http://lod.bco-dmo.org/id/dataset/839041
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2021-01-28
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
Diel carbonate and nutrient chemistry reported for different benthic reef communities under ambient and acidified conditions during summer and winter
2021-01-28
publication
2021-01-28
revision
BCO-DMO Linked Data URI
2021-01-28
creation
http://lod.bco-dmo.org/id/dataset/839041
Andreas Andersson
University of California-San Diego Scripps
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
Cite this dataset as: Page, H., Andersson, A. (2021) Diel carbonate and nutrient chemistry reported for different benthic reef communities under ambient and acidified conditions during summer and winter. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2021-01-28 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/839041 [access date]
Diel carbonate and nutrient chemistry Dataset Description: Methods and Sampling: <p><strong>General study design:</strong><br />
This experiment was designed to quantify and compare the influence of different benthic reef communities on diel seawater carbonate and nutrient chemistry under ambient and acidified conditions during summer and winter in flow-through mesocosms.</p>
<p><strong>Methods description:</strong><br />
Different coral reef benthic communities (carbonate sand, crustose coralline algae, coral, fleshy macroalgae, and a mixed community) were created in outdoor flow-through mesocosms at Hawaii Institute of Marine Biology. Diurnal seawater chemistry was measured for communities experiencing ambient or acidified (ambient pH – 0.4) seawater conditions during summer (August 2013) and winter (January 2014). Acidification treatments were achieved by CO2 (g) bubbling of the header tank. Hourly water quality measurements were taken over the course of 26-hours with water samples collected for analysis of dissolved inorganic carbon and total alkalinity every 2 hours and for inorganic nutrients every 4 hours. A total of four experiments were conducted across two seasons (Summer and Winter) and two pH treatments (ambient and acidified). Seawater chemistry data were used to calculate diurnal net community production (NCP) and net community calcification (NCC) rates using modified standard equations (Langdon et al. 2010). In addition, the attribution of these processes to diurnal pH and saturation state changes were quantified.;</p>
<p>For additional details, please see Page et al. (2016).</p>
<p><strong>Analytical Methods:</strong><br />
Seawater samples were collected by hand using 250 ml Pyrex glass bottles and immediately fixed with 100 µL HgCl2 as per standard protocols (Dickson et al. 2007). Handheld YSI multi-meter instrument was used to measure temperature, salinity, dissolved oxygen, and pH at the time of sampling. All seawater samples were transported to the Scripps Coastal and Open Ocean Biogeochemistry lab and analyzed for TA via an open-cell potentiometric acid titration system developed at Scripps Institution of Oceanography (SIO) by A. Dickson (Dickson et al. 2007) and DIC via an automated infra-red inorganic carbon analyzer (AIRICA, Marianda Inc).</p>
<p><strong>Quality Control:</strong><br />
Standard protocols were followed for sampling and analysis of seawater TA and DIC (Dickson et al. 2007). YSI multi-meter instrument was calibrated prior to each sampling period with accuracies of 0.2 °C for temperature, 1% for salinity, ±2% for dissolved oxygen saturation, 0.2 mg/L for dissolved oxygen concentration, and 0.2 for pH. The accuracy and precision of TA (-0.2 ± 3.3 μmol/kg) and DIC (-1.0 ± 2.3 μmol/kg) measurements were evaluated using certified reference materials (CRM) provided by the laboratory of A. Dickson at SIO and analyzed every 5 samples for DIC and ~15-20 samples for TA.</p>
<p><strong>Known Problems:</strong><br />
Rows where Date is&nbsp;06-01-14 and Time values are 10:14 to 10:44 (inclusive) (lines&nbsp;866-881 in original Excel file): The YSI Pro Plus Handheld Multi-meter temporarily malfunctioned, so temperature and salinity data were measured using an alternate handheld multi-meter probe.</p>
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1255042 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1255042
onGoing
Andreas Andersson
University of California-San Diego Scripps
858-822-2486
Scripps Institution of Oceanography 9500 Gilman Dr. #0244
La Jolla
CA
92093-0244
USA
aandersson@ucsd.edu
pointOfContact
asNeeded
Dataset Version: 1
Unknown
Season
Treatment
Date
Time
ISO_DateTime_UTC
MesocosmID
Community
Temp
Salinity
DO_sat
DO_conc
pH_ysi
TA
DIC
Total_N
Nitrite
Inorg_P
Silicate
Ammonia
Nitrate
pH_calc
Omega_calc
pCO2_calc
NCC
NCP
AIRICA (Marianda Inc.)
