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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/871203.rdf" xlink:actuate="onRequest">Water column analytical data from the Chile Triple Junction collected on two cruises aboard the R/V Melville during February-March 2010 and April 2012</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: German, C. R., Baumberger, T., Saito, M. A. (2022) Water column analytical data from the Chile Triple Junction collected on two cruises aboard the R/V Melville during February-March 2010 and April 2012. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2022-03-28 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.871203.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Water column analytical data from Chile Triple Junction Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;The hydrothermal plume samples reported here were acquired aboard R/V Melville during two short cruises of opportunity conducted in 2010 (MV 1003) and 2012 (MV 1205). Surveys along the axis of the ridge-crest were conducted using the ship's Seabird 911+ CTD rosette. A combination of tow-yo, vertical casts, and &amp;quot;pogo&amp;quot; stations were employed. An ultra-short baseline (USBL) navigation beacon was attached to the CTD-rosette for all deployments to ensure that we could navigate precisely where all samples and ancillary data were collected, as well as their sample depths.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples collected for Helium analyses were processed at the NOAA/PMEL Helium Isotope Laboratory in Newport, OR. The gas and liquid phases of the cold-welded samples were separated using a high-vacuum extraction line. The content of each sealed Cu tube was dropped into an evacuated flask and continuously stirred with a magnetic stirrer during the extraction process. A combined charcoal-LN₂ trap was then used to pump the gas phase into aluminosilicate ampoules during the 15 minute-long gas extraction process. The ampoules were subsequently sealed with a hot flame and stored dry until analysis. Isotope ratios and concentrations of helium were determined using a dual collector, 21 cm radius, sector-type mass spectrometer specially designed for helium isotope analyses. The precision for the helium isotope ratios in seawater samples averaged 0.2% in δ³He, where δ³He is the percentage deviation of the isotopic ratio R=³He/⁴He in the water sample from the atmospheric ³He/⁴He ratio Rₐ= 1.39 x 10⁻⁶:&amp;amp;nbsp; &amp;amp;nbsp;δ³He =((R/Ra)-1)*100 [%].&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Methane concentrations were determined at sea. After equilibration, the headspace gas was injected into a SRI 8610C gas chromatograph. Separation of CH₄ was done using a 15 m long Molecular Sieve 5A column and CH₄ concentrations were measured with a flame ionization detector. The measured background seawater CH₄ concentration was 0.4 nM. Sampling and analytical precision, determined through replicate draws, was &amp;amp;lt;2.5% of the measured concentrations or ±0.1 nM, whichever is greater.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Analyses for total dissolvable iron (TDFe) and manganese (TDMn) were conducted on samples selected from Cruise MV1003 (2010) based on shipboard dissolved CH₄ data. Those analyses were conducted using Mg-precipitation, isotope dilution, and inductively coupled plasma mass spectrometry (ICP-MS) following standard methods described elsewhere [Saito and Schneider, 2006; Noble et al., 2008]. Briefly, unfiltered seawater samples were acidified to pH 1.7 using high purity HCl (SeaStar Inc) and then left for 4 months to allow the dissolution of labile metals in weak acid. For each analysis 13.0mL of processed sample was decanted into a centrifuge tube, spiked with ⁵⁷Fe stable isotope and precipitated using a small amount of high-purity ammonia (SeaStar Inc.) then centrifuged for 3 min at 3000 rpm (1460 x g) and decanted. The sample was resuspended in 5% high-purity nitric acid with 1ppm indium (In) and analysis was conducted on an Element 2 ICP-MS using an Aridus desolvator and platinum X-cones. Fe and Mn concentrations were calculated using the ⁵⁷Fe for isotope dilution and In as a recovery tracer [Saito and Schneider, 2006]. Precisions in the measurements were typically better than ±1.0nM for Fe and ±0.2nM for Mn.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;All relevant metadata (precision, accuracy, etc.) are published in German et al., 2022 (doi: &amp;lt;a href=&amp;quot;http://dx.doi.org/10.1029/2021GC010317&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;10.1029/2021GC010317&amp;lt;/a&amp;gt;).&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/871213.rdf" xlink:title="NOAA-OER NA08OAR4600757" xlink:actuate="onRequest">Funding provided by NOAA Ocean Exploration () Award Number: NOAA-OER NA08OAR4600757</gmx:Anchor>
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&amp;lt;p&amp;gt;Samples collected for Helium analyses were processed at the NOAA/PMEL Helium Isotope Laboratory in Newport, OR. The gas and liquid phases of the cold-welded samples were separated using a high-vacuum extraction line. The content of each sealed Cu tube was dropped into an evacuated flask and continuously stirred with a magnetic stirrer during the extraction process. A combined charcoal-LN₂ trap was then used to pump the gas phase into aluminosilicate ampoules during the 15 minute-long gas extraction process. The ampoules were subsequently sealed with a hot flame and stored dry until analysis. Isotope ratios and concentrations of helium were determined using a dual collector, 21 cm radius, sector-type mass spectrometer specially designed for helium isotope analyses. The precision for the helium isotope ratios in seawater samples averaged 0.2% in δ³He, where δ³He is the percentage deviation of the isotopic ratio R=³He/⁴He in the water sample from the atmospheric ³He/⁴He ratio Rₐ= 1.39 x 10⁻⁶:&amp;amp;nbsp; &amp;amp;nbsp;δ³He =((R/Ra)-1)*100 [%].&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Methane concentrations were determined at sea. After equilibration, the headspace gas was injected into a SRI 8610C gas chromatograph. Separation of CH₄ was done using a 15 m long Molecular Sieve 5A column and CH₄ concentrations were measured with a flame ionization detector. The measured background seawater CH₄ concentration was 0.4 nM. Sampling and analytical precision, determined through replicate draws, was &amp;amp;lt;2.5% of the measured concentrations or ±0.1 nM, whichever is greater.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Analyses for total dissolvable iron (TDFe) and manganese (TDMn) were conducted on samples selected from Cruise MV1003 (2010) based on shipboard dissolved CH₄ data. Those analyses were conducted using Mg-precipitation, isotope dilution, and inductively coupled plasma mass spectrometry (ICP-MS) following standard methods described elsewhere [Saito and Schneider, 2006; Noble et al., 2008]. Briefly, unfiltered seawater samples were acidified to pH 1.7 using high purity HCl (SeaStar Inc) and then left for 4 months to allow the dissolution of labile metals in weak acid. For each analysis 13.0mL of processed sample was decanted into a centrifuge tube, spiked with ⁵⁷Fe stable isotope and precipitated using a small amount of high-purity ammonia (SeaStar Inc.) then centrifuged for 3 min at 3000 rpm (1460 x g) and decanted. The sample was resuspended in 5% high-purity nitric acid with 1ppm indium (In) and analysis was conducted on an Element 2 ICP-MS using an Aridus desolvator and platinum X-cones. Fe and Mn concentrations were calculated using the ⁵⁷Fe for isotope dilution and In as a recovery tracer [Saito and Schneider, 2006]. Precisions in the measurements were typically better than ±1.0nM for Fe and ±0.2nM for Mn.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;All relevant metadata (precision, accuracy, etc.) are published in German et al., 2022 (doi: &amp;lt;a href=&amp;quot;http://dx.doi.org/10.1029/2021GC010317&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;10.1029/2021GC010317&amp;lt;/a&amp;gt;).&amp;lt;/p&amp;gt;</gco:CharacterString>
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