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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/831046.rdf" xlink:actuate="onRequest">Temperature, salinity, fluorescence, and dissolved O2/Ar ratios measured continuously underway onboard basin-wide transects of the North Pacific from Hong Kong to Long Beach, CA</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Palevsky, H. I., Quay, P. (2021) Temperature, salinity, fluorescence, and dissolved O2/Ar ratios measured continuously underway onboard basin-wide transects of the North Pacific from Hong Kong to Long Beach, CA. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2020-11-20 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.831046.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Measurements of temperature, salinity, fluorescence, and dissolved O2/Ar ratios from North Pacific Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Measurements&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Measurements for O2/Ar dissolved gas ratios, temperature, salinity, and fluorescence were continuously measured from an underway seawater system (10 m depth) on basin-wide transects of the North Pacific between Hong Kong and Long Beach, California onboard the M/V OOCL Tianjin and the M/V OOCL Tokyo (each individual transect has a unique Cruise ID). Sea surface temperature and salinity at the time of sample collection were determined using a Sea-Bird Electronics SBE45 thermosalinograph (TSG) installed in the ship’s seawater intake. Fluorescence was measured using a Seapoint Chlorophyll&amp;amp;nbsp;Fluorometer.&amp;amp;nbsp; This dataset presents uncalibrated data; the discrete calibration data are in https://www.bco-dmo.org/dataset/626855.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Underway measurements of O2/Ar dissolved gas ratios were made using continuous flow equilibrator inlet mass spectrometry (EIMS), following the method of Cassar et al. (2009). Water from the underway seawater system was pumped into an equilibrator cartridge (Membrana MicroModule G569, 0.75” x 1”), the headspace of which was delivered to a quadrupole mass spectrometer (Pfeiffer Prisma QMS) that measured individual ion currents at one-second intervals. To prevent biofouling that could cause respiration in the ship’s seawater lines (Juranek et al., 2010), intake lines between the anticorrosive sea chest and the sampling port were purged with bleach and freshwater between every cruise.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;NOTE:&amp;lt;/strong&amp;gt; Since the samples were collected underway on a vessel moving ~24 knots and samples for all parameters were collected by a single shiprider, ship transit from the time that the location coordinates were recorded to the time of actual sampling could reflect a transit distance offset from the recorded location of up to 40 kilometers.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Methods&amp;amp;nbsp;and Calculations&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Methods&amp;amp;nbsp;are described in detail in Clayton et al. (in preparation for JGR: Oceans).&amp;amp;nbsp;&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
To aid in interpretation of the O2/Ar data provided here, we include calculations of the air-sea flux of biological oxygen driven by the biological saturation anomaly (O2Arbiosat), termed “bioflux” by Jonsson et al. [2013]:&amp;lt;br /&amp;gt;
&amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp;Air_sea_flux = k*[O2]eq*(O2Arbiosat/100)&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Where k represents the wind speed-dependent air-sea gas transfer velocity and [O2]eq is the oxygen concentration that would be expected in the mixed layer were it in equilibrium with the atmosphere. We calculate k from daily wind speed data from the NOAA National Climatic Data Center’s multiple-satellite Blended Sea Winds product (&amp;lt;a href=&amp;quot;https://www.ncdc.noaa.gov/data-access/marineocean-data/blended-global/blended-sea-winds&amp;quot; rel=&amp;quot;noopener noreferrer&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;https://www.ncdc.noaa.gov/data-access/marineocean-data/blended-global/blended-sea-winds&amp;lt;/a&amp;gt;) following the Nightingale et al. (2000)&amp;amp;nbsp;equation and the 60-day (Reuer et al., 2007)&amp;amp;nbsp;time-dependent weighting scheme. We report k here as “Wkn” representing the weighted k value using the Nightingale algorithm. In conditions with limited influence of physical advection, entrainment, and transient changes due to non-steady state conditions over the dissolved gas residence time in the mixed layer, bioflux is equivalent to net community production. However, there are potential biases in quantifying net community production based on observed O2/Ar in dynamic western boundary current regions where steady state assumptions are likely invalid and strong vertical turbulent dissipation rates have been observed.