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            <gco:CharacterString>Cite this dataset as: McGillicuddy, D. J., Sosik, H. M., Zhang, W. G., Smith, W. O., Stanley, R., Turner, J., Petitpas, C. (2022) Bottle sample data from CTD casts from the second cruise of SPIROPA project, R/V Ronald H. Brown cruise RB1904, to the New England Shelfbreak in May of 2019. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2022-05-04 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.873854.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Bottle dataset May 2019 Dataset Description: &amp;lt;p&amp;gt;Cast numbers in version 1 are: [1:62, 64:67, 69:119]&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;Location: New England Shelfbreak 40 S 71W depth : 0-2000m.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Standard station CTD profiles measurements (down casts) with water sampling (up casts).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Twenty-four 10 L Niskin bottles fitted with Teflon-coated external closures were used for water column sampling. At&amp;amp;nbsp;each station, samples were typically collected at 12 discrete depths for assessment of nutrient concentrations. These&amp;amp;nbsp;samples were syringe-filtered and stored at -20°C &amp;amp;nbsp;until analysis at the WHOI Nutrient Analytical Facility. Nitrate and&amp;amp;nbsp;silicate were measured using standard AutoAnalyzer techniques. To measure ammonium concentrations, site water&amp;amp;nbsp;was cartridge-filtered (0.1 µm, Pall Co.) directly from Niskin bottles using a peristaltic pump. Filtrate was collected in&amp;amp;nbsp;FalconTM tubes that were pre-treated with orthophthaldialdehyde (OPA) and measured on-board via the OPA method&amp;amp;nbsp;(Holmes et al., 1999) with a detection limit of 10 nM.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
To measure particulate organic carbon and nitrogen, water was collected from the Niskin bottles and filtered through&amp;amp;nbsp;combusted 0.7 µm glass fiber filters (Whatman GF/F), rinsed with a weak acid (0.01 N HCl in seawater) to remove&amp;amp;nbsp;carbonates, then dried in combusted glass vials at 60 °C. Diatom biomass was assessed by sampling for biogenic&amp;amp;nbsp;silica. Samples were filtered through 0.6 µm polycarbonate filters, dried at 60°C in plastic Petri dishes, and dissolved in&amp;amp;nbsp;strong acid. &amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;For incubation-based primary productivity, water samples were taken from Niskin&amp;amp;nbsp;bottles at known isolumes, then placed in sterile 285 mL&amp;amp;nbsp;Qorpak bottles, then&amp;amp;nbsp;~20 µCi NaH14CO3&amp;amp;nbsp;was added. An on-deck incubator holding&amp;amp;nbsp;the bottles had&amp;amp;nbsp;surface seawater flowing through it, with irradiance attenuated&amp;amp;nbsp;by neutral density filters to the light&amp;amp;nbsp;levels at the isolumes sampled. Blue&amp;amp;nbsp;filters were used for isolumes below 30% Eo. After 24 h, samples&amp;amp;nbsp;were filtered through GFF filters and placed in 7 mL scintillation vials. Size&amp;amp;nbsp;fractionations were&amp;amp;nbsp;conducted at all stations using 20 µm Poretics filters on&amp;amp;nbsp;subsamples from each bottle. 100 µL 1N HCl&amp;amp;nbsp;was added to volatilize absorbed&amp;amp;nbsp;inorganic&amp;amp;nbsp;14C. Ecolume (5 mL) was then added to each vial, and all&amp;amp;nbsp;vials were counted after 24 h on a liquid scintillation counter. Total activity&amp;amp;nbsp;was measured by counting&amp;amp;nbsp;100 μL of non-acidified sample in&amp;amp;nbsp;β-phenethanylamine.&amp;amp;nbsp;&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/748850.rdf" xlink:title="OCE-1657803" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1657803 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1657803</gmx:Anchor>
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&lt;p&gt;The continental shelf break of the Middle Atlantic Bight supports a productive and diverse ecosystem. Current paradigms suggest that this productivity is driven by several upwelling mechanisms at the shelf break front. This upwelling supplies nutrients that stimulate primary production by phytoplankton, which in turn leads to enhanced production at higher trophic levels. Although local enhancement of phytoplankton biomass has been observed in some circumstances, such a feature is curiously absent from time-averaged measurements, both from satellites and shipboard sampling. Why would there not be a mean enhancement in phytoplankton biomass as a result of the upwelling? One hypothesis is that grazing by zooplankton prevents accumulation of biomass on seasonal and longer time scales, transferring the excess production to higher trophic levels and thereby contributing to the overall productivity of the ecosystem. However, another possibility is that the net impact of these highly intermittent processes is not adequately represented in long-term means of the observations, because of the relatively low