http://lod.bco-dmo.org/id/dataset/751211
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2018-12-18
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
The ratio of 13C to 12C of dissolved inorganic carbon (DIC) measured during the GEOTRACES Arctic cruise (HLY 1502, ARC01) during Fall 2015
2019-09-20
publication
2019-09-20
revision
Marine Biological Laboratory/Woods Hole Oceanographic Institution Library (MBLWHOI DLA)
2021-05-12
publication
https://doi.org/10.26008/1912/bco-dmo.751211.2
Paul Quay
University of Washington
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
Cite this dataset as: Quay, P. (2021) The ratio of 13C to 12C of dissolved inorganic carbon (DIC) measured during the GEOTRACES Arctic cruise (HLY 1502, ARC01) during Fall 2015. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 2) Version Date 2019-09-20 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.751211.2 [access date]
The ratio of 13C to 12C of dissolved inorganic carbon (DIC) measured during the GEOTRACES Arctic cruise (HLY 1502, ARC01) during Fall 2015 Dataset Description: Methods and Sampling: <p>The seawater samples were collected by transferring water from a Niskin bottle into a pre-washed and pre-baked Pyrex 250ml bottle with a ground glass top. The water was overflowed for at least one bottle volume. The sample was poisoned by adding 100uL of saturated HgCl2 solution. A greased glass stopper was inserted and rotated to insure an air tight seal. The bottle was stored at room temperature. Tests in the lab have indicated that a sample collected correctly can be stored for more than 1 year without significant offset in the d13C value.</p>
<p>The d13C value of dissolved inorganic carbon (DIC) in seawater was measured by: (i) drawing the seawater sample into an evacuated gravimetrically calibrated burette; (ii) transferring the sample to a helium bubbler; (iii) acidifying with 50% phosphoric acid; (iv) stripping with 99.999% pure He at a flow rate of 40 cubic cm per minute for 30 minutes and collecting the CO2 at -196 °C, after trapping out water at -78 °C. The d13C of the CO2 gas was measured on a Thermo Scientific MAT253 isotope ratio mass spectrometer. The N2O correction was less than 0.02 ‰ based on the measured mass 30/44 ratio. The d13C value is reported in per mil units (‰) relative to PDB based on working lab standards calibrated against NBS-19. The overall precision of d13C measurement was ±0.03 ‰ based on measured duplicate samples.</p>
<p>For complete sampling and analytical methodologies, refer to Quay et al. 2003.</p>
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1433349 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1433349
completed
Paul Quay
University of Washington
206-685-8061
University of Washington School of Oceanography MS 355351
Seattle
WA
98195-7940
USA
pdquay@uw.edu
pointOfContact
asNeeded
Dataset Version: 2
Unknown
EXPOCODE
SECT_ID
GEOTRC_EVENTNO
STNNBR
CASTNO
Coll_Date
TIME
LATITUDE
LONGITUDE
GEOTRC_SAMPNO
SAMPNO
BTLNBR
BTLNBR_FLAG_W
Depth
DIC_13_12_D_DELTA_BOTTLE
DIC_13_12_D_DELTA_BOTTLE_FLAG
Thermo Scientific MAT253
Niskin bottle
theme
None, User defined
EXPOCODE
Cruise identfier
event
station
cast
date
time of day
latitude
longitude
sample identification
bottle
quality flag
depth
13C to 12C ratio in DIC
featureType
BCO-DMO Standard Parameters
Isotope-ratio Mass Spectrometer
Niskin bottle
instrument
BCO-DMO Standard Instruments
HLY1502
service
Deployment Activity
Western Arctic Ocean
place
Locations
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
U.S. GEOTRACES
http://www.geotraces.org/
U.S. GEOTRACES
GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.
GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;
* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and
* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.
GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.
Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.
