Mercury and methylmercury concentrations in melt pond water from samples collected during the GEOTRACES Arctic Ocean cruise in 2015 (HLY1502, GN01).

Website: https://www.bco-dmo.org/dataset/779280
Data Type: Cruise Results
Version: 1
Version Date: 2021-01-25

Project
» U.S. Arctic GEOTRACES Study (U.S. GEOTRACES Arctic)
» Collaborative Research: GEOTRACES Arctic Section: Determination of atmospheric wet and dry deposition and air-sea exchange of mercury species from coastal and offshore waters (GEOTRACES Arctic Atmos Hg)

Program
» U.S. GEOTRACES (U.S. GEOTRACES)
ContributorsAffiliationRole
Mason, Robert P.University of Connecticut (UConn)Principal Investigator
Rauch, ShannonWoods Hole Oceanographic Institution (WHOI BCO-DMO)BCO-DMO Data Manager

Abstract
The data include measurements of mercury and methylmercury concentrations in melt pond water from the GEOTRACES Arctic Ocean cruise in 2015 (HLY1502, GN01).


Coverage

Spatial Extent: N:89.9903 E:-148.894 S:82.5039 W:-176.761
Temporal Extent: 2015-09-11 - 2015-09-14

Dataset Description

The data include measurements of mercury and methylmercury concentrations in melt pond water from the GEOTRACES Arctic Ocean cruise in 2015 (HLY1502, GN01).


Acquisition Description

Methodology: Details of the methods for the cruise are given in DiMento et al. (2019). Details of the overall method and approach for dissolved gaseous mercury and atmospheric mercury methods are given in Andersson et al. (2008), Mason et al. (2017), Soerensen et al. (2014), and Soerensen et al. (2013). Analytical methods are detailed in DiMento et al. (2019) with additional information in the papers listed above and in Munson et al. (2014), Morton et al. (2013), and Gichuki & Mason (2014). See "Related Publications" below for complete citations.

Sampling Procedures: Melt pond water samples were collected using a battery powered peristaltic pump (Pegasus Alexis) to fill acid-washed 20 L carboys (low density polyethylene – LDPE) through C-Flex tubing (Masterflex) that had been acid-cleaned with 0.1 M ultrapure HCl and thoroughly rinsed with ultrapure water before use (Marsay et al., 2018). At each melt pond, the tubing was used as a probe to ascertain that the pond did indeed have a bottom layer of ice, although it was not possible to determine any connectivity with seawater through flaws in the ice, or the presence of a "false bottom" formed from refreezing of fresh meltwater. Samples for TE analysis were also collected from snow, sea ice, and from seawater beneath the sea ice at each station. Snow samples for TE analysis were collected using an acid-cleaned polyethylene shovel to transfer the snow column into an acid-cleaned LDPE drum insert (CDF Corporation), which was held inside a plastic bucket, and which was subsequently sealed before transfer to the ship. The sample was allowed to melt at room temperature on the ship (8–10 h), and then homogenized by gentle shaking (Marsay et al., 2018).

Methylmercury concentrations were determined following the ascorbic acid-assisted direct ethylation method (Munson et al., 2014) using a Tekran 2700 instrument and autosampler to automate the purging, trapping, and detection via cold vapor atomic fluorescence spectroscopy (CVAFS). Samples were thawed then acidified to 1% (v/v) H2SO4 and left to digest overnight before neutralizing with 8N potassium hydroxide (KOH), buffering with 4M acetate, adding 2.5% (w/v) ascorbic acid and finally 1% (w/v) sodium tetraethyl borate (NaTEB) to ethylate the methylmercury. Total mercury concentrations were determined by dual gold-amalgamation CVAFS utilizing a Tekran 2600 instrument in accordance with U.S. EPA Method 1631. Briefly, waters were digested with bromine monochloride (BrCl) followed by a pre-reduction step with hydroxylamine hydrochloride (NH₂OH·HCl). Inorganic Hg(II) was then reduced to Hg⁰ using stannous chloride (SnCl₂) prior to automated analysis on the Tekran.