resolution of the in-water measurements and the fact that the frontal enhancement can take place below the depth observable by satellite. The deployment of the Ocean Observatories Initiative (OOI) Pioneer Array south of New England has provided a unique opportunity to test these hypotheses. The combination of moored instrumentation and autonomous underwater vehicles will facilitate observations of the frontal system with unprecedented spatial and temporal resolution. This will provide an ideal four-dimensional (space-time) context in which to conduct a detailed study of frontal dynamics and plankton communities needed to examine mechanisms controlling phytoplankton populations in this frontal system. This project will also: (1) promote teaching, training and learning via participation of graduate and undergraduate students in the research , (2) provide a broad dissemination of information by means of outreach in public forums, printed media, and a video documentary of the field work, and (3) contribute to improving societal well-being and increased economic competitiveness by providing the knowledge needed for science-based stewardship of coastal ecosystems, with particular emphasis on connecting with the fishing industry through the Commercial Fisheries Research Foundation.&lt;/p&gt;
&lt;p&gt;The investigators will conduct a set of three cruises to obtain cross-shelf sections of physical, chemical, and biological properties within the Pioneer Array. Nutrient distributions will be assayed together with hydrography to detect the signature of frontal upwelling and associated nutrient supply. The investigators expect that enhanced nutrient supply will lead to changes in the phytoplankton assemblage, which will be quantified with conventional flow cytometry, imaging flow cytometry (Imaging FlowCytobot, IFCB), optical imaging (Video Plankton Recorder, VPR), traditional microscopic methods, and pigment analysis. Zooplankton will be measured in size classes ranging from micro- to mesozooplankton with the IFCB and VPR, respectively, and also with microscopic analysis. Biological responses to upwelling will be assessed by measuring rates of primary productivity, zooplankton grazing, and net community production. These observations will be synthesized in the context of a coupled physical-biological model to test the two hypotheses that can potentially explain prior observations: (1) grazer-mediated control and (2) undersampling. Hindcast simulations will also be used to diagnose the relative importance of the various mechanisms of upwelling. The intellectual merit of this effort stems from our interdisciplinary approach, advanced observational techniques, and integrated analysis in the context of a state-of-the-art coupled model. The project will address longstanding questions regarding hydrodynamics and productivity of an important ecosystem, leading to improved understanding of physical-biological interactions in a complex continental shelf regime. Given the importance of frontal systems in the global coastal ocean, it is expected that knowledge gained will have broad applicability beyond the specific region being studied.&lt;/p&gt;</gco:CharacterString>
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	Units: year
	Description: &lt;p&gt;NMEA UTC year&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875415.rdf
	Name: month
	Units: month number
	Description: &lt;p&gt;NMEA UTC month&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875416.rdf
	Name: day
	Units: day of month
	Description: &lt;p&gt;NMEA UTC day&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875417.rdf
	Name: time
	Units: hhmm
	Description: &lt;p&gt;NMEA UTC time&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875418.rdf
	Name: ISO_DateTime_UTC
	Units: unitless
	Description: &lt;p&gt;Cast start time in ISO8601 format yyyy-mm-ddTHH:MMZ (UTC time)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875419.rdf
	Name: latitude
	Units: degrees N
	Description: &lt;p&gt;NMEA latitude&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875420.rdf
	Name: longitude
	Units: degrees W
	Description: &lt;p&gt;NMEA longitude&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875421.rdf
	Name: target_depth
	Units: m
	Description: &lt;p&gt;target depth&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875422.rdf
	Name: depth
	Units: m
	Description: &lt;p&gt;depth&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875423.rdf
	Name: press
	Units: db
	Description: &lt;p&gt;pressure&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875424.rdf
	Name: niskin_used
	Units: unitless
	Description: &lt;p&gt;The number of niskin bottles used for CTD BTL data averaging&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875425.rdf
	Name: sigmat
	Units: kg/m^3
	Description: &lt;p&gt;Sigma-theta density from primary sensors&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875426.rdf
	Name: sigmat2
	Units: kg/m^3
	Description: &lt;p&gt;a&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875427.rdf
