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        <gco:CharacterString>d13C and d18O isotopic data for carbonate nodules and sedimentary carbonates in Guaymas Basin and Sonora Margin sediments Dataset Description: &amp;lt;p&amp;gt;d13C and d18O isotopic data for carbonate nodules and sedimentary carbonates in Guaymas Basin and Sonora Margin sediments collected from R/V El Puma (the Pacific Coast research vessel of the Autonomous University of Mexico) from October 14, 2014 to October 27, 2014.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Data for each core include: sample identification (core No., section number, cm within section, sample type), total sediment depth in cm, and d¹³C isotopic composition in permille. background = sediment around the nodule.&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;Sediment cores were obtained by Piston coring (using commercial PVC core liners) onboard R/V El Puma. Samples selected for carbonate isotope analyses were freeze-dried, homogenized, and roasted under vacuum to eliminate organic matter. Isotope analyses was performed on ~500 µg of sediment using a Kiel devise coupled with a Thermo MAT 253 gas ratio mass spectrometer at the University of California, Santa Cruz. Values are reported in the per mil (‰) notation relative to Vienna Pee Dee Belemnite (VPDB). Reproducibility of in-house standards is 0.07‰ for 18O and 0.03‰ for 13C.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/554980.rdf" xlink:title="OCE-0939564" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-0939564 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=0939564</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/626086.rdf" xlink:title="OCE-1449604" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1449604 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1449604</gmx:Anchor>
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The Guaymas Basin in the central Gulf of California is an active tectonic spreading center overlain with thick, organic-rich sediments. In contrast to typical deep-water, mid-ocean ridge spreading centers that have very focused magmatism and little or no sediment, magmatism in the Guaymas Basis is more broadly distributed. This broadly-distributed magmatism significantly expands the fraction of organic-rich sediments that may be subject to alteration by the magmatic heat and thus it greatly expands the range of environments that support hydrocarbon generation and microbial populations in the sediments. Recognition that magmatism is not confined to the spreading axis, but instead is distributed throughout Guaymas Basin, suggests that models for the natural sequestration of carbon, the formation of oceanic crust, and life in the subsurface in marginal rift basins should be reconsidered as this has implications for the long-term removal of atmospheric carbon dioxide (and hence potential climatic implications). The Principal Investigator of this RAPID proposal is a lead proponent on an International Ocean Discovery Program (IODP) proposal to study this system in depth through scientific ocean drilling. To properly plan this expensive IODP expedition, additional site characterization gained from sediment sampling and seismic data is required. This proposal requests funds for the Principal Investigator to participate on an already planned site survey cruise aboard the Mexican Research Vessel (RV) El Puma. The results from this cruise will provide valuable data, at an exceptionally low investment, to guide decisions about potential future scientific drilling in the Guaymas Basin.&lt;/p&gt;
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