Processing Description

QA/QC: Funnel rinse blanks and distilled water blanks were analyzed for total mercury and methylmercury to assess the blanks. Concentrations were based on a standard calibration curve and verified using standard addition techniques. Methylmercury concentrations were determined following the ascorbic cid-assisted direct ethylation method (Munson et al., 2014) using a Tekran 2700 instrument and autosampler to automate the purging, trapping, and detection via cold vapor atomic fluorescence spectroscopy (CVAFS). Sample concentrations were corrected (for matrix spike recoveries, which averaged 82%) with a typical relative standard deviation (RSD) of 10%. Average method detection limits (MDL) were <10 fM. For total mercury, matrix spike recoveries averaged 98 ± 9%, and the MDL was 0.25 pM. Method detection limits for aerosols were about 0.1 pg m-3 for total mercury and 2 fg m-3 for methylmercury, based on the average volume of air filtered and the volume of digest analyzed.

BCO-DMO Processing:
- modified parameter names to conform with BCO-DMO and GEOTRACES naming conventions;
- formatted dates to yyyy-mm-dd;
- added date-time column in ISO8601 format;
- filled blanks with "nd" (no data);
- 2021-01-25: renamed fields with the GEOTRACES DOoR barcodes.


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Related Publications

Andersson, M. E., Gårdfeldt, K., & Wängberg, I. (2008). A description of an automatic continuous equilibrium system for the measurement of dissolved gaseous mercury. Analytical and Bioanalytical Chemistry, 391(6), 2277–2282. doi:10.1007/s00216-008-2127-4
Methods
DiMento, B. P., Mason, R. P., Brooks, S., & Moore, C. (2019). The impact of sea ice on the air-sea exchange of mercury in the Arctic Ocean. Deep Sea Research Part I: Oceanographic Research Papers, 144, 28–38. doi:10.1016/j.dsr.2018.12.001
Methods
Gichuki, S. W., & Mason, R. P. (2014). Wet and dry deposition of mercury in Bermuda. Atmospheric Environment, 87, 249–257. doi:10.1016/j.atmosenv.2014.01.025
Methods
Hammerschmidt, C. R., & Fitzgerald, W. F. (2006). Bioaccumulation and Trophic Transfer of Methylmercury in Long Island Sound. Archives of Environmental Contamination and Toxicology, 51(3), 416–424. doi:10.1007/s00244-005-0265-7
Methods
Marsay, C. M., Aguilar-Islas, A., Fitzsimmons, J. N., Hatta, M., Jensen, L. T., John, S. G., … Buck, C. S. (2018). Dissolved and particulate trace elements in late summer Arctic melt ponds. Marine Chemistry, 204, 70–85. doi:10.1016/j.marchem.2018.06.002
Methods
Marsay, C. M., Kadko, D., Landing, W. M., Morton, P. L., Summers, B. A., & Buck, C. S. (2018). Concentrations, provenance and flux of aerosol trace elements during US GEOTRACES Western Arctic cruise GN01. Chemical Geology. doi:10.1016/j.chemgeo.2018.06.007
Methods
Mason, R. P., Hammerschmidt, C. R., Lamborg, C. H., Bowman, K. L., Swarr, G. J., & Shelley, R. U. (2017). The air-sea exchange of mercury in the low latitude Pacific and Atlantic Oceans. Deep Sea Research Part I: Oceanographic Research Papers, 122, 17–28. doi:10.1016/j.dsr.2017.01.015
Methods
Morton, P. L., Landing, W. M., Hsu, S.-C., Milne, A., Aguilar-Islas, A. M., Baker, A. R., … Zamora, L. M. (2013). Methods for the sampling and analysis of marine aerosols: results from the 2008 GEOTRACES aerosol intercalibration experiment. Limnology and Oceanography: Methods, 11(2), 62–78. doi:10.4319/lom.2013.11.62
Methods
Munson, K. M., Babi, D., & Lamborg, C. H. (2014). Determination of monomethylmercury from seawater with ascorbic acid-assisted direct ethylation. Limnology and Oceanography: Methods, 12(1), 1–9. doi:10.4319/lom.2014.12.1
Methods
Soerensen, A. L., Mason, R. P., Balcom, P. H., & Sunderland, E. M. (2013). Drivers of Surface Ocean Mercury Concentrations and Air–Sea Exchange in the West Atlantic Ocean. Environmental Science & Technology, 47(14), 7757–7765. doi:10.1021/es401354q
General
Soerensen, A. L., Mason, R. P., Balcom, P. H., Jacob, D. J., Zhang, Y., Kuss, J., & Sunderland, E. M. (2014). Elemental Mercury Concentrations and Fluxes in the Tropical Atmosphere and Ocean. Environmental Science & Technology, 48(19), 11312–11319. doi:10.1021/es503109p
Methods