Open-cell potentiometric acid titration system
YSI Professional Plus (Pro Plus) Handheld Multiparameter
theme
None, User defined
season
treatment
date
time of day
ISO_DateTime_UTC
tank
sample description
water temperature at measurement depth
salinity
O2 saturation
dissolved Oxygen
pH
total alkalinity (TA)
dissolved inorganic Carbon
nitrate plus nitrite
Nitrite
Phosphorus
Silicate, Si(OH)4, silicic acid
Ammonia
Nitrate
Aragonite Saturation State
Partial pressure of CO2
calcification
primary production
featureType
BCO-DMO Standard Parameters
Inorganic Carbon Analyzer
Titrator
Water Quality Multiprobe
instrument
BCO-DMO Standard Instruments
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
CAREER: Biogeochemical Modification of Seawater CO2 Chemistry in Near-Shore Environments: Effect of Ocean Acidification
https://osprey.bco-dmo.org/project/737878
CAREER: Biogeochemical Modification of Seawater CO2 Chemistry in Near-Shore Environments: Effect of Ocean Acidification
<p><em>NSF Award Abstract:</em><br />
Because of well-known chemical principles, changes in the CO2 chemistry of seawater in the open ocean as a result of rising atmospheric CO2 can be predicted very accurately. On the other hand, in near-shore environments, these projections are much more difficult because the CO2 chemistry is largely modified by biogeochemical processes operating on timescales of hours to months. To make predictions on how near-shore seawater CO2 chemistry will change in response to ocean acidification (OA), it is critical to consider the relative influence of net ecosystem production (NEP) and net ecosystem calcification (NEC), and how these processes might change in response to this major perturbation. Understanding how future OA will alter near-shore seawater CO2 chemistry and variability was identified as a major critical knowledge gap at the recent IPCC WG II/WG I workshop on impacts of ocean acidification on marine biology and ecosystems in January of 2011, and also at the International Ocean Acidification Network workshop in Seattle in June of 2012.</p>
<p>With funding from this CAREER award, a researcher at the Scripps Institute of Oceanography and his students will study how biogeochemical processes and the relative contributions from NEP and NEC modify seawater CO2 chemistry in near-shore environments influenced by different benthic communities under well-characterized environmental and physical conditions, and how these processes might change in response to OA. The team will investigate a limited number of contrasting habitats in subtropical (reef crest, back/patch reef, lagoon, seagrass bed, algal mat) and temperate (kelp bed, inter- and sub-tidal, marsh) environments during summer and winter, employing a method that evaluates the function and performance of the carbon cycle of a system using a stoichiometric vector approach based on changes in total dissolved inorganic carbon (DIC) and total alkalinity (TA). These field studies will be complemented by controlled mesocosm experiments with contrasting and mixed benthic communities under different OA scenarios.</p>
<p>The project has two educational components: (1) developing a research-driven OA and biogeochemistry course based on inquiry-, experience-, and collaborative-based learning; and (2) working with the Ocean Discovery Institute (ODI) to engage individuals from a local underrepresented minority community in science through educational activities focused on OA, and also providing a moderate number of internships for high school and college students to engage in this research project.</p>