U.S. GEOTRACES
largerWorkCitation
program
U.S. Arctic GEOTRACES Study (GN01)
https://www.geotraces.org/
U.S. Arctic GEOTRACES Study (GN01)
<p><em>Description from NSF award abstract:</em><br />
In pursuit of its goal "to identify processes and quantify fluxes that control the distributions of key trace elements and isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions", in 2015 the International GEOTRACES Program will embark on several years of research in the Arctic Ocean. In a region where climate warming and general environmental change are occurring at amazing speed, research such as this is important for understanding the current state of Arctic Ocean geochemistry and for developing predictive capability as the regional ecosystem continues to warm and influence global oceanic and climatic conditions. The three investigators funded on this award, will manage a large team of U.S.scientists who will compete through the regular NSF proposal process to contribute their own unique expertise in marine trace metal, isotopic, and carbon cycle geochemistry to the U.S. effort. The three managers will be responsible for arranging and overseeing at-sea technical services such as hydrographic measurements, nutrient analyses, and around-the-clock management of on-deck sampling activites upon which all participants depend, and for organizing all pre- and post-cruise technical support and scientific meetings. The management team will also lead educational outreach activities for the general public in Nome and Barrow, Alaska, to explain the significance of the study to these communities and to learn from residents' insights on observed changes in the marine system. The project itself will provide for the support and training of a number of pre-doctoral students and post-doctoral researchers. Inasmuch as the Arctic Ocean is an epicenter of global climate change, findings of this study are expected to advance present capability to forecast changes in regional and globlal ecosystem and climate system functioning.</p>
<p>As the United States' contribution to the International GEOTRACES Arctic Ocean initiative, this project will be part of an ongoing multi-national effort to further scientific knowledge about trace elements and isotopes in the world ocean. This U.S. expedition will focus on the western Arctic Ocean in the boreal summer of 2015. The scientific team will consist of the management team funded through this award plus a team of scientists from U.S. academic institutions who will have successfully competed for and received NSF funds for specific science projects in time to participate in the final stages of cruise planning. The cruise track segments will include the Bering Strait, Chukchi shelf, and the deep Canada Basin. Several stations will be designated as so-called super stations for intense study of atmospheric aerosols, sea ice, and sediment chemistry as well as water-column processes. In total, the set of coordinated international expeditions will involve the deployment of ice-capable research ships from 6 nations (US, Canada, Germany, Sweden, UK, and Russia) across different parts of the Arctic Ocean, and application of state-of-the-art methods to unravel the complex dynamics of trace metals and isotopes that are important as oceanographic and biogeochemical tracers in the sea.</p>
U.S. GEOTRACES Arctic
largerWorkCitation
project
US GEOTRACES ARCTIC: Measuring stable isotopes of carbon in dissolved inorganic carbon and oxygen/argon gas ratios to show impact of organic matter export on nutrient distributions
https://osprey.bco-dmo.org/project/751214
US GEOTRACES ARCTIC: Measuring stable isotopes of carbon in dissolved inorganic carbon and oxygen/argon gas ratios to show impact of organic matter export on nutrient distributions
<p><em>NSF Award Abstract:</em><br />
