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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/764875.rdf" xlink:actuate="onRequest">Pore water chemical concentration data and location from push cores collected by the ROV Jason II on dive J2-773 from cruise MSM37 on R/V Maria S. Merian from March to April 2014</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Wheat, C. G. (2019) Pore water chemical concentration data and location from push cores collected by the ROV Jason II on dive J2-773 from cruise MSM37 on R/V Maria S. Merian from March to April 2014. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2019-04-11 [if applicable, indicate subset used]. doi:10.1575/1912/bco-dmo.764875.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Pore water chemical concentration data and location from push cores collected by the ROV Jason II on dive J2-773 Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;Push cores were collected by the ROV Jason II on dive J2-773 on 11-April-2014.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Pore waters were extracted in a cold room at 4C using acid-rinsed, washed and dried rhizomes. The first 2 ml of fluid was discarded, then the remaining fluid was filtered through a 0.45 micron membrane and stored in hot acid (60C) washed high-density polyethylene bottles. Fluids were analyzed by electrode (pH), titration (chlorinate, calcium, and alkalinity), colorimetric (nitrate), inductively coupled optical emission spectroscopy (ICPOES), and inductively coupled mass spectroscopy (ICPMS). Precision was generally 0.2% for chlorinate and calcium titrations, 2% for alkalinity titrations, 0.01&amp;amp;nbsp; for pH, 5% for nitrate determinations, 2% for ICPOES measurements and 5% for ICPMS measurements. All measurements were above detection limits with the exception of Mn (0.1 umol/kg) and Fe (0.01 mol/kg).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Careful consideration of these data should examine the potential of sampling artifacts for many of the solutes. We believe, for example, the Ca difference from bottom seawater values is an artifact of sample handling, resulting from the movement of sediment with carbonate present to the ship where the sediment was handled. Other solutes are likewise probably affected.&amp;lt;/p&amp;gt;</gco:CharacterString>
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Japan's Ministry of Education, Culture, Sports, Science and Technology (MEXT) 
The European Consortium for Ocean Research Drilling (ECORD)

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Current estimates suggest that the volume of ocean crust capable of sustaining life is comparable in magnitude to that of the oceans. To date, there is little understanding of the composition or functional capacity of microbial communities in the sub-seafloor, or their influence on the chemistry of the oceans and subsequent consequences for global biogeochemical cycles. This project focuses on understanding the relationship between microbial communities and fluid chemistry in young crustal fluids that are responsible for the transport of energy, nutrients, and organisms in the crust. Specifically, the PIs will couple microbial activity measurements, including autotrophic carbon, nitrogen and sulfur metabolisms as well as mineral oxide reduction, with quantitative assessments of functional gene expression and geochemical transformations in basement fluids. Through a comprehensive suite of in situ and shipboard analyses, this research will yield cross-disciplinary advances in our understanding of the microbial ecology and geochemistry of the sub-seafloor biosphere. The focus of the effort is at North Pond, an isolated sediment pond located on ridge flank oceanic crust 7-8 million years old on the western side of the Mid-Atlantic Ridge. North Pond is currently the target for drilling on IODP expedition 336, during which it will be instrumented with three sub-seafloor basement observatories.&lt;/p&gt;
&lt;p&gt;The project will leverage this opportunity for targeted and distinct sampling at North Pond on two German-US research cruises to accomplish three main objectives:&lt;/p&gt;
&lt;p&gt;1. to determine if different basement fluid horizons across North Pond host distinct microbial communities and chemical milieus and the degree to which they change over a two-year post-drilling period.&lt;/p&gt;
&lt;p&gt;2. to quantify the extent of autotrophic metabolism via microbially-mediated transformations in carbon, nitrogen, and sulfur species in basement fluids at North Pond.&lt;/p&gt;
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&lt;p&gt;There are no data about microbial communities in ubiquitous cold, oceanic crust, the emphasis of the proposed work. This is an interdisciplinary project at the interface of microbial ecology, chemistry, and deep-sea oceanography with direct links to international and national research and educational organizations.&lt;/p&gt;</gco:CharacterString>
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	Name: Core
	Units: unitless
	Description: &lt;p&gt;Core identification number&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/764937.rdf
	Name: Depth
	Units: centimeters (cm)
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http://lod.bco-dmo.org/id/dataset-parameter/764938.rdf
	Name: pH
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	Name: alkalinity
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http://lod.bco-dmo.org/id/dataset-parameter/764940.rdf
	Name: Nitrate
	Units: micromoles per kilogram (umol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764941.rdf
	Name: Chlorinity
	Units: millimoles per kilogram (mmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764942.rdf
	Name: Ca
	Units: millimoles per kilogram (mmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764943.rdf
	Name: B
	Units: micromoles per kilogram (umol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764944.rdf
	Name: Mn
	Units: micromoles per kilogram (umol/kg)
	Description: &lt;p&gt;Manganese (Mn) concentration; measured by ICP-OES&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/764945.rdf
	Name: Fe
	Units: micromoles per kilogram (umol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764946.rdf
	Name: Si
	Units: micromoles per kilogram (umol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764947.rdf
	Name: Sr
	Units: micromoles per kilogram (umol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764948.rdf
	Name: Li
	Units: micromoles per kilogram (umol/kg)
	Description: &lt;p&gt;Lithium (Li) concentration; measured by ICP-OES&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/764949.rdf
	Name: S
	Units: millimoles per kilogram (mmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764950.rdf
	Name: Na
	Units: millimoles per kilogram (mmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764951.rdf
	Name: Mg
	Units: millimoles per kilogram (mmol/kg)
	Description: &lt;p&gt;Magnesium (Mg) concentration; measured by ICP-OES&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/764952.rdf
	Name: K
	Units: millimoles per kilogram (mmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764953.rdf
	Name: V
	Units: nanomoles per kilogram (nmol/kg)
	Description: &lt;p&gt;Vanadium (V) concentration; measured by ICPMS&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/764954.rdf
	Name: Rb
	Units: micromoles per kilogram (umol/kg)
	Description: &lt;p&gt;Rubidium (Rb) concentration; measured by ICPMS&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/764955.rdf
	Name: Mo
	Units: nanomoles per kilogram (nmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764956.rdf
	Name: Cs
	Units: nanomoles per kilogram (nmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764957.rdf
	Name: Ba
	Units: nanomoles per kilogram (nmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764958.rdf
	Name: U
	Units: nanomoles per kilogram (nmol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/764959.rdf
	Name: Lat
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http://lod.bco-dmo.org/id/dataset-parameter/764960.rdf
	Name: Lon
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http://lod.bco-dmo.org/id/dataset-parameter/764961.rdf
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&amp;lt;p&amp;gt;Careful consideration of these data should examine the potential of sampling artifacts for many of the solutes. We believe, for example, the Ca difference from bottom seawater values is an artifact of sample handling, resulting from the movement of sediment with carbonate present to the ship where the sediment was handled. Other solutes are likewise probably affected.&amp;lt;/p&amp;gt;</gco:CharacterString>
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