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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/880376.rdf" xlink:actuate="onRequest">Particle bulk d15N values from EXPORTS cruises SR1812 on R/V Sally Ride and RR1813 on R/V Roger Revelle in August to September 2018</gmx:Anchor>
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                        <gco:Date>2022-09-30</gco:Date>
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            <gco:CharacterString>Cite this dataset as: Wojtal, P. K., Popp, B. N., Close, H. G. (2022) Particle bulk d15N values from EXPORTS cruises SR1812 on R/V Sally Ride and RR1813 on R/V Roger Revelle in August to September 2018. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2022-09-13 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.880376.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Particle bulk d15N values Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;em&amp;gt;In situ&amp;lt;/em&amp;gt; pump filtration was performed using large volume pumps (WTS-LV; McLane Research Laboratories, Inc.) outfitted with mini-MULVFS (Multiple Unit Large Volume in-situ Filtration System) filter holders (Bishop et al. 2012). Pumps were loaded with filter stacks of either 3 filter pore sizes (51- and 5-um acid cleaned Nitex screens and 1 um pre-combusted quartz fiber filter) or 4 filter pore sizes (51- and 6-um acid cleaned Nitex screens, a double layer of 1 um pre-combusted quartz fiber filters, and a double layer of 0.3 um of pre-combusted glass fiber filters). Samples were frozen at -80 degrees Celsius until laboratory analysis. Sediment trap collection was performed using surface tethered sediment traps (STT) and neutrally buoyant sediment traps (NBST). Particles were collected in polycarbonate tubes with a collection area of 0.0113 m² and triggered to close at the end of the sampling period. Samples were collected in 500 mL of 70 ppt salinity, 0.1% formaldehyde-poisoned brine, buffered to pH 8.5 with borate and overlain with 1‑um filtered surface seawater. After collection and allowing particles to sink to the bottom of the tube on board the ship for an hour, brine was filtered through a 335‑um polyester screen and rotary wet split onto pre-combusted glass fiber filters with a pore size of 0.7 um. Samples were frozen at -80 degrees Celsius until laboratory analysis.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Subsamples were split gravimetrically and packed directly into tin capsules for elemental and isotopic composition.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Analyses were carried out using a Thermo Fisher Scientific Flash Elemental Analyzer (EA) coupled to a MAT 253 Plus Isotope Ratio Mass Spectrometer (IRMS) via a Conflo IV open split interface. The EA oxidation reactor was held at 980 degrees C, the reduction reactor at 650 degrees C, and the gas chromatography column at 65 degrees C.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/768319.rdf" xlink:title="OCE-1830016" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1830016 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1830016</gmx:Anchor>
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Ocean ecosystems play a critical role in the Earth’s carbon cycle and the quantification of their impacts for both present conditions and for predictions into the future remains one of the greatest challenges in oceanography. The goal of the EXport Processes in the Ocean from Remote Sensing (EXPORTS) Science Plan is to develop a predictive understanding of the export and fate of global ocean net primary production (NPP) and its implications for present and future climates. The achievement of this goal requires a quantification of the mechanisms that control the export of carbon from the euphotic zone as well as its fate in the underlying &quot;twilight zone&quot; where some fraction of exported carbon will be sequestered in the ocean’s interior on time scales of months to millennia. In particular, EXPORTS will advance satellite diagnostic and numerical prognostic models by comparing relationships among the ecological, biogeochemical and physical oceanographic processes that control carbon cycling across a range of ecosystem and carbon cycling states. EXPORTS will achieve this through a combination of ship and robotic field sampling, satellite remote sensing and numerical modeling. Through a coordinated, process-oriented approach, EXPORTS will foster new insights on ocean carbon cycling that maximizes its societal relevance through the achievement of U.S. and International research agency goals and will be a key step towards our understanding of the Earth as an integrated system.</gco:CharacterString>
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                            <gco:CharacterString>&lt;p&gt;&lt;em&gt;NSF Award Abstract:&lt;/em&gt;&lt;br /&gt;
