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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/768325.rdf" xlink:title="OCE-1829425" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1829425 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1829425</gmx:Anchor>
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Ocean ecosystems play a critical role in the Earth’s carbon cycle and the quantification of their impacts for both present conditions and for predictions into the future remains one of the greatest challenges in oceanography. The goal of the EXport Processes in the Ocean from Remote Sensing (EXPORTS) Science Plan is to develop a predictive understanding of the export and fate of global ocean net primary production (NPP) and its implications for present and future climates. The achievement of this goal requires a quantification of the mechanisms that control the export of carbon from the euphotic zone as well as its fate in the underlying &quot;twilight zone&quot; where some fraction of exported carbon will be sequestered in the ocean’s interior on time scales of months to millennia. In particular, EXPORTS will advance satellite diagnostic and numerical prognostic models by comparing relationships among the ecological, biogeochemical and physical oceanographic processes that control carbon cycling across a range of ecosystem and carbon cycling states. EXPORTS will achieve this through a combination of ship and robotic field sampling, satellite remote sensing and numerical modeling. Through a coordinated, process-oriented approach, EXPORTS will foster new insights on ocean carbon cycling that maximizes its societal relevance through the achievement of U.S. and International research agency goals and will be a key step towards our understanding of the Earth as an integrated system.</gco:CharacterString>
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The biological pump is largely responsible for the vertical transport of organic carbon from the surface to the ocean interior. However, only a small fraction of organic material produced in surface waters is sequestered in the deep ocean. The rest is consumed, or respired, by bacteria and larger organisms. The overarching goal of the proposed work is to characterize the relative influences of bacteria versus larger organisms on the degradation of organic material with depth. Guided by recent results from the subtropical Pacific, the investigators will use measurements of stable isotopes of nitrogen in different amino acids (compound-specific isotopic analysis of amino acids, known as AA-CSIA), along with measurements of the abundances of different forms of amino acids, and other parameters derived from these analyses to identify how the partitioning and flux of large and small particles are affected by different degradation processes. By improving the interpretive power of the AA-CSIA technique the investigators propose to determine: 1) the relative importance of microbial and zooplankton consumption on the efficiency of the biological carbon pump in the subarctic northeast Pacific, and 2) how much microbially-altered small particles fuel the metabolisms of mid-water zooplankton. This work capitalizes on an existing, comprehensive field program (NASA EXPORTS) specifically focused on building a predictive framework relating surface ocean properties to the vertical flux of organic carbon. The tremendous amount of data to be collected on all aspects of the biological pump as part of the EXPORTS program will aid the development and interpretation of the investigators' amino acid isotopic tool. Results will be broadly communicated via production and distribution of several episodes of Voice of the Sea, a local television program that will air in Hawaii and across many Pacific islands. Episodes also will be posted online and publicized through social media to the south Florida community. This project will support a Ph.D. student and an undergraduate student at University of Miami, which serves a 25% Hispanic population, and an M.S. student and an undergraduate student at University of Hawaii, which is a designated minority-serving institution.&lt;/p&gt;
&lt;p&gt;The proposed work introduces a new geochemical framework to distinguish microbial versus zooplankton alteration of marine organic matter. Piloted on samples from the subtropical Pacific, this approach interrogates unamended sinking material directly, using amino acid compound-specific isotopic analysis (AA-CSIA) to determine the progressive, cumulative impact of microbial and zooplankton degradative pathways. The proposed work (1) will extend this interpretive framework to explicitly define end-member signatures such as fecal pellets and will apply this refined method to a study site in the subarctic northeast Pacific to (2) determine the vertical progression of degradative mechanisms in an oceanographic location with contrasting productivity and vertical length scales of flux attenuation and (3) determine whether microbially- degraded biomass is important for fueling midwater metazoans under contrasting carbon flux conditions. The proposed work will be conducted in collaboration with the NASA EXPORTS program at the Ocean Station Papa time-series site. Teaming with this program presents a unique opportunity to refine AA-CSIA interpretation in parallel with intensive data collection defining productivity, particle size distribution and flux, and numerous biological parameters. In comparing subtropical and subarctic Pacific locations, the proposed work will test how differences in productivity and plankton community structure influence vertical patterns of consumption and alteration of phytodetritus by microbes and zooplankton, from surface to mesopelagic depths.&lt;/p&gt;
&lt;p&gt;This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.&lt;/p&gt;</gco:CharacterString>
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	Name: Cruise
	Units: unitless
	Description: &lt;p&gt;Cruise designation&lt;/p&gt; 
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http://lod.bco-dmo.org/id/dataset-parameter/868219.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868220.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868221.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868222.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868223.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868224.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868225.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868226.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/868227.rdf
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	Units: meters (m)
	Description: &lt;p&gt;maximum depth of sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868228.rdf
	Name: DepthInterval_min
	Units: meters (m)
	Description: &lt;p&gt;minimum depth of sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868229.rdf
	Name: SizeFraction_min
	Units: micrometers (um)
	Description: &lt;p&gt;minimum wet sieved size fraction&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868230.rdf
	Name: SizeFraction_max
	Units: micrometers (um)
	Description: &lt;p&gt;maximum wet sieved size fraction&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868231.rdf
	Name: Taxa
	Units: text
	Description: &lt;p&gt;which taxa were analyzed&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868232.rdf
	Name: d15N_Ala
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the nitrogen isotopic composition of alanine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868233.rdf
	Name: d15N_Gly