A scientist from the University of Washington will participate in the 2015 U.S. GEOTRACES Arctic Ocean cruise and measure the vertical distribution of the stable isotopes of carbon found in dissolved inorganic carbon (del13C), a tracer of biogeochemical cycling. In addition, he will determine the spatial variation in the ratio of oxygen gas to argon gas (O2/Ar) in surface water samples because this ratio can be used as a proxy for organic matter export. In common with other multinational initiatives in the International GEOTRACES Program, the goals of the U.S. Arctic expedition are to identify processes and quantify fluxes that control the distributions of key trace elements and isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions. Some trace elements are essential to life, others are known biological toxins, and still others are important because they can be used as tracers of a variety of physical, chemical, and biological processes in the sea. Results from this study will further our understanding of the processes that control observed trace elements, nutrients, and the stable carbon isotopes in dissolved inorganic carbon in the present day ocean and use this information to gain information on past changes in ocean circulation on carbon cycling. This project will also provide training opportunities for undergraduate students, and results will be integrated into public outreach activities and material for class lectures.</p>
<p>A better understanding of the impact of physical and biological processes on the distribution of nutrient and trace elements in the modern ocean is critical to our interpretation of future changes in their distributions in the Arctic and their utility as proxies of circulation and biological pump conditions in the historic ocean. One key parameter needed to understand these processes is del13C of dissolved inorganic carbon, for which little to no data currently exists in the Arctic Ocean. This study will aim to measure the depth distribution of the del13C of dissolved inorganic carbon and the dissolved O2/Ar ratio in the surface layer of the ocean. These measurements will help to quantify the contributions of chemical processes and the biological pump on the spatial distribution of nutrients, trace elements, and del13C, as well as estimate organic matter export rates from the surface ocean.</p>
GEOTRACES Arctic del13C
largerWorkCitation
project
eng; USA
oceans
Western Arctic Ocean
-179.8934
179.1997
60.252
89.9876
2015-08-12
2015-10-07
From projects that focused on the following 2 locations: 1. Arctic Ocean; Sailing from Dutch Harbor to Dutch Harbor (GN01) 2. Arctic
0
BCO-DMO catalogue of parameters from The ratio of 13C to 12C of dissolved inorganic carbon (DIC) measured during the GEOTRACES Arctic cruise (HLY 1502, ARC01) during Fall 2015
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/751362.rdf
Name: EXPOCODE
Units: unitless
Description: <p>Cruise identifier</p>
http://lod.bco-dmo.org/id/dataset-parameter/751363.rdf
Name: SECT_ID
Units: unitless
Description: <p>GO SHIP Cruise Identifier</p>
http://lod.bco-dmo.org/id/dataset-parameter/751364.rdf
Name: GEOTRC_EVENTNO
Units: unitless
Description: <p>GEOTRACES event number</p>
http://lod.bco-dmo.org/id/dataset-parameter/751365.rdf
Name: STNNBR
Units: unitless
Description: <p>Station number</p>
http://lod.bco-dmo.org/id/dataset-parameter/751366.rdf
Name: CASTNO
Units: unitless
Description: <p>Cast number</p>
http://lod.bco-dmo.org/id/dataset-parameter/751367.rdf
Name: Coll_Date
Units: unitless
Description: <p>Sample collection date. Format: yyyymmdd</p>
http://lod.bco-dmo.org/id/dataset-parameter/751368.rdf
Name: TIME
Units: unitless
Description: <p>Sample collection date. Format: HHMM</p>
http://lod.bco-dmo.org/id/dataset-parameter/751369.rdf
Name: LATITUDE
Units: decimal degrees
Description: <p>Latitude</p>
http://lod.bco-dmo.org/id/dataset-parameter/751370.rdf
Name: LONGITUDE
Units: decimal degrees
Description: <p>Longitude (- value = W; + value = East)</p>
http://lod.bco-dmo.org/id/dataset-parameter/751371.rdf
Name: GEOTRC_SAMPNO
Units: unitless
Description: <p>GEOTRACES sample number</p>
http://lod.bco-dmo.org/id/dataset-parameter/751372.rdf
Name: SAMPNO
Units: unitless
Description: <p>Sample number</p>
http://lod.bco-dmo.org/id/dataset-parameter/751373.rdf
Name: BTLNBR
Units: unitless
Description: <p>Niskin bottle number</p>
http://lod.bco-dmo.org/id/dataset-parameter/751374.rdf
Name: BTLNBR_FLAG_W
Units: unitless
Description: <p>QC flag for bottle performance</p>
http://lod.bco-dmo.org/id/dataset-parameter/752618.rdf
Name: Depth
Units: meters (m)
Description: <p>Sample depth</p>
http://lod.bco-dmo.org/id/dataset-parameter/752619.rdf
Name: DIC_13_12_D_DELTA_BOTTLE
Units: per mil