The biological pump is largely responsible for the vertical transport of organic carbon from the surface to the ocean interior. However, only a small fraction of organic material produced in surface waters is sequestered in the deep ocean. The rest is consumed, or respired, by bacteria and larger organisms. The overarching goal of the proposed work is to characterize the relative influences of bacteria versus larger organisms on the degradation of organic material with depth. Guided by recent results from the subtropical Pacific, the investigators will use measurements of stable isotopes of nitrogen in different amino acids (compound-specific isotopic analysis of amino acids, known as AA-CSIA), along with measurements of the abundances of different forms of amino acids, and other parameters derived from these analyses to identify how the partitioning and flux of large and small particles are affected by different degradation processes. By improving the interpretive power of the AA-CSIA technique the investigators propose to determine: 1) the relative importance of microbial and zooplankton consumption on the efficiency of the biological carbon pump in the subarctic northeast Pacific, and 2) how much microbially-altered small particles fuel the metabolisms of mid-water zooplankton. This work capitalizes on an existing, comprehensive field program (NASA EXPORTS) specifically focused on building a predictive framework relating surface ocean properties to the vertical flux of organic carbon. The tremendous amount of data to be collected on all aspects of the biological pump as part of the EXPORTS program will aid the development and interpretation of the investigators' amino acid isotopic tool. Results will be broadly communicated via production and distribution of several episodes of Voice of the Sea, a local television program that will air in Hawaii and across many Pacific islands. Episodes also will be posted online and publicized through social media to the south Florida community. This project will support a Ph.D. student and an undergraduate student at University of Miami, which serves a 25% Hispanic population, and an M.S. student and an undergraduate student at University of Hawaii, which is a designated minority-serving institution.&lt;/p&gt;
&lt;p&gt;The proposed work introduces a new geochemical framework to distinguish microbial versus zooplankton alteration of marine organic matter. Piloted on samples from the subtropical Pacific, this approach interrogates unamended sinking material directly, using amino acid compound-specific isotopic analysis (AA-CSIA) to determine the progressive, cumulative impact of microbial and zooplankton degradative pathways. The proposed work (1) will extend this interpretive framework to explicitly define end-member signatures such as fecal pellets and will apply this refined method to a study site in the subarctic northeast Pacific to (2) determine the vertical progression of degradative mechanisms in an oceanographic location with contrasting productivity and vertical length scales of flux attenuation and (3) determine whether microbially- degraded biomass is important for fueling midwater metazoans under contrasting carbon flux conditions. The proposed work will be conducted in collaboration with the NASA EXPORTS program at the Ocean Station Papa time-series site. Teaming with this program presents a unique opportunity to refine AA-CSIA interpretation in parallel with intensive data collection defining productivity, particle size distribution and flux, and numerous biological parameters. In comparing subtropical and subarctic Pacific locations, the proposed work will test how differences in productivity and plankton community structure influence vertical patterns of consumption and alteration of phytodetritus by microbes and zooplankton, from surface to mesopelagic depths.&lt;/p&gt;
&lt;p&gt;This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.&lt;/p&gt;</gco:CharacterString>
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	Name: Cruise
	Units: Unitless
	Description: &lt;p&gt;Cruise designation&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880400.rdf
	Name: Cruise_SampleID
	Units: Unitless
	Description: &lt;p&gt;Sample Number given to each filter&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880401.rdf
	Name: R2R_Event
	Units: Unitless
	Description: &lt;p&gt;R2R catalog identifier for this cruise&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880402.rdf
	Name: Latitude
	Units: Decimal degrees North
	Description: &lt;p&gt;Latitude in decimal degrees North&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880403.rdf
	Name: Longitude
	Units: Decimal degrees West
	Description: &lt;p&gt;Longitude in decimal degrees West&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880404.rdf
	Name: ISO_DateTime_UTC
	Units: Unitless
	Description: &lt;p&gt;Date and time (UTC) of sampling in ISO8601 format: YYYY-MM-DDThh:mm:ssZ&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880405.rdf
	Name: Date
	Units: Unitless
	Description: &lt;p&gt;Sampling date (UTC); format: YYYY-MM-DD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880406.rdf
	Name: Time
	Units: Unitless
	Description: &lt;p&gt;Sampling time (UTC); format: hh:mm:ss&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880407.rdf
	Name: Depth
	Units: meters (m)
	Description: &lt;p&gt;Depth of pump deployment&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880408.rdf
	Name: Size_Fraction_Min
	Units: micrometers (mm)
	Description: &lt;p&gt;Minimum size fraction captured on filter&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880409.rdf
	Name: Size_Fraction_Max
	Units: micrometers (mm)
	Description: &lt;p&gt;Maximum size fraction captured on filter&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880410.rdf
	Name: Volume_Filtered
	Units: liters (L)
	Description: &lt;p&gt;Volume of water filtered through the filter&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880411.rdf
	Name: Start_R2R_Event
	Units: Unitless
	Description: &lt;p&gt;R2R catalog identifier for the start of the sediment trap deployment for this cruise&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880412.rdf
	Name: End_R2R_Event
	Units: Unitless