<p>Broader Impacts: This project will directly support one PhD student, one junior research technician, and two high school and college interns from underrepresented minorities (URM) each summer of the project. It will contribute to the education of 80 undergraduate and graduate students participating in the research based ocean acidification/biogeochemistry course offered four times throughout the duration of the project at SIO/UCSD. Education and curricular material on the topics of OA, including hands-on laboratories, classroom and field-based activities will be developed through the collaboration with the ODI and brought to hundreds of URM students and their teachers in the City Heights area, a community with the highest poverty and ethnic diversity in the San Diego region. This collaboration will enable URM students to directly engage in a rapidly evolving field of research that has high relevance at both the local and global scales. To ensure broad dissemination of this project and the topic of OA, the research team will work with the Google Ocean team to incorporate information and educational material in the Google Ocean Explorer.</p>
Nearshore CO2
largerWorkCitation
project
eng; USA
oceans
-157.786461
-157.786461
21.433019
21.433019
2013-08-21
2014-01-11
San Diego, California; Bermuda; Oahu, Hawaii
0
BCO-DMO catalogue of parameters from Diel carbonate and nutrient chemistry reported for different benthic reef communities under ambient and acidified conditions during summer and winter
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/839052.rdf
Name: Season
Units: unitless
Description: <p>Season during which experiments were conducted</p>
http://lod.bco-dmo.org/id/dataset-parameter/839053.rdf
Name: Treatment
Units: unitless
Description: <p>CO2 treatment for each experiment</p>
http://lod.bco-dmo.org/id/dataset-parameter/839054.rdf
Name: Date
Units: unitless
Description: <p>Date of measurements (local time; HST); format: DD-MM-YY</p>
http://lod.bco-dmo.org/id/dataset-parameter/839055.rdf
Name: Time
Units: unitless
Description: <p>Time of measurements (local time; HST); format: hh:mm:ss</p>
http://lod.bco-dmo.org/id/dataset-parameter/839056.rdf
Name: ISO_DateTime_UTC
Units: unitless
Description: <p>Date and time of measurements (UTC) in ISO8601 format: YYYY-MM-DDThh:mm:ssZ</p>
http://lod.bco-dmo.org/id/dataset-parameter/839057.rdf
Name: MesocosmID
Units: unitless
Description: <p>Mesocosm identification</p>
http://lod.bco-dmo.org/id/dataset-parameter/839058.rdf
Name: Community
Units: unitless
Description: <p>Reef community within the mesocosm</p>
http://lod.bco-dmo.org/id/dataset-parameter/839059.rdf
Name: Temp
Units: degrees Celsius
Description: <p>In situ temperature</p>
http://lod.bco-dmo.org/id/dataset-parameter/839060.rdf
Name: Salinity
Units: unitless
Description: <p>In situ salinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/839061.rdf
Name: DO_sat
Units: unitless (percent)
Description: <p>In situ dissolved oxygen percent saturation</p>
http://lod.bco-dmo.org/id/dataset-parameter/839062.rdf
Name: DO_conc
Units: milligrams per liter (mg/L)
Description: <p>In situ dissolved oxygen concentration</p>
http://lod.bco-dmo.org/id/dataset-parameter/839063.rdf
Name: pH_ysi
Units: unitless
Description: <p>In situ pH</p>
http://lod.bco-dmo.org/id/dataset-parameter/839064.rdf
Name: TA
Units: micromoles per kilogram (umol/Kg)
Description: <p>In situ total alkalinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/839065.rdf
Name: DIC
Units: micromoles per kilogram (umol/Kg)
Description: <p>In situ dissolved inorganic carbon</p>
http://lod.bco-dmo.org/id/dataset-parameter/839066.rdf
Name: Total_N
Units: micromoles per liter (umol/L)
Description: <p>In situ dissolved inoganic nitrogen and nitrate</p>
http://lod.bco-dmo.org/id/dataset-parameter/839067.rdf
Name: Nitrite
Units: micromoles per liter (umol/L)
Description: <p>In situ dissolved nitrite</p>
http://lod.bco-dmo.org/id/dataset-parameter/839068.rdf
Name: Inorg_P
Units: micromoles per liter (umol/L)
Description: <p>In situ dissolved inorganic phosphorus</p>
http://lod.bco-dmo.org/id/dataset-parameter/839069.rdf
Name: Silicate
Units: micromoles per liter (umol/L)