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the nitrogen isotopic composition of glycine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868234.rdf
	Name: d15N_Thr
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the nitrogen isotopic composition of threonine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868235.rdf
	Name: d15N_Ser
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the nitrogen isotopic composition of serine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868236.rdf
	Name: d15N_Val
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the nitrogen isotopic composition of valine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868237.rdf
	Name: d15N_Leu
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the nitrogen isotopic composition of leucine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868238.rdf
	Name: d15N_Iso
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the nitrogen isotopic composition of isoleucine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868239.rdf
	Name: d15N_Pro
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868240.rdf
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	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868241.rdf
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	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868242.rdf
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	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868243.rdf
	Name: d15N_Phe
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868244.rdf
	Name: d15N_Tyr
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868245.rdf
	Name: d15N_Lys
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868246.rdf
	Name: SD_d15N_Ala
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868247.rdf
	Name: SD_d15N_Gly
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868248.rdf
	Name: SD_d15N_Thr
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868249.rdf
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	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868250.rdf
	Name: SD_d15N_Val
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868251.rdf
	Name: SD_d15N_Leu
	Units: permil relative to AIR (‰)
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http://lod.bco-dmo.org/id/dataset-parameter/868252.rdf
	Name: SD_d15N_Ile
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of isoleucine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868253.rdf
	Name: SD_d15N_Pro
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of proline&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868254.rdf
	Name: SD_d15N_Asx
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of aspartic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868255.rdf
	Name: SD_d15N_Met
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of aspartic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868256.rdf
	Name: SD_d15N_Glx
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of glutamic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868257.rdf
	Name: SD_d15N_Phe
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of phenylalanine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868258.rdf
	Name: SD_d15N_Tyr
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of tyrosine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868259.rdf
	Name: SD_d15N_Lys
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;the standard deviation of the nitrogen isotopic composition of lysine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868260.rdf
	Name: d13C_Ala
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of alanine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868261.rdf
	Name: d13C_Gly
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of glycine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868262.rdf
	Name: d13C_Thr
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of threonine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868263.rdf
	Name: d13C_Ser
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of serine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868264.rdf
	Name: d13C_Val
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of valine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868265.rdf
	Name: d13C_Leu
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of leucine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868266.rdf
	Name: d13C_Iso
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of isoleucine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868267.rdf
	Name: d13C_Pro
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of proline&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868268.rdf
	Name: d13C_Asx
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of aspartic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868269.rdf
	Name: d13C_Met
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of aspartic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868270.rdf
	Name: d13C_Glx
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of glutamic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868271.rdf
	Name: d13C_Phe
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of phenylalanine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868272.rdf
	Name: d13C_Tyr
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of tyrosine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868273.rdf
	Name: d13C_Lys
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the carbon isotopic composition of lysine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868274.rdf
	Name: SD_d13C_Ala
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of alanine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868275.rdf
	Name: SD_d13C_Gly
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of glycine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868276.rdf
	Name: SD_d13C_Thr
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of threonine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868277.rdf
	Name: SD_d13C_Ser
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of serine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868278.rdf
	Name: SD_d13C_Val
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of valine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868279.rdf
	Name: SD_d13C_Leu
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of leucine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868280.rdf
	Name: SD_d13C_Ile
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of isoleucine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868281.rdf
	Name: SD_d13C_Pro
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of proline&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868282.rdf
	Name: SD_d13C_Asx
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of aspartic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868283.rdf
	Name: SD_d13C_Met
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of aspartic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868284.rdf
	Name: SD_d13C_Glx
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of glutamic acid&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868285.rdf
	Name: SD_d13C_Phe
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of phenylalanine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868286.rdf
	Name: SD_d13C_Tyr
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of tyrosine&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/868287.rdf
	Name: SD_d13C_Lys
	Units: permil relative to VPDB (‰)
	Description: &lt;p&gt;the standard deviation of the carbon isotopic composition of lysine&lt;/p&gt; 
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