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The following are additional details for relevant fields&amp;amp;nbsp;in this dataset:&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;TrueO2Ar&amp;lt;/strong&amp;gt;:&amp;amp;nbsp; ratio of dissolved O2/dissolved Ar in surface seawater as measured by continuous underway equilibrator inlet mass spec, and calibrated with discrete samples from existing dataset (https://www.bco-dmo.org/dataset/626855).&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;O2Arsat&amp;lt;/strong&amp;gt;:&amp;amp;nbsp;O2/Ar ratio expected if both gases were in equilibrium with the atmosphere, which is a function of Salinity and Temperature (Garcia and Gordon, 1992; Hamme and Emerson, 2007)&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;O2Arbiosat&amp;lt;/strong&amp;gt;:&amp;amp;nbsp; percent supersaturation of O2 in surface seawater, calculated from the TrueO2Ar and O2Arsat [O2Arbiosat = (TrueO2Ar/O2Arsat – 1)*100]&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;MLD&amp;lt;/strong&amp;gt;: climatological mixed layer depth from monthly World Ocean Atlas 2013 (with 1 degree gridded data)&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;Wkn&amp;lt;/strong&amp;gt;: air-sea gas transfer velocity in m/day, calculated using a relationship between wind speed and gas transfer from Nightingale et al. (2000) and the NOAA/NCDC Blended Sea Winds satellite wind speed product (Zhang et al. 2006), and using the Reuer et al. (2007) time-dependent weighting scheme and the MLD values given here.&amp;lt;/li&amp;gt;
&amp;lt;/ul&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/626073.rdf" xlink:title="OCE-0628663" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-0628663 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=0628663</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/626074.rdf" xlink:title="OCE-1259055" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1259055 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1259055</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/626076.rdf" xlink:title="A10OAR4310088" xlink:actuate="onRequest">Funding provided by NOAA Oceanic and Atmospheric Research (OAR) Climate Program Office  (NOAA OAR Climate Program) Award Number: A10OAR4310088</gmx:Anchor>
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http://lod.bco-dmo.org/id/dataset-parameter/834040.rdf
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	Units: decimal degrees
	Description: &lt;p&gt;Latitude of sample collection, South is negative&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/834041.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/834042.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/834043.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/834044.rdf
	Name: Temperature
	Units: degrees Celsius
	Description: &lt;p&gt;Sea Surface Temperature as measured by shipboard thermosalinograph (TSG)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/834045.rdf
	Name: Fluo
	Units: microgram per liter (ug/L)
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http://lod.bco-dmo.org/id/dataset-parameter/834046.rdf
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	Units: unitless
	Description: &lt;p&gt;Ratio of dissolved O2/dissolved Ar in surface seawater as measured by continuous underway equilibrator inlet mass spectrometry, and calibrated with discrete samples from existing dataset &lt;a href=&quot;https://www.bco-dmo.org/dataset/626855&quot;&gt;https://www.bco-dmo.org/dataset/626855&lt;/a&gt;&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/834047.rdf
	Name: O2Arsat
	Units: unitless
	Description: &lt;p&gt;O2/Ar ratio expected if both gases were in equilibrium with the atmosphere, which is a function of Salinity and Temperature (Garcia and Gordon, 1992; Hamme and Emerson, 2007)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/834048.rdf
	Name: O2Arbiosat
	Units: percent (%)
	Description: &lt;p&gt;Percent biological supersaturation of O2 in surface seawater, &lt;strong&gt;calculated&lt;/strong&gt; from the TrueO2Ar and O2Arsat   [O2Arbiosat = (TrueO2Ar/O2Arsat – 1)*100]. &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/834049.rdf
	Name: MLD_WOA13
	Units: meters
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http://lod.bco-dmo.org/id/dataset-parameter/834050.rdf
	Name: Wkn
	Units: meters per day (m/day)
	Description: &lt;p&gt;Air-sea gas transfer velocity in m/day, &lt;strong&gt;calculated&lt;/strong&gt; using a relationship between wind speed and gas transfer from Nightingale et al. (2000) and the NOAA/NCDC Blended Sea Winds satellite wind speed product (Zhang et al. 2006), and using the Reuer et al. (2007) time-dependent weighting scheme and the MLD values given here. &lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/834051.rdf
