http://lod.bco-dmo.org/id/dataset/744679
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2018-08-28
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
Nitrate, nitrite, and nitrous oxide isotope measurements from the Eastern Tropical South Pacific ocean collected on RVIB Nathaniel B. Palmer cruise NBP1305 from June to July 2013
2018-08-28
publication
2018-08-28
revision
Marine Biological Laboratory/Woods Hole Oceanographic Institution Library (MBLWHOI DLA)
2019-03-15
publication
https://doi.org/10.1575/1912/bco-dmo.744679.1
Karen L. Casciotti
Stanford University
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
Cite this dataset as: Casciotti, K. (2018) Nitrate, nitrite, and nitrous oxide isotope measurements from the Eastern Tropical South Pacific ocean collected on RVIB Nathaniel B. Palmer cruise NBP1305 from June to July 2013. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2018-08-28 [if applicable, indicate subset used]. doi:10.1575/1912/bco-dmo.744679.1 [access date]
Nitrate, nitrite, and nitrous oxide isotope measurements from the Eastern Tropical South Pacific ocean (NBP13-05) Dataset Description: <p>Nitrate, nitrite, and nitrous oxide isotope measurements from the Eastern Tropical South Pacific ocean (NBP13-05). The data in this dataset were published in&nbsp;Peters et al. (2018) and Casciotti et al. (2018).</p> Methods and Sampling: <p>Samples were collected from a standard Niskin bottle rosette.</p>
<p>Nitrate isotope analyses were conducted by denitrifier method (Sigman et al., 2001; Casciotti et al., 2002) with updates (McIlviin and Casciotti, 2011). Nitrite was removed from samples containing more than 0.1 uM nitrite, using sulfuric acid (Granger and Sigman, 2009). Standards include USGS32, USGS34, and USGS35.</p>
<p>Nitrite isotope analyses were conducted by azide method (McIlvin and Altabet, 2005). Standards include N23, N7373, and N10219.</p>
<p>Nitrous oxide isotope analyses were conducted as described in McIlvin and Casciotti, 2010. N2O isotope measurements were calibrated against a laboratory N2O working gas.</p>
<p>The water mass analysis for the oxygen deficient zone waters was conducted as described in Peters et al., 2018, Deep Sea Research II, Estimating fixed nitrogen loss and associated isotope effects using concentration and isotope measurements of NO3-, NO2-, and N2 from the Eastern Tropical South Pacific oxygen deficient zone.</p>
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1233339 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1233339
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1140404 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1140404
completed
Karen L. Casciotti
Stanford University
650-721-5545
Department of Environmental Earth System Science 473 Via Ortega, Y2E2 Building, Room 140
Stanford
CA
94305
USA
kcasciotti@stanford.edu
pointOfContact
asNeeded
Dataset Version: 1
Unknown
CTD_cast
STN
date
DEPTH
PRESSURE
latitude
longitude
TEMPERATURE
SALINITY
SIGMA_THETA
SBE_OXYGEN
O2_SAT_mL_L
O2_SAT_umol_kg
AOU
NO3_sample_IDs
sulfamic_treated
d15N_NO3
d15N_NO3_sd
d18O_NO3
d18O_NO3_sd
d15N_NO2
d15N_NO2_sd
d18O_NO2
d18O_NO2_sd
N2O_sample_ID_1
N2O_sample_ID_2
N2O_conc
N2O_conc_sd
N2O_SP
N2O_SP_sd
d15N_N2O
d15N_N2O_sd
d18O_N2O
d18O_N2O_sd
d15Na
d15Na_sd
d15Nb
d15Nb_sd
Kelvin
ln_Ko
Ko
N2O_sat_mol_kg
N2O_sat_nmol_L
delta_N2O
ESPIW
ESSW
ThermoFinnigan DeltaPLUS XP
theme
None, User defined
cast
station
date
depth
water pressure
latitude
longitude
water temperature at measurement depth
salinity
sigma-theta potential density
dissolved Oxygen
O2 saturation
Apparent Oxygen Utilization
sample identification
treatment
d15N_NO3
d18O_NO3
No BCO-DMO term
Nitrous Oxide
d15N
featureType
BCO-DMO Standard Parameters
Isotope-ratio Mass Spectrometer
instrument
