrode, and pH-sensitive dye approach to measure the calcifying fluid pH of three species of scleractinian corals, and to assess how their calcifying fluid pH (a primary factor controlling their calcification) responds to experimentally induced ocean acidification. As a result this multi-pronged approach to measuring calcifying fluid pH of the same coral species under equivalent culturing conditions will permit the first systematic cross-examination of the validity of these independent approaches. The combined approach will also yield values of calcifying fluid pH with uncertainties that can be quantified via inter-comparison and statistical treatment of these independent measurements. Importantly, this multi-pronged approach will be used on three coral species that due to differences in the carbonate chemistry of their native waters possess differing capacities for proton regulation at their site of calcification; a deep, cold-water coral (strong proton-pumper); a shallow, temperate coral (moderate proton-pumper); and a shallow, tropical coral (weak proton-pumper). Target outcomes of this research include (1) cross-examination of the validity of three independent approaches to estimating coral calcifying fluid pH, (2) quantification of uncertainty associated with the three approaches to estimating coral calcifying fluid pH, (3) advancement of our mechanistic understanding of coral calcification, (4) exploration of the mechanism by which ocean acidification impacts coral calcification, (5) elucidation why corals exhibit such varied responses to ocean acidification, (6) identification of coral types most vulnerable to ocean acidification, (7) exploration of so-called &quot;vital effects&quot; that limit the use of corals in paleoceanographic reconstructions, and (8) quantitative constraint of existing models of coral biomineralization.&lt;/p&gt;</gco:CharacterString>
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		    <gmd:CI_Telephone>
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				    <gco:CharacterString>Unavailable</gco:CharacterString>
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				    <gco:CharacterString>508-289-2009</gco:CharacterString>
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		    <gmd:CI_Address>
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				    <gco:CharacterString>WHOI MS#36</gco:CharacterString>
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				  <gmd:city>
				    <gco:CharacterString>Woods Hole</gco:CharacterString>
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				    <gco:CharacterString>MA</gco:CharacterString>
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				    <gco:CharacterString>02543</gco:CharacterString>
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				    <gco:CharacterString>USA</gco:CharacterString>
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				    <gco:CharacterString>info@bco-dmo.org</gco:CharacterString>
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		  </gmd:address>
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            <gmd:linkage>
              <gmd:URL>http://www.bco-dmo.org</gmd:URL>
            </gmd:linkage>
          </gmd:CI_OnlineResource>
        </gmd:onlineResource>
		  <gmd:hoursOfService>
        <gco:CharacterString>Monday - Friday 8:00am - 5:00pm</gco:CharacterString>
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		  <gmd:contactInstructions>
		    <gco:CharacterString>For questions regarding this resource, please contact BCO-DMO via the email address provided.</gco:CharacterString>
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</gmd:CI_ResponsibleParty>
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    </gmd:MD_MaintenanceInformation>
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    <gmi:instrument>
        <gmi:MI_Instrument>
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              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/685.rdf" xlink:title="Mass Spectrometer" xlink:actuate="onRequest">Thermo Scientific MAT 253 gas-source mass spectrometers based at Caltech and UCLA</gmx:Anchor>
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