	Name: oxy
	Units: ml/l
	Description: &lt;p&gt;Dissolved oxygen concentration&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875428.rdf
	Name: oxyM
	Units: Mm/Kg
	Description: &lt;p&gt;Dissolved oxygen concentration&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875429.rdf
	Name: oxySat
	Units: Mm/Kg
	Description: &lt;p&gt;Dissolved oxygen concentration&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875430.rdf
	Name: potTemp
	Units: ITS-90, deg C
	Description: &lt;p&gt;Potential temperature  from primary sensor&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875431.rdf
	Name: potTemp2
	Units: ITS-90, deg C
	Description: &lt;p&gt;Potential temperature  from secondary sensor&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875432.rdf
	Name: sal
	Units: unitless
	Description: &lt;p&gt;Salinity practical from primary sensors&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875433.rdf
	Name: sal2
	Units: unitless
	Description: &lt;p&gt;Salinity practical from secondary sensors&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875434.rdf
	Name: dens
	Units: kg/m^3
	Description: &lt;p&gt;Density from primary sensors&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875435.rdf
	Name: dens2
	Units: kg/m^3
	Description: &lt;p&gt;Density from secondary sensors&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875436.rdf
	Name: svCM
	Units: m/s
	Description: &lt;p&gt;Sound velocity (chen-millero) from primary sensors&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875437.rdf
	Name: svCM2
	Units: m/s
	Description: &lt;p&gt;Sound velocity (chen-millero) from secondary sensors&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875438.rdf
	Name: temp
	Units: ITS-90, deg C
	Description: &lt;p&gt;temperature from primary sensor&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875439.rdf
	Name: temp2
	Units: ITS-90, deg C
	Description: &lt;p&gt;temperature from secondary sensor&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875440.rdf
	Name: cond
	Units: S/m
	Description: &lt;p&gt;conductivity from primary sensor&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875441.rdf
	Name: cond2
	Units: S/m
	Description: &lt;p&gt;conductivity from secondary sensor&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875442.rdf
	Name: oxyV
	Units: V
	Description: &lt;p&gt;oxygen raw&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875443.rdf
	Name: fluor1
	Units: mg/m^3
	Description: &lt;p&gt;Fluorescence, WET Labs ECO-AFL/FL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875444.rdf
	Name: fluor2
	Units: mg/m^3
	Description: &lt;p&gt;Fluorescence, WET labs CDOM&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875445.rdf
	Name: trans
	Units: %
	Description: &lt;p&gt;CStarTr0: Beam Transmission, WET Labs C-Star&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875446.rdf
	Name: turb
	Units: NTU
	Description: &lt;p&gt;turbWETntu0: Turbidity, WET Labs ECO&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875447.rdf
	Name: alt
	Units: m
	Description: &lt;p&gt;Altimeter&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875448.rdf
	Name: salDC
	Units: unitless
	Description: &lt;p&gt;Salinity practical from primary sensor (output from Data Conversion)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875449.rdf
	Name: spar
	Units: microEinsteins/m^2/second
	Description: &lt;p&gt;SPAR/surface irradiance&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875450.rdf
	Name: par
	Units: microEinsteins/m^2/second
	Description: &lt;p&gt;PAR/irradiance&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875451.rdf
	Name: cpar
	Units: %
	Description: &lt;p&gt;CPAR/Corrected Irradiance&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875452.rdf
	Name: V0
	Units: Volt
	Description: &lt;p&gt;Fluor1 Voltage&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875453.rdf
	Name: bottle_nuts
	Units: unitless
	Description: &lt;p&gt;CTD bottle number for nutrient analyses&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875454.rdf
	Name: NO3
	Units: umol L^-^1
	Description: &lt;p&gt;Nitrate concentration&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875455.rdf
	Name: NH4
	Units: umol L^-^1
	Description: &lt;p&gt;Ammonium concentration&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875456.rdf
	Name: PO4
	Units: umol L^-^1
	Description: &lt;p&gt;Phosphate concentration&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875457.rdf
	Name: Si
	Units: umol L^-^1
	Description: &lt;p&gt;Silicate concentration&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875458.rdf
	Name: bottle_toi
	Units: unitless
	Description: &lt;p&gt;CTD bottle number for Triple Oxygen Isotope (TOI) analyses&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875459.rdf
	Name: D17corr
	Units: per meg
	Description: &lt;p&gt;D17corr&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875460.rdf
	Name: Littled17corr
	Units: per mil
	Description: &lt;p&gt;Littled17corr&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875461.rdf