BCO-DMO Standard Instruments
NBP1305
service
Deployment Activity
Eastern Tropical South Pacific
place
Locations
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
Biogeochemistry of nitrous oxide cycling in the eastern tropical South Pacific
https://osprey.bco-dmo.org/project/2271
Biogeochemistry of nitrous oxide cycling in the eastern tropical South Pacific
<p>The eastern tropical South Pacific (ETSP) is a hot spot for oceanic nitrogen cycling. This region of upwelling and high productivity fuels high rates of oxygen consumption below the mixed layer, nitrate regeneration from nitrification, and ultimately denitrification of nitrate to N2 gas. The climatically important trace gas nitrous oxide (N2O) also reaches extreme high concentrations in the oxycline and extreme low concentrations in the heart of the oxygen minimum zone (OMZ), indicating active cycling in this region. Despite many years of investigation, the mechanism of N2O production in this hot spot is ambiguous because of the potential overlap or coupling of nitrification and denitrification processes at low oxygen tensions.</p>
<p>The investigators employed novel stable isotopic techniques to identify processes involved with nitrous oxide production and consumption in the water column at multiple sites within the eastern tropical South Pacific. They also sought to map the natural distributions of nitrate, nitrite and nitrous oxide concentrations and isotopes at high spatial resolution in order to develop a dataset with which to constrain ocean models based on their rate measurements.</p>
<p>Incubation experiments were carried out at sea to quantify the rates of nitrification and N2O cycling in samples throughout the oxygen minimum zone. In addition, approximately 1000 samples were collected for nitrate and nitrite isotopic analysis and 500 samples for N2O isotopic analysis. The investigators worked closely with other researchers onboard to work towards developing the most coherent picture of nitrogen cycling in the eastern tropical Pacific to date.</p>
N2O Cycling
largerWorkCitation
project
eng; USA
oceans
Eastern Tropical South Pacific
-85.9989
-70.58334
-22.21654
-11.99976
2013-06-27
2013-07-19
Peruvian Oxygen Deficient Zone
0
BCO-DMO catalogue of parameters from Nitrate, nitrite, and nitrous oxide isotope measurements from the Eastern Tropical South Pacific ocean collected on RVIB Nathaniel B. Palmer cruise NBP1305 from June to July 2013
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/744859.rdf
Name: CTD_cast
Units: unitless
Description: <p>cast identifier from cruise</p>
http://lod.bco-dmo.org/id/dataset-parameter/744860.rdf
Name: STN
Units: unitless
Description: <p>station identifier from cruise</p>
http://lod.bco-dmo.org/id/dataset-parameter/744861.rdf
Name: date
Units: unitless
Description: <p>date; formatted as yyyy-mm-dd</p>
http://lod.bco-dmo.org/id/dataset-parameter/744862.rdf
Name: DEPTH
Units: meters
Description: <p>sample depth</p>
http://lod.bco-dmo.org/id/dataset-parameter/744863.rdf
Name: PRESSURE
Units: decibars
Description: <p>pressure</p>
http://lod.bco-dmo.org/id/dataset-parameter/744864.rdf
Name: latitude
Units: degrees North
Description: <p>latitude of sampling</p>
http://lod.bco-dmo.org/id/dataset-parameter/744865.rdf
Name: longitude
Units: degrees East
Description: <p>longitude of sampling</p>
http://lod.bco-dmo.org/id/dataset-parameter/744866.rdf
Name: TEMPERATURE
Units: degrees C
Description: <p>temperature</p>
http://lod.bco-dmo.org/id/dataset-parameter/744867.rdf
Name: SALINITY
Units: PSU
Description: <p>salinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/744868.rdf
Name: SIGMA_THETA
Units: kg/m3
Description: <p>sigma-theta</p>
http://lod.bco-dmo.org/id/dataset-parameter/744869.rdf
Name: SBE_OXYGEN