Description: <p>In situ dissolved silicate</p>
http://lod.bco-dmo.org/id/dataset-parameter/839070.rdf
Name: Ammonia
Units: micromoles per liter (umol/L)
Description: <p>In situ dissolved ammonia</p>
http://lod.bco-dmo.org/id/dataset-parameter/839071.rdf
Name: Nitrate
Units: micromoles per liter (umol/L)
Description: <p>In situ dissolved nitrate</p>
http://lod.bco-dmo.org/id/dataset-parameter/839072.rdf
Name: pH_calc
Units: unitless
Description: <p>In situ pH (total scale) calculated from in situ temperature, salinity, TA, and DIC</p>
http://lod.bco-dmo.org/id/dataset-parameter/839073.rdf
Name: Omega_calc
Units: unitless
Description: <p>Seawater saturation state with respect to aragonite calculated from in situ temperature, salinity, TA, and DIC</p>
http://lod.bco-dmo.org/id/dataset-parameter/839074.rdf
Name: pCO2_calc
Units: microatmospheres (uatm)
Description: <p>In situ pCO2 calculated from in situ temperature, salinity, TA, and DIC</p>
http://lod.bco-dmo.org/id/dataset-parameter/839075.rdf
Name: NCC
Units: millimoles per square meter per hour (mmol/m^2/h)
Description: <p>Net community calcification rate</p>
http://lod.bco-dmo.org/id/dataset-parameter/839076.rdf
Name: NCP
Units: millimoles per square meter per hour (mmol/m^2/h)
Description: <p>Net community primary production rate</p>
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
https://osprey.bco-dmo.org/dataset/839041/data/download
download
onLine
dataset
<p><strong>General study design:</strong><br />
This experiment was designed to quantify and compare the influence of different benthic reef communities on diel seawater carbonate and nutrient chemistry under ambient and acidified conditions during summer and winter in flow-through mesocosms.</p>
<p><strong>Methods description:</strong><br />
Different coral reef benthic communities (carbonate sand, crustose coralline algae, coral, fleshy macroalgae, and a mixed community) were created in outdoor flow-through mesocosms at Hawaii Institute of Marine Biology. Diurnal seawater chemistry was measured for communities experiencing ambient or acidified (ambient pH – 0.4) seawater conditions during summer (August 2013) and winter (January 2014). Acidification treatments were achieved by CO2 (g) bubbling of the header tank. Hourly water quality measurements were taken over the course of 26-hours with water samples collected for analysis of dissolved inorganic carbon and total alkalinity every 2 hours and for inorganic nutrients every 4 hours. A total of four experiments were conducted across two seasons (Summer and Winter) and two pH treatments (ambient and acidified). Seawater chemistry data were used to calculate diurnal net community production (NCP) and net community calcification (NCC) rates using modified standard equations (Langdon et al. 2010). In addition, the attribution of these processes to diurnal pH and saturation state changes were quantified.;</p>
<p>For additional details, please see Page et al. (2016).</p>
<p><strong>Analytical Methods:</strong><br />
Seawater samples were collected by hand using 250 ml Pyrex glass bottles and immediately fixed with 100 µL HgCl2 as per standard protocols (Dickson et al. 2007). Handheld YSI multi-meter instrument was used to measure temperature, salinity, dissolved oxygen, and pH at the time of sampling. All seawater samples were transported to the Scripps Coastal and Open Ocean Biogeochemistry lab and analyzed for TA via an open-cell potentiometric acid titration system developed at Scripps Institution of Oceanography (SIO) by A. Dickson (Dickson et al. 2007) and DIC via an automated infra-red inorganic carbon analyzer (AIRICA, Marianda Inc).</p>
<p><strong>Quality Control:</strong><br />