	Name: Littled18corr
	Units: per mil
	Description: &lt;p&gt;Littled18corr&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875462.rdf
	Name: O2Arcorr
	Units: unitless
	Description: &lt;p&gt;O2Arcorr&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875463.rdf
	Name: Samp_toi
	Units: unitless
	Description: &lt;p&gt;Sample TOI (Triple Oxygen Isotope)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875464.rdf
	Name: Vial_toi
	Units: unitless
	Description: &lt;p&gt;Vial TOI  (Triple Oxygen Isotope)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875465.rdf
	Name: PPVial
	Units: unitless
	Description: &lt;p&gt;primary productivity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875466.rdf
	Name: Volfilt
	Units: ml
	Description: &lt;p&gt;primary productivity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875467.rdf
	Name: N_mg
	Units: mg
	Description: &lt;p&gt;Nitrogen&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875468.rdf
	Name: C_mg
	Units: mg
	Description: &lt;p&gt;Carbon&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875469.rdf
	Name: PON
	Units: umol L^-^1
	Description: &lt;p&gt;particulate organic Nitrogen&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875470.rdf
	Name: POC
	Units: umol L^-^1
	Description: &lt;p&gt;particulate organic Carbon&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875471.rdf
	Name: CN_ratio
	Units: mol/mol
	Description: &lt;p&gt;Carbon/Nitrogen ratio&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875472.rdf
	Name: Proc_io
	Units: %
	Description: &lt;p&gt;irradiance/surface irradiance ratio&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875473.rdf
	Name: Prod
	Units: mg m^-^3 h^-^1
	Description: &lt;p&gt;primary productivity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875474.rdf
	Name: IntProd
	Units: mg C m^-^2 d^-^1
	Description: &lt;p&gt;integrated primary productivity per day&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875475.rdf
	Name: Bsi
	Units: umol L^-^1
	Description: &lt;p&gt;biogenic silica&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875476.rdf
	Name: bottle_chl
	Units: unitless
	Description: &lt;p&gt;CTD bottle number for Chlorophyll analyses&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875477.rdf
	Name: Filt_0
	Units: unitless
	Description: &lt;p&gt;Filt_0 ID=0&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875478.rdf
	Name: Chl_x_0
	Units: ug L^-^1
	Description: &lt;p&gt;Chlorophyll Filt_0&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875479.rdf
	Name: Chl_y_0
	Units: ug L^-^1
	Description: &lt;p&gt;Chlorophyll Filt_0 (replicates)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875480.rdf
	Name: Phaeo_x_0
	Units: ug L^-^1
	Description: &lt;p&gt;total phaeopigment Filt_0&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875481.rdf
	Name: Phaeo_y_0
	Units: ug L^-^1
	Description: &lt;p&gt;total phaeopigment Filt_0 (replicates)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875482.rdf
	Name: QCflag_x_0
	Units: unitless
	Description: &lt;p&gt;Filt_0 Quality flag:  1-inspected, 2-some question&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875483.rdf
	Name: QCflag_y_0
	Units: unitless
	Description: &lt;p&gt;Filt_0 (replicates) Quality flag: 1-inspected, 2-some question&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875484.rdf
	Name: Filt_10
	Units: unitless
	Description: &lt;p&gt;Filt_10 ID=10&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875485.rdf
	Name: Chl_x_10
	Units: ug L^-^1
	Description: &lt;p&gt;Chlorophyll Filt_10&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875486.rdf
	Name: Chl_y_10
	Units: ug L^-^1
	Description: &lt;p&gt;chlorophyll Filt_10 (replicates)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875487.rdf
	Name: Phaeo_x_10
	Units: ug L^-^1
	Description: &lt;p&gt;total phaeopigment Filt_10&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875488.rdf
	Name: Phaeo_y_10
	Units: ug L^-^1
	Description: &lt;p&gt;total phaeopigment Filt_10 (replicates)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875489.rdf
	Name: QCflag_x_10
	Units: unitless
	Description: &lt;p&gt;Filt_10 Quality flag: 1-inspected, 2-some question&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875490.rdf
	Name: QCflag_y_10
	Units: unitless
	Description: &lt;p&gt;Filt_10 (replicates) Quality flag: 1-inspected, 2-some question&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875491.rdf
	Name: bottle_alk
	Units: unitless
	Description: &lt;p&gt;CTD bottle number for Alkalinity  analyses&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875492.rdf
	Name: CO3
	Units: umol/kg
	Description: &lt;p&gt;Carbon trioxide&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875493.rdf
	Name: HCO3
	Units: umol/kg
	Description: &lt;p&gt;Bicarbonate ?&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875494.rdf
	Name: Ar
	Units: umol / kg
	Description: &lt;p&gt;Aragonite&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875495.rdf