Description: <p>delta13C in per mil units relative to PDB</p>
http://lod.bco-dmo.org/id/dataset-parameter/752620.rdf
Name: DIC_13_12_D_DELTA_BOTTLE_FLAG
Units: unitless
Description: <p>QC flag for DIC_13_12_D_DELTA_BOTTLE (2=good, 3=questionable, 4=bad and 6 = duplicate)</p>
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
35318
https://darchive.mblwhoilibrary.org/bitstream/1912/27111/1/dataset-751211_gn01-d13c-dic__v2.tsv
download
https://doi.org/10.26008/1912/bco-dmo.751211.2
download
onLine
dataset
<p>The seawater samples were collected by transferring water from a Niskin bottle into a pre-washed and pre-baked Pyrex 250ml bottle with a ground glass top. The water was overflowed for at least one bottle volume. The sample was poisoned by adding 100uL of saturated HgCl2 solution. A greased glass stopper was inserted and rotated to insure an air tight seal. The bottle was stored at room temperature. Tests in the lab have indicated that a sample collected correctly can be stored for more than 1 year without significant offset in the d13C value.</p>
<p>The d13C value of dissolved inorganic carbon (DIC) in seawater was measured by: (i) drawing the seawater sample into an evacuated gravimetrically calibrated burette; (ii) transferring the sample to a helium bubbler; (iii) acidifying with 50% phosphoric acid; (iv) stripping with 99.999% pure He at a flow rate of 40 cubic cm per minute for 30 minutes and collecting the CO2 at -196 °C, after trapping out water at -78 °C. The d13C of the CO2 gas was measured on a Thermo Scientific MAT253 isotope ratio mass spectrometer. The N2O correction was less than 0.02 ‰ based on the measured mass 30/44 ratio. The d13C value is reported in per mil units (‰) relative to PDB based on working lab standards calibrated against NBS-19. The overall precision of d13C measurement was ±0.03 ‰ based on measured duplicate samples.</p>
<p>For complete sampling and analytical methodologies, refer to Quay et al. 2003.</p>
Specified by the Principal Investigator(s)
<p>BCO-DMO Processing:<br />
-&nbsp;modified parameter names to conform with BCO-DMO and GEOTRACES naming conventions;<br />
- removed spaces in front of values;<br />
- formatted time to HHMM;<br />
- 20-Sept-2019: replaced previous version of data (02-Jan-2019) with version received 16-Aug-2019.</p>
Specified by the Principal Investigator(s)
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
Thermo Scientific MAT253
Thermo Scientific MAT253
PI Supplied Instrument Name: Thermo Scientific MAT253 PI Supplied Instrument Description:The d13C of the CO2 gas was measured on a Thermo Scientific MAT253 isotope ratio mass spectrometer. Instrument Name: Isotope-ratio Mass Spectrometer Instrument Short Name:IR Mass Spec; IRMS Instrument Description: The Isotope-ratio Mass Spectrometer is a particular type of mass spectrometer used to measure the relative abundance of isotopes in a given sample (e.g. VG Prism II Isotope Ratio Mass-Spectrometer). Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB16/
Niskin bottle
Niskin bottle
PI Supplied Instrument Name: Niskin bottle PI Supplied Instrument Description:The seawater samples were collected by transferring water from a Niskin bottle into a pre-washed and pre-baked Pyrex 250ml bottle with a ground glass top. Instrument Name: Niskin bottle Instrument Short Name:Niskin bottle Instrument Description: A Niskin bottle (a next generation water sampler based on the Nansen bottle) is a cylindrical, non-metallic water collection device with stoppers at both ends. The bottles can be attached individually on a hydrowire or deployed in 12, 24, or 36 bottle Rosette systems mounted on a frame and combined with a CTD. Niskin bottles are used to collect discrete water samples for a range of measurements including pigments, nutrients, plankton, etc. Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0412/
Cruise: HLY1502
HLY1502
USCGC Healy
Community Standard Description
International Council for the Exploration of the Sea
USCGC Healy
vessel
HLY1502
David C. Kadko
Florida International University
https://datadocs.bco-dmo.org/docs/302/geotraces/GEOTRACES_ARCTIC/data_docs/cruise_reports/healy1502.pdf
Report describing HLY1502
USCGC Healy
Community Standard Description
International Council for the Exploration of the Sea
USCGC Healy
vessel