	Name: Air_sea_flux
	Units: millimoles O2 per meters squared per day (mmol O2 m-2 d-1)
	Description: &lt;p&gt;Exchange of oxygen between the ocean and atmosphere:  Airseaflux = (O2Arbiosat/100)*(O2sat)*wkn, where O2sat is &lt;strong&gt;calculated&lt;/strong&gt; from the solubility equation from Garcia and Gordon, 1992.&lt;/p&gt; 
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                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Measurements&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Measurements for O2/Ar dissolved gas ratios, temperature, salinity, and fluorescence were continuously measured from an underway seawater system (10 m depth) on basin-wide transects of the North Pacific between Hong Kong and Long Beach, California onboard the M/V OOCL Tianjin and the M/V OOCL Tokyo (each individual transect has a unique Cruise ID). Sea surface temperature and salinity at the time of sample collection were determined using a Sea-Bird Electronics SBE45 thermosalinograph (TSG) installed in the ship’s seawater intake. Fluorescence was measured using a Seapoint Chlorophyll&amp;amp;nbsp;Fluorometer.&amp;amp;nbsp; This dataset presents uncalibrated data; the discrete calibration data are in https://www.bco-dmo.org/dataset/626855.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Underway measurements of O2/Ar dissolved gas ratios were made using continuous flow equilibrator inlet mass spectrometry (EIMS), following the method of Cassar et al. (2009). Water from the underway seawater system was pumped into an equilibrator cartridge (Membrana MicroModule G569, 0.75” x 1”), the headspace of which was delivered to a quadrupole mass spectrometer (Pfeiffer Prisma QMS) that measured individual ion currents at one-second intervals. To prevent biofouling that could cause respiration in the ship’s seawater lines (Juranek et al., 2010), intake lines between the anticorrosive sea chest and the sampling port were purged with bleach and freshwater between every cruise.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;NOTE:&amp;lt;/strong&amp;gt; Since the samples were collected underway on a vessel moving ~24 knots and samples for all parameters were collected by a single shiprider, ship transit from the time that the location coordinates were recorded to the time of actual sampling could reflect a transit distance offset from the recorded location of up to 40 kilometers.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Methods&amp;amp;nbsp;and Calculations&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Methods&amp;amp;nbsp;are described in detail in Clayton et al. (in preparation for JGR: Oceans).&amp;amp;nbsp;&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
To aid in interpretation of the O2/Ar data provided here, we include calculations of the air-sea flux of biological oxygen driven by the biological saturation anomaly (O2Arbiosat), termed “bioflux” by Jonsson et al. [2013]:&amp;lt;br /&amp;gt;
&amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp; &amp;amp;nbsp;Air_sea_flux = k*[O2]eq*(O2Arbiosat/100)&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Where k represents the wind speed-dependent air-sea gas transfer velocity and [O2]eq is the oxygen concentration that would be expected in the mixed layer were it in equilibrium with the atmosphere. We calculate k from daily wind speed data from the NOAA National Climatic Data Center’s multiple-satellite Blended Sea Winds product (&amp;lt;a href=&amp;quot;https://www.ncdc.noaa.gov/data-access/marineocean-data/blended-global/blended-sea-winds&amp;quot; rel=&amp;quot;noopener noreferrer&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;https://www.ncdc.noaa.gov/data-access/marineocean-data/blended-global/blended-sea-winds&amp;lt;/a&amp;gt;) following the Nightingale et al. (2000)&amp;amp;nbsp;equation and the 60-day (Reuer et al., 2007)&amp;amp;nbsp;time-dependent weighting scheme. We report k here as “Wkn” representing the weighted k value using the Nightingale algorithm. In conditions with limited influence of physical advection, entrainment, and transient changes due to non-steady state conditions over the dissolved gas residence time in the mixed layer, bioflux is equivalent to net community production. However, there are potential biases in quantifying net community production based on observed O2/Ar in dynamic western boundary current regions where steady state assumptions are likely invalid and strong vertical turbulent dissipation rates have been observed.