	Name: Ca
	Units: umol / kg
	Description: &lt;p&gt;Calcium&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875496.rdf
	Name: Alk
	Units: umol / kg
	Description: &lt;p&gt;Alkalinity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875497.rdf
	Name: Dic
	Units: umol / kg
	Description: &lt;p&gt;dissolved inorganic carbon&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875498.rdf
	Name: PCO2
	Units: uatm
	Description: &lt;p&gt;Partial Pressure of Carbon Dioxide&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/875499.rdf
	Name: PH
	Units: total scale
	Description: &lt;p&gt;pH&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/878383.rdf
	Name: upoly0
	Units: micromolar nitrate (mmol nitrate per m^3
	Description: &lt;p&gt;Upoly 0, SUNA 2km ASY-NTR-00081&lt;/p&gt; 
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        </gmd:DQ_Scope>
      </gmd:scope>
            <gmd:lineage>
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          <gmd:processStep xlink:title="Methods and Sampling">
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                <gco:CharacterString>&amp;lt;p&amp;gt;Location: New England Shelfbreak 40 S 71W depth : 0-2000m.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Standard station CTD profiles measurements (down casts) with water sampling (up casts).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Twenty-four 10 L Niskin bottles fitted with Teflon-coated external closures were used for water column sampling. At&amp;amp;nbsp;each station, samples were typically collected at 12 discrete depths for assessment of nutrient concentrations. These&amp;amp;nbsp;samples were syringe-filtered and stored at -20°C &amp;amp;nbsp;until analysis at the WHOI Nutrient Analytical Facility. Nitrate and&amp;amp;nbsp;silicate were measured using standard AutoAnalyzer techniques. To measure ammonium concentrations, site water&amp;amp;nbsp;was cartridge-filtered (0.1 µm, Pall Co.) directly from Niskin bottles using a peristaltic pump. Filtrate was collected in&amp;amp;nbsp;FalconTM tubes that were pre-treated with orthophthaldialdehyde (OPA) and measured on-board via the OPA method&amp;amp;nbsp;(Holmes et al., 1999) with a detection limit of 10 nM.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
To measure particulate organic carbon and nitrogen, water was collected from the Niskin bottles and filtered through&amp;amp;nbsp;combusted 0.7 µm glass fiber filters (Whatman GF/F), rinsed with a weak acid (0.01 N HCl in seawater) to remove&amp;amp;nbsp;carbonates, then dried in combusted glass vials at 60 °C. Diatom biomass was assessed by sampling for biogenic&amp;amp;nbsp;silica. Samples were filtered through 0.6 µm polycarbonate filters, dried at 60°C in plastic Petri dishes, and dissolved in&amp;amp;nbsp;strong acid. &amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;For incubation-based primary productivity, water samples were taken from Niskin&amp;amp;nbsp;bottles at known isolumes, then placed in sterile 285 mL&amp;amp;nbsp;Qorpak bottles, then&amp;amp;nbsp;~20 µCi NaH14CO3&amp;amp;nbsp;was added. An on-deck incubator holding&amp;amp;nbsp;the bottles had&amp;amp;nbsp;surface seawater flowing through it, with irradiance attenuated&amp;amp;nbsp;by neutral density filters to the light&amp;amp;nbsp;levels at the isolumes sampled. Blue&amp;amp;nbsp;filters were used for isolumes below 30% Eo. After 24 h, samples&amp;amp;nbsp;were filtered through GFF filters and placed in 7 mL scintillation vials. Size&amp;amp;nbsp;fractionations were&amp;amp;nbsp;conducted at all stations using 20 µm Poretics filters on&amp;amp;nbsp;subsamples from each bottle. 100 µL 1N HCl&amp;amp;nbsp;was added to volatilize absorbed&amp;amp;nbsp;inorganic&amp;amp;nbsp;14C. Ecolume (5 mL) was then added to each vial, and all&amp;amp;nbsp;vials were counted after 24 h on a liquid scintillation counter. Total activity&amp;amp;nbsp;was measured by counting&amp;amp;nbsp;100 μL of non-acidified sample in&amp;amp;nbsp;β-phenethanylamine.&amp;amp;nbsp;&amp;lt;/p&amp;gt;</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;Sea-Bird Software:&amp;lt;br /&amp;gt;
- Data acquisition: SBE Seasave, version 7.26.7.107&amp;lt;br /&amp;gt;
- Data processing: SBE Data Processing, version 7.26.7.114&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Bad data is indicated with a flag:&amp;lt;br /&amp;gt;
Bad data flag=-9.990e-29&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;BCO-DMO data manager processing notes version 1:&amp;lt;br /&amp;gt;
* Data imported into the BCO-DMO dataset system from file rb1904_bottle_data_Dec_2020.txt&amp;lt;br /&amp;gt;
* Constructed ISO_DateTime_UTC from year, month, day and time columns which were NMEA UTC times.&amp;amp;nbsp;&amp;lt;br /&amp;gt;
* Made longitude negative since West is negative in decimal degrees.&amp;lt;br /&amp;gt;
* Switched columns OxyM and OxySat on request of submitter.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        </gmd:LI_Lineage>
      </gmd:lineage>