Units: umol/kg
Description: <p>oxygen measured by SBE</p>
http://lod.bco-dmo.org/id/dataset-parameter/744870.rdf
Name: O2_SAT_mL_L
Units: ml/L
Description: <p>oxygen saturation in milliters per liter</p>
http://lod.bco-dmo.org/id/dataset-parameter/744871.rdf
Name: O2_SAT_umol_kg
Units: umol/kg
Description: <p>oxygen saturation in micromoles per kilogram</p>
http://lod.bco-dmo.org/id/dataset-parameter/744872.rdf
Name: AOU
Units: umol/kg
Description: <p>apparent oxygen utilization</p>
http://lod.bco-dmo.org/id/dataset-parameter/744873.rdf
Name: NO3_sample_IDs
Units: unitless
Description: <p>internal reference number for sample</p>
http://lod.bco-dmo.org/id/dataset-parameter/744874.rdf
Name: sulfamic_treated
Units: unitless
Description: <p>An asterisk indicates a sample was treated with sulfamic acid to remove nitrite prior to nitrate isotopic analysis</p>
http://lod.bco-dmo.org/id/dataset-parameter/744875.rdf
Name: d15N_NO3
Units: per mil vs. N2
Description: <p>delta 15N of nitrate</p>
http://lod.bco-dmo.org/id/dataset-parameter/744876.rdf
Name: d15N_NO3_sd
Units: per mil
Description: <p>standard deviation of d15N_NO3</p>
http://lod.bco-dmo.org/id/dataset-parameter/744877.rdf
Name: d18O_NO3
Units: per mil vs. VSMOW
Description: <p>delta 18O of nitrate</p>
http://lod.bco-dmo.org/id/dataset-parameter/744878.rdf
Name: d18O_NO3_sd
Units: per mil
Description: <p>standard deviation of d18O_NO3</p>
http://lod.bco-dmo.org/id/dataset-parameter/744879.rdf
Name: d15N_NO2
Units: per mil vs. N2
Description: <p>delta 15N of nitrite</p>
http://lod.bco-dmo.org/id/dataset-parameter/744880.rdf
Name: d15N_NO2_sd
Units: per mil
Description: <p>standard deviation of d15N_NO2</p>
http://lod.bco-dmo.org/id/dataset-parameter/744881.rdf
Name: d18O_NO2
Units: per mil vs. VSMOW
Description: <p>d18O of nitrite</p>
http://lod.bco-dmo.org/id/dataset-parameter/744882.rdf
Name: d18O_NO2_sd
Units: per mil
Description: <p>standard deviation of d18O_NO2</p>
http://lod.bco-dmo.org/id/dataset-parameter/744883.rdf
Name: N2O_sample_ID_1
Units: unitless
Description: <p>internal reference number for sample (replicate 1 of 2)</p>
http://lod.bco-dmo.org/id/dataset-parameter/744884.rdf
Name: N2O_sample_ID_2
Units: unitless
Description: <p>internal reference number for sample (replicate 2 of 2)</p>
http://lod.bco-dmo.org/id/dataset-parameter/744885.rdf
Name: N2O_conc
Units: nM
Description: <p>N2O concentration</p>
http://lod.bco-dmo.org/id/dataset-parameter/744886.rdf
Name: N2O_conc_sd
Units: nM
Description: <p>standard deviation of N2O_conc</p>
http://lod.bco-dmo.org/id/dataset-parameter/744887.rdf
Name: N2O_SP
Units: per mil
Description: <p>N2O site preference</p>
http://lod.bco-dmo.org/id/dataset-parameter/744888.rdf
Name: N2O_SP_sd
Units: per mil
Description: <p>standard deviation of N2O_SP</p>
http://lod.bco-dmo.org/id/dataset-parameter/744889.rdf
Name: d15N_N2O
Units: per mil vs. N2
Description: <p>delta 15N of N2O</p>
http://lod.bco-dmo.org/id/dataset-parameter/744890.rdf
Name: d15N_N2O_sd
Units: per mil
Description: <p>standard deviation of d15N_N2O</p>
http://lod.bco-dmo.org/id/dataset-parameter/744891.rdf
Name: d18O_N2O
Units: per mil vs. VSMOW
Description: <p>delta 18O of N2O</p>
http://lod.bco-dmo.org/id/dataset-parameter/744892.rdf
Name: d18O_N2O_sd
Units: per mil
Description: <p>standard deviation of d18O_N2O</p>
http://lod.bco-dmo.org/id/dataset-parameter/744893.rdf
Name: d15Na
Units: per mil vs. N2
Description: <p>delta 15N of N2O-alpha</p>
http://lod.bco-dmo.org/id/dataset-parameter/744894.rdf
Name: d15Na_sd
Units: per mil
Description: <p>standard deviation of d15Na</p>
http://lod.bco-dmo.org/id/dataset-parameter/744895.rdf
Name: d15Nb
Units: per mil vs. N2
Description: <p>delta 15N of N2O-beta</p>
http://lod.bco-dmo.org/id/dataset-parameter/744896.rdf