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The following are additional details for relevant fields&amp;amp;nbsp;in this dataset:&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;TrueO2Ar&amp;lt;/strong&amp;gt;:&amp;amp;nbsp; ratio of dissolved O2/dissolved Ar in surface seawater as measured by continuous underway equilibrator inlet mass spec, and calibrated with discrete samples from existing dataset (https://www.bco-dmo.org/dataset/626855).&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;O2Arsat&amp;lt;/strong&amp;gt;:&amp;amp;nbsp;O2/Ar ratio expected if both gases were in equilibrium with the atmosphere, which is a function of Salinity and Temperature (Garcia and Gordon, 1992; Hamme and Emerson, 2007)&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;O2Arbiosat&amp;lt;/strong&amp;gt;:&amp;amp;nbsp; percent supersaturation of O2 in surface seawater, calculated from the TrueO2Ar and O2Arsat [O2Arbiosat = (TrueO2Ar/O2Arsat – 1)*100]&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;MLD&amp;lt;/strong&amp;gt;: climatological mixed layer depth from monthly World Ocean Atlas 2013 (with 1 degree gridded data)&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;&amp;lt;strong&amp;gt;Wkn&amp;lt;/strong&amp;gt;: air-sea gas transfer velocity in m/day, calculated using a relationship between wind speed and gas transfer from Nightingale et al. (2000) and the NOAA/NCDC Blended Sea Winds satellite wind speed product (Zhang et al. 2006), and using the Reuer et al. (2007) time-dependent weighting scheme and the MLD values given here.&amp;lt;/li&amp;gt;
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                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Data processing:&amp;lt;/strong&amp;gt;&amp;amp;nbsp;&amp;lt;br /&amp;gt;
Data are reported as the mean over a three-minute measurement period, chosen to match the e-folding response time of O2/Ar ion current ratios for this EIMS setup. This yields a spatial resolution of ~2 km at the average ship speed of ~25 knots. For the Tokyo_3 cruise, a Loess filter with a 30-minute half-span was applied to remove high frequency instrument noise in the EIMS setup, reducing the spatial resolution to ~40 km,&amp;amp;nbsp;giving a marginal sampling for mesoscale fields. This filter was not applied to the May 2011 or July 2012 cruises in order to preserve the spatial resolution of the data.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;BCO-DMO processing&amp;lt;/strong&amp;gt;:&amp;lt;br /&amp;gt;
- Data from all cruises were combined into a single&amp;amp;nbsp;dataset with an added column for Cruise ID&amp;lt;br /&amp;gt;
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- Missing data identifier of 'nd' (no data) used&amp;lt;/p&amp;gt;</gco:CharacterString>
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Source: Department of Geosciences, Princeton University, Princeton, New Jersey 08544, USA. ncassar@princeton.edu

Abstract
The oxygen (O(2)) concentration in the surface ocean is influenced by biological and physical processes. With concurrent measurements of argon (Ar), which has similar solubility properties as oxygen, we can remove the physical contribution to O(2) supersaturation and determine the biological oxygen supersaturation. Biological O(2) supersaturation in the surface ocean reflects the net metabolic balance between photosynthesis and respiration, i.e., the net community productivity (NCP). We present a new method for continuous shipboard measurements of O(2)/Ar by equilibrator inlet mass spectrometry (EIMS). From these measurements and an appropriate gas exchange parametrization, NCP can be estimated at high spatial and temporal resolution. In the EIMS configuration, seawater from the ship's continuous intake flows through a cartridge enclosing a gas-permeable microporous membrane contactor. Gases in the headspace of the cartridge equilibrate with dissolved gases in the flowing seawater. A fused-silica capillary continuously samples headspace gases, and the O(2)/Ar ratio is measured by mass spectrometry. The ion current measurements on the mass spectrometer reflect the partial pressures of dissolved gases in the water flowing through the equilibrator. Calibration of the O(2)/Ar ion current ratio (32/40) is performed automatically every 2 h by sampling ambient air through a second capillary. A conceptual model demonstrates that the ratio of gases reaching the mass spectrometer is dependent on several parameters, such as the differences in molecular diffusivities and solubilities of the gases. Laboratory experiments and field observations performed by EIMS are discussed. We also present preliminary evidence that other gas measurements, such as N(2)/Ar and pCO(2) measurements, may potentially be performed with EIMS. Finally, we compare the characteristics of the EIMS with the previously described membrane inlet mass spectrometry (MIMS) approach.

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