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Parameters

ParameterDescriptionUnits
Station_IDStation number unitless
Event_IDGEOTRACES event number unitless
Sample_IDGEOTRACES sample number unitless
LatitudeLatitude; positive values = North decimal degrees
LongitudeLongitude; positive values = East decimal degrees
DateDate; format: yyyy-mm-dd unitless
TimeTime; format: HH:MM unitless
ISO_DateTime_UTCDate and time (UTC) formatted to ISO8601 standard; format: yyyy-mm-ddTHH:MM unitless
Hg_Me_D_CONC_MELTPOND_PUMP_nh4cocmethylmercury concentration in melt pond water sample picomolar (pM)
Hg_T_CONC_MELTPOND_PUMP_87d1rbtotal mercury concentration in melt pond water samples picomolar (pM)


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Instruments

Dataset-specific Instrument Name
Tekran 2537B mercury analyzer
Generic Instrument Name
Cold Vapor Atomic Fluorescence Spectrophotometer
Generic Instrument Description
A Cold Vapor Atomic Fluorescent Spectrophotometer (CVAFS) is an instrument used for quantitative determination of volatile heavy metals, such as mercury. CVAFS make use of the characteristic of mercury that allows vapor measurement at room temperature. Mercury atoms in an inert carrier gas are excited by a collimated UV light source at a particular wavelength. As the atoms return to their non-excited state they re-radiate their absorbed energy at the same wavelength. The fluorescence may be detected using a photomultiplier tube or UV photodiode.

Dataset-specific Instrument Name
peristaltic pump
Generic Instrument Name
Pump
Generic Instrument Description
A pump is a device that moves fluids (liquids or gases), or sometimes slurries, by mechanical action. Pumps can be classified into three major groups according to the method they use to move the fluid: direct lift, displacement, and gravity pumps

Dataset-specific Instrument Name
Tekran 2600; Tekran 2700
Generic Instrument Name
Automated Mercury Analysis System
Dataset-specific Description
Tekran 2600 automated sampler for total mercury and Tekran 2700 automated sampler for methylmercury
Generic Instrument Description
Examples include Tekran Models 2600 and 2700 


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Deployments

HLY1502

Website
Platform
USCGC Healy
Report
Start Date
2015-08-09
End Date
2015-10-12
Description
Arctic transect encompassing Bering and Chukchi Shelves and the Canadian, Makarov and Amundsen sub-basins of the Arctic Ocean. The transect started in the Bering Sea (60°N) and traveled northward across the Bering Shelf, through the Bering Strait and across the Chukchi shelf, then traversing along 170-180°W across the Alpha-Mendeleev and Lomonosov Ridges to the North Pole (Amundsen basin, 90°N), and then back southward along ~150°W to terminate on the Chukchi Shelf (72°N). Additional cruise information is available in the GO-SHIP Cruise Report (PDF) and from the Rolling Deck to Repository (R2R): https://www.rvdata.us/search/cruise/HLY1502


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Project Information

U.S. Arctic GEOTRACES Study (U.S. GEOTRACES Arctic)


Coverage: Arctic Ocean; Sailing from Dutch Harbor to Dutch Harbor (GN01)