Name: d15Nb_sd
Units: per mil
Description: <p>standard deviation of d15Nb</p>
http://lod.bco-dmo.org/id/dataset-parameter/744897.rdf
Name: Kelvin
Units: K
Description: <p>Temperature in Kelvin</p>
http://lod.bco-dmo.org/id/dataset-parameter/744898.rdf
Name: ln_Ko
Units: unitless
Description: <p>natural logarithm of Ko, the solubility of N2O in seawater as per Weiss and Price, 1980</p>
http://lod.bco-dmo.org/id/dataset-parameter/744899.rdf
Name: Ko
Units: mol N2O/kg/atm
Description: <p>solubility of N2O in seawater, as per Weiss and Price, 1980</p>
http://lod.bco-dmo.org/id/dataset-parameter/744900.rdf
Name: N2O_sat_mol_kg
Units: mol N2O/kg
Description: <p>concentration of N2O at equilibrium with atmosphere at in situ temperature and salinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/744901.rdf
Name: N2O_sat_nmol_L
Units: nmol N2O/L
Description: <p>concentration of N2O at equilibrium with atmosphere at in situ temperature and salinity, converted to nmol/L</p>
http://lod.bco-dmo.org/id/dataset-parameter/744902.rdf
Name: delta_N2O
Units: nmol N2O/L
Description: <p>N2O supersaturation, deltaN2O = [N2O]obs - [N2O]sat</p>
http://lod.bco-dmo.org/id/dataset-parameter/744903.rdf
Name: ESPIW
Units: %
Description: <p>% Eastern South Pacific Intermediate Water, as per Peters et al., 2018 Deep Sea Research II</p>
http://lod.bco-dmo.org/id/dataset-parameter/744904.rdf
Name: ESSW
Units: %
Description: <p>% Equatorial Subsurface Water, as per Peters et al., 2018 Deep Sea Research II</p>
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
129954
https://darchive.mblwhoilibrary.org/bitstream/1912/23831/1/dataset-744679_etsp-2013-no3-no2-n2o__v1.tsv
download
https://doi.org/10.1575/1912/bco-dmo.744679.1
download
onLine
dataset
<p>Samples were collected from a standard Niskin bottle rosette.</p>
<p>Nitrate isotope analyses were conducted by denitrifier method (Sigman et al., 2001; Casciotti et al., 2002) with updates (McIlviin and Casciotti, 2011). Nitrite was removed from samples containing more than 0.1 uM nitrite, using sulfuric acid (Granger and Sigman, 2009). Standards include USGS32, USGS34, and USGS35.</p>
<p>Nitrite isotope analyses were conducted by azide method (McIlvin and Altabet, 2005). Standards include N23, N7373, and N10219.</p>
<p>Nitrous oxide isotope analyses were conducted as described in McIlvin and Casciotti, 2010. N2O isotope measurements were calibrated against a laboratory N2O working gas.</p>
<p>The water mass analysis for the oxygen deficient zone waters was conducted as described in Peters et al., 2018, Deep Sea Research II, Estimating fixed nitrogen loss and associated isotope effects using concentration and isotope measurements of NO3-, NO2-, and N2 from the Eastern Tropical South Pacific oxygen deficient zone.</p>
Specified by the Principal Investigator(s)
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
ThermoFinnigan DeltaPLUS XP
ThermoFinnigan DeltaPLUS XP
PI Supplied Instrument Name: ThermoFinnigan DeltaPLUS XP PI Supplied Instrument Description:All isotopic measurements were made on a ThermoFinnigan DeltaPLUS XP isotope ratio mass spectrometer. Instrument Name: Isotope-ratio Mass Spectrometer Instrument Short Name:IR Mass Spec; IRMS Instrument Description: The Isotope-ratio Mass Spectrometer is a particular type of mass spectrometer used to measure the relative abundance of isotopes in a given sample (e.g. VG Prism II Isotope Ratio Mass-Spectrometer). Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB16/
Cruise: NBP1305
NBP1305
Community Standard Description
International Council for the Exploration of the Sea
RVIB Nathaniel B. Palmer
vessel
Community Standard Description
International Council for the Exploration of the Sea
RVIB Nathaniel B. Palmer
vessel