   </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
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        <gco:CharacterString>7.x-1.1</gco:CharacterString>
      </gmd:maintenanceNote>
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    <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/affiliation/191.rdf" xlink:actuate="onRequest">Biological and Chemical Oceanography Data Management Office (BCO-DMO)</gmx:Anchor>
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		    <gmd:CI_Telephone>
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				    <gco:CharacterString>USA</gco:CharacterString>
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		  <gmd:hoursOfService>
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		  <gmd:contactInstructions>
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    <gmi:instrument>
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This term applies to profiling CTDs. For fixed CTDs, see https://www.bco-dmo.org/instrument/869934. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/130/</gco:CharacterString>
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      <gmi:instrument>
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              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/480.rdf" xlink:title="LI-COR Biospherical PAR Sensor" xlink:actuate="onRequest">LI-COR Biospherical PAR</gmx:Anchor>
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          </gmi:identifier>
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          <gmi:description>
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        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
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              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/567.rdf" xlink:title="Pressure Sensor" xlink:actuate="onRequest">Pressure, Digiquartz with TC</gmx:Anchor>
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        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
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                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/552.rdf" xlink:title="Sea-Bird SBE 43 Dissolved Oxygen Sensor" xlink:actuate="onRequest">SBE 43 Dissolved Oxygen</gmx:Anchor>
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            <gco:CharacterString>PI Supplied Instrument Name: SBE 43 Dissolved Oxygen Instrument Name: Sea-Bird SBE 43 Dissolved Oxygen Sensor Instrument Short Name:SBE-43 DO   Instrument Description: The Sea-Bird SBE 43 dissolved oxygen sensor is a redesign of the Clark polarographic membrane type of dissolved oxygen sensors. more information from Sea-Bird Electronics Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0036/</gco:CharacterString>
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      </gmi:instrument>
      <gmi:instrument>
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                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/829841.rdf" xlink:title="Wet Labs ECO Puck" xlink:actuate="onRequest">Turbidity, WET Labs ECO</gmx:Anchor>
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          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: Turbidity, WET Labs ECO Instrument Name: Wet Labs ECO Puck Instrument Short Name:   Instrument Description: The Puck is a miniature version of the ECO series of sensors, specifically designed for use in AUVs, profiling floats, and Slocum gliders with a dry science bay. This compact optical sensor is available in combinations of backscattering and fluorescence measurements.
Manufacturer's website: https://www.seabird.com/auv-rov-sensors/eco-puck/family?productCategoryId=55352274651</gco:CharacterString>
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      <gmi:instrument>
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              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/592.rdf" xlink:title="Wet Labs ECO-AFL/FL Fluorometer" xlink:actuate="onRequest">ECO-AFL/FL</gmx:Anchor>
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          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>ECO-AFL/FL</gco:CharacterString>
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          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: ECO-AFL/FL Instrument Name: Wet Labs ECO-AFL/FL Fluorometer Instrument Short Name:ECO AFL/FL   Instrument Description: The Environmental Characterization Optics (ECO) series of single channel fluorometers delivers both high resolution and wide ranges across the entire line of parameters using 14 bit digital processing. The ECO series excels in biological monitoring and dye trace studies. The potted optics block results in long term stability of the instrument and the optional anti-biofouling technology delivers truly long term field measurements.
 more information from Wet Labs Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0172/</gco:CharacterString>
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