Description from NSF award abstract:
In pursuit of its goal "to identify processes and quantify fluxes that control the distributions of key trace elements and isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions", in 2015 the International GEOTRACES Program will embark on several years of research in the Arctic Ocean. In a region where climate warming and general environmental change are occurring at amazing speed, research such as this is important for understanding the current state of Arctic Ocean geochemistry and for developing predictive capability as the regional ecosystem continues to warm and influence global oceanic and climatic conditions. The three investigators funded on this award, will manage a large team of U.S.scientists who will compete through the regular NSF proposal process to contribute their own unique expertise in marine trace metal, isotopic, and carbon cycle geochemistry to the U.S. effort. The three managers will be responsible for arranging and overseeing at-sea technical services such as hydrographic measurements, nutrient analyses, and around-the-clock management of on-deck sampling activites upon which all participants depend, and for organizing all pre- and post-cruise technical support and scientific meetings. The management team will also lead educational outreach activities for the general public in Nome and Barrow, Alaska, to explain the significance of the study to these communities and to learn from residents' insights on observed changes in the marine system. The project itself will provide for the support and training of a number of pre-doctoral students and post-doctoral researchers. Inasmuch as the Arctic Ocean is an epicenter of global climate change, findings of this study are expected to advance present capability to forecast changes in regional and globlal ecosystem and climate system functioning.

As the United States' contribution to the International GEOTRACES Arctic Ocean initiative, this project will be part of an ongoing multi-national effort to further scientific knowledge about trace elements and isotopes in the world ocean. This U.S. expedition will focus on the western Arctic Ocean in the boreal summer of 2015. The scientific team will consist of the management team funded through this award plus a team of scientists from U.S. academic institutions who will have successfully competed for and received NSF funds for specific science projects in time to participate in the final stages of cruise planning. The cruise track segments will include the Bering Strait, Chukchi shelf, and the deep Canada Basin. Several stations will be designated as so-called super stations for intense study of atmospheric aerosols, sea ice, and sediment chemistry as well as water-column processes. In total, the set of coordinated international expeditions will involve the deployment of ice-capable research ships from 6 nations (US, Canada, Germany, Sweden, UK, and Russia) across different parts of the Arctic Ocean, and application of state-of-the-art methods to unravel the complex dynamics of trace metals and isotopes that are important as oceanographic and biogeochemical tracers in the sea.


Collaborative Research: GEOTRACES Arctic Section: Determination of atmospheric wet and dry deposition and air-sea exchange of mercury species from coastal and offshore waters (GEOTRACES Arctic Atmos Hg)


NSF Award Abstract:
In this project, a group of investigators participating in the 2015 U.S. GEOTRACES Arctic expedition will measure concentrations of atmospherically-derived mercury in the Arctic Ocean. In common with other multinational initiatives in the International GEOTRACES Program, the goals of the U.S. Arctic expedition are to identify processes and quantify fluxes that control the distributions of key trace elements and isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions. Some trace elements are essential to life, others are known biological toxins, and still others are important because they can be used as tracers of a variety of physical, chemical, and biological processes in the sea. Mercury, primarily as methylmercury, is an element that substantially bioaccumulates through aquatic food webs and impacts neurological functions in humans and wildlife, and it is therefore critical to understand the inputs of mercury to the region. Educational activities as part of this study include training and mentoring of undergraduate and graduate students and a postdoctoral researcher. Researchers will also conduct public outreach activities about mercury impacts to local Arctic communities.

In the Arctic Ocean, subsistence local fishermen and several species of Arctic wildlife, such as beluga whales, seals and polar bears, commonly have elevated levels of methylmercury in their system. Atmospheric deposition is the major pathway of mercury input to the marine environment as both wet and dry (aerosol and gaseous ionic mercury) deposition. Therefore, measurements of mercury and a better understanding of its cycling in the Arctic Ocean are critical. This study will provide further understanding of the drivers of mercury speciation in air and surface waters, including snow/ice, melt ponds, and surface seawater and how these concentrations, and other physical and biological factors, impact deposition rates at the air-sea interface. The primary measurements to be made include a baseline of mercury measurements over the open water from the ship, and over sea-ice environments of the Arctic Ocean, which will be compared to simultaneous and historic coastal measurements, as well as model studies. Overall, results will provide the crucial data and information necessary to comprehend the role of human activity and climate change in exacerbating or ameliorating the exposure of humans and wildlife to methylmercury in the Arctic Ocean.



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Program Information

U.S. GEOTRACES (U.S. GEOTRACES)


Coverage: Global


GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.

GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;

* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and

* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.

GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.

Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.



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Funding

Funding SourceAward
NSF Division of Ocean Sciences (NSF OCE)

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