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            <gco:CharacterString>Cite this dataset as: Teske, A., Ravelo, A. C. (2019) Radiocarbon [14C] ages of sedimentary organic matter and sedimentation rates for Guaymas Basin and Sonora Margin sediments collected from R/V El Puma, leaving Guaymas on October 14, 2014 and returning to Mazatlan on October 27, 2014. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2019-03-13 [if applicable, indicate subset used]. doi:10.1575/1912/bco-dmo.763941.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Radiocarbon [14C] ages of sedimentary organic matter and sedimentation rates for Guaymas Basin and Sonora Margin sediments Dataset Description: &amp;lt;p&amp;gt;Radiocarbon [14C] ages of sedimentary organic matter and sedimentation rates for Guaymas Basin and Sonora Margin sediments collected from R/V El Puma (the Pacific Coast research vessel of the Autonomous University of Mexico) from October 14, 2014 to October 27, 2014.&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;Sediment cores were obtained by Piston coring (using commercial PVC core liners) onboard R/V El Puma. The sediment cores were recovered during the RV El Puma cruise in October 2014. Core PO3 is from the northwestern ridge flanks [27°N 37.6759/111°W 52.5740; 1611 m depth], P10 is from ca. 1 mile west of Ringvent [27°N 30.5193/111°W 42.1722 W; 1731 m depth], core P11 is from the center of Ringvent [27°N 30.5090/111°W 40.6860, 1749 m], core P12 is from the upper Sonora Margin [27°N 52.1129/111°W 41.5902, 667 m], and core P13 is from the southeastern ridge flank of Guaymas Basin [27°N 12.4470/111°W 13.7735, 1859m]. Sedimentation rates were not inferred from cores P5 and P6 due to distortions by slumping. Measurements were made on bulk sediment without authigenic carbonate phases, and thus the majority of carbon in the samples is organic carbon produced by primary producers.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples selected for radiocarbon analyses were freeze-dried, homogenized, and acidified to remove CaCO₃, allowing for the analysis of remaining organic matter, and preventing the distortion of radiocarbon ages by methane-derived carbonates. Acidification was performed on ~200 mg of sample, which was treated with ~5ml buffered pH 5 acetic acid solution for ~24 hours to dissolve the CaCO₃. Samples were then rinsed with Milli-Q water 6 to 8 times to remove the acetic acid. Acidified samples were then freeze-dried again, re-homogenized and stored for ¹⁴C and ¹³C analysis. Radiocarbon dating was performed at Lawrence Livermore National Laboratory Center for Accelerator Mass Spectrometry, and a reservoir age of 406 years was used before conversion to calendar years using CALIB REV7.1.0. (Stuiver et al. 2019). The d¹³C values of all the acidified samples used for radiocarbon analyses were approximately -20 to -22‰, as expected from marine (primary producers) derived organic matter.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/554980.rdf" xlink:title="OCE-0939564" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-0939564 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=0939564</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/626086.rdf" xlink:title="OCE-1449604" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1449604 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1449604</gmx:Anchor>
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The Guaymas Basin in the central Gulf of California is an active tectonic spreading center overlain with thick, organic-rich sediments. In contrast to typical deep-water, mid-ocean ridge spreading centers that have very focused magmatism and little or no sediment, magmatism in the Guaymas Basis is more broadly distributed. This broadly-distributed magmatism significantly expands the fraction of organic-rich sediments that may be subject to alteration by the magmatic heat and thus it greatly expands the range of environments that support hydrocarbon generation and microbial populations in the sediments. Recognition that magmatism is not confined to the spreading axis, but instead is distributed throughout Guaymas Basin, suggests that models for the natural sequestration of carbon, the formation of oceanic crust, and life in the subsurface in marginal rift basins should be reconsidered as this has implications for the long-term removal of atmospheric carbon dioxide (and hence potential climatic implications). The Principal Investigator of this RAPID proposal is a lead proponent on an International Ocean Discovery Program (IODP) proposal to study this system in depth through scientific ocean drilling. To properly plan this expensive IODP expedition, additional site characterization gained from sediment sampling and seismic data is required. This proposal requests funds for the Principal Investigator to participate on an already planned site survey cruise aboard the Mexican Research Vessel (RV) El Puma. The results from this cruise will provide valuable data, at an exceptionally low investment, to guide decisions about potential future scientific drilling in the Guaymas Basin.&lt;/p&gt;
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&amp;lt;p&amp;gt;Samples selected for radiocarbon analyses were freeze-dried, homogenized, and acidified to remove CaCO₃, allowing for the analysis of remaining organic matter, and preventing the distortion of radiocarbon ages by methane-derived carbonates. Acidification was performed on ~200 mg of sample, which was treated with ~5ml buffered pH 5 acetic acid solution for ~24 hours to dissolve the CaCO₃. Samples were then rinsed with Milli-Q water 6 to 8 times to remove the acetic acid. Acidified samples were then freeze-dried again, re-homogenized and stored for ¹⁴C and ¹³C analysis. Radiocarbon dating was performed at Lawrence Livermore National Laboratory Center for Accelerator Mass Spectrometry, and a reservoir age of 406 years was used before conversion to calendar years using CALIB REV7.1.0. (Stuiver et al. 2019). The d¹³C values of all the acidified samples used for radiocarbon analyses were approximately -20 to -22‰, as expected from marine (primary producers) derived organic matter.&amp;lt;/p&amp;gt;</gco:CharacterString>
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The sedimentation Rate (Sed_Rate) is based on using the youngest and oldest samples to obtain an average for the dated part of the core.&amp;lt;br /&amp;gt;
** = outlier&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;BCO-DMO Processing:&amp;lt;br /&amp;gt;
- copied values from merged cells into each row;&amp;lt;br /&amp;gt;
- modified column headers (replaced spaces with underscores, renamed standard deviation columns for clarity);&amp;lt;br /&amp;gt;
- separated original C14_age column into two: one for the value and one for the stdev.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmd:code>
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    <gmi:description>
      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54060.rdf" xlink:title="R/V El Puma" xlink:actuate="onRequest">vessel</gmx:Anchor>
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                      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/deployment/661688.rdf" xlink:title="Cruise" xlink:actuate="onRequest">Guaymas_2014</gmx:Anchor>
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                          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/person/51412.rdf" xlink:actuate="onRequest">Andreas Teske</gmx:Anchor>
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                        <gmd:organisationName>
                          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/affiliation/20.rdf" xlink:title="Affiliation" xlink:actuate="onRequest">University of North Carolina at Chapel Hill</gmx:Anchor>
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                        <gmd:CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="principalInvestigator"/>
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      <gmd:MD_Identifier>
        <gmd:code>
          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54060.rdf"
           xlink:actuate="onRequest">R/V El Puma</gmx:Anchor>
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      </gmd:MD_Identifier>
    </gmi:identifier>
    <gmi:description>
      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54060.rdf" xlink:title="R/V El Puma" xlink:actuate="onRequest">vessel</gmx:Anchor>
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    <gmi:instrument gco:nilReason="unknown"/>
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