Standard protocols were followed for sampling and analysis of seawater TA and DIC (Dickson et al. 2007). YSI multi-meter instrument was calibrated prior to each sampling period with accuracies of 0.2 °C for temperature, 1% for salinity, ±2% for dissolved oxygen saturation, 0.2 mg/L for dissolved oxygen concentration, and 0.2 for pH. The accuracy and precision of TA (-0.2 ± 3.3 μmol/kg) and DIC (-1.0 ± 2.3 μmol/kg) measurements were evaluated using certified reference materials (CRM) provided by the laboratory of A. Dickson at SIO and analyzed every 5 samples for DIC and ~15-20 samples for TA.</p>
<p><strong>Known Problems:</strong><br />
Rows where Date is&nbsp;06-01-14 and Time values are 10:14 to 10:44 (inclusive) (lines&nbsp;866-881 in original Excel file): The YSI Pro Plus Handheld Multi-meter temporarily malfunctioned, so temperature and salinity data were measured using an alternate handheld multi-meter probe.</p>
Specified by the Principal Investigator(s)
<p><strong>Data Processing:</strong><br />
Carbonate chemistry (pH_calc, pCO2_calc, and omega_calc) was constrained using CO2SYS software (Lewis and Wallace 1998). Data were processed and statistically compared using R Software (v 3.2.0).</p>
<p><strong>BCO-DMO Processing:</strong><br />
- added UTC date/time field in ISO8601 format.</p>
Specified by the Principal Investigator(s)
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
AIRICA (Marianda Inc.)
AIRICA (Marianda Inc.)
PI Supplied Instrument Name: AIRICA (Marianda Inc.) PI Supplied Instrument Description:The Automated Infra Red Inorganic Carbon Analyzer (AIRICA) utilizes infrared detection of CO2 gas purged from an acidified seawater sample. A high-precision syringe pump extracts the seawater sample, acidifies the sample with phosphoric acid, and analyzes the gas released with an infrared light analyzer (LICOR). The CO2 signal is integrated for each sample to quantify the total inorganic carbon for a given aliquot of seawater analyzed. Three aliquots and peak integrations are performed for each seawater sample and averaged to determine the dissolved inorganic carbon for each sample. Please see http://marianda.com/index.php?site=products&subsite=airica for a complete instrument description. Instrument Name: Inorganic Carbon Analyzer Instrument Short Name: Instrument Description: Instruments measuring carbonate in sediments and inorganic carbon (including DIC) in the water column.
Open-cell potentiometric acid titration system
Open-cell potentiometric acid titration system
PI Supplied Instrument Name: Open-cell potentiometric acid titration system PI Supplied Instrument Description:The open-cell potentiometric acid titration system was developed by the laboratory of A.G. Dickson. Briefly, a known amount of seawater is added to an open cell beaker where hydrochloric acid as acidified to a pH of 3.5-4.0 and allowed to stabilize to remove CO2 gas formed by the addition of acid. Small aliquots of hydrochloric acid are then added to pH of ~ 3.0. The titration is monitored by a glass electrode and the total alkalinity of the sample is calculated using a non-linear least-squares method following Dickson et al. (2007). Instrument Name: Titrator Instrument Short Name:Titrator Instrument Description: Titrators are instruments that incrementally add quantified aliquots of a reagent to a sample until the end-point of a chemical reaction is reached. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB12/
YSI Professional Plus (Pro Plus) Handheld Multiparameter
YSI Professional Plus (Pro Plus) Handheld Multiparameter
PI Supplied Instrument Name: YSI Professional Plus (Pro Plus) Handheld Multiparameter PI Supplied Instrument Description:YSI Handheld Multiparameter Instruments were used to monitor in situ temperature (accuracy ± 0.2°C), salinity (accuracy ± 1%), DO_mg (accuracy ± 0.2 mg/L), and DO_% (accuracy ± 2%), and pH (accuracy ± 0.2). Instrument Name: Water Quality Multiprobe Instrument Short Name:Water Quality Multiprobe Instrument Description: An instrument which measures multiple water quality parameters based on the sensor configuration.