	Description: &lt;p&gt;R2R catalog identifier for the end of the sediment trap deployment for this cruise&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880413.rdf
	Name: Deploy_Latitude
	Units: Decimal degrees North
	Description: &lt;p&gt;Latitude at time of sediment trap deployment in decimal degrees North&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880414.rdf
	Name: Deploy_Longitude
	Units: Decimal degrees West
	Description: &lt;p&gt;Longitude at time of sediment trap deployment in decimal degrees West&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880415.rdf
	Name: Resurfaced_Latitude
	Units: Decimal degrees North
	Description: &lt;p&gt;Latitude at time of sediment trap resurface in decimal degrees North&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880416.rdf
	Name: Resurfaced_Longitude
	Units: Decimal degrees West
	Description: &lt;p&gt;Longitude at time of sediment trap resurface in decimal degrees West&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880417.rdf
	Name: Recover_Latitude
	Units: Decimal degrees North
	Description: &lt;p&gt;Latitude at time of sediment trap recovery in decimal degrees North&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880418.rdf
	Name: Recover_Longitude
	Units: Decimal degrees West
	Description: &lt;p&gt;Longitude at time of sediment trap recovery in decimal degrees West&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880419.rdf
	Name: ISO_DateTime_UTC_Deployed
	Units: Unitless
	Description: &lt;p&gt;Date and time (UTC) of sediment trap deployment in ISO8601 format: YYYY-MM-DDThh:mm:ssZ&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880420.rdf
	Name: Date_Deployed
	Units: Unitless
	Description: &lt;p&gt;Sediment trap deployment date (UTC); format: YYYY-MM-DD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880421.rdf
	Name: Time_Deployed
	Units: Unitless
	Description: &lt;p&gt;Sediment trap deployment time (UTC); format: hh:mm:ss&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880422.rdf
	Name: ISO_DateTime_UTC_AtDepth
	Units: Unitless
	Description: &lt;p&gt;Date and time (UTC) of sediment trap reaching sampling depth in ISO8601 format: YYYY-MM-DDThh:mm:ssZ&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880423.rdf
	Name: Date_AtDepth
	Units: Unitless
	Description: &lt;p&gt;Sediment trap reaching sampling depth date (UTC); format: YYYY-MM-DD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880424.rdf
	Name: Time_AtDepth
	Units: Unitless
	Description: &lt;p&gt;Sediment trap reaching sampling depth time (UTC); format: hh:mm:ss&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880425.rdf
	Name: ISO_DateTime_UTC_LidsClosed
	Units: Unitless
	Description: &lt;p&gt;Date and time (UTC) of sediment trap tube lids closing in ISO8601 format: YYYY-MM-DDThh:mm:ssZ&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880426.rdf
	Name: Date_LidsClosed
	Units: Unitless
	Description: &lt;p&gt;Sediment trap tube lids closing date (UTC); format: YYYY-MM-DD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880427.rdf
	Name: Time_LidsClosed
	Units: Unitless
	Description: &lt;p&gt;Sediment trap tube lids closing time (UTC); format: hh:mm:ss&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880428.rdf
	Name: ISO_DateTime_UTC_Resurfaced
	Units: Unitless
	Description: &lt;p&gt;Date and time (UTC) of sediment trap resurfacing in ISO8601 format: YYYY-MM-DDThh:mm:ssZ&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880429.rdf
	Name: Date_Resurfaced
	Units: Unitless
	Description: &lt;p&gt;Sediment trap resurfacing date (UTC); format: YYYY-MM-DD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880430.rdf
	Name: Time_Resurfaced
	Units: Unitless
	Description: &lt;p&gt;Sediment resurfacing time (UTC); format: hh:mm:ss&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880431.rdf
	Name: ISO_DateTime_UTC_Recovered
	Units: Unitless
	Description: &lt;p&gt;Date and time (UTC) of sediment trap recovery in ISO8601 format: YYYY-MM-DDThh:mm:ssZ&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880432.rdf
	Name: Date_Recovered
	Units: Unitless
	Description: &lt;p&gt;Sediment trap recovery date (UTC); format: YYYY-MM-DD&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880433.rdf
	Name: Time_Recovered
	Units: Unitless
	Description: &lt;p&gt;Sediment recovery time (UTC); format: hh:mm:ss&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880434.rdf
	Name: Target_Depth
	Units: meters (m)
	Description: &lt;p&gt;Target sampling depth for sediment traps&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880435.rdf
	Name: Actual_Depth
	Units: meters (m)
	Description: &lt;p&gt;Actual sampling depth for sediment traps&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880436.rdf
	Name: Time_Elapsed_Deploy_to_Recover
	Units: days (d)
	Description: &lt;p&gt;Time elapsed between sediment trap being deployed and sediment trap being recovered&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880437.rdf
	Name: Flux
	Units: square meters per day (m2/d)
	Description: &lt;p&gt;Area of collection of the sediment traps divided by the number of days of collection&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880438.rdf
	Name: d15N
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;The isotopic composition of particulate nitrogen in the sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880439.rdf
	Name: SD_d15N
	Units: permil relative to AIR (‰)
	Description: &lt;p&gt;The standard deviation of the isotopic composition of particulate nitrogen in the sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880440.rdf
	Name: PN_Conc
	Units: micromoles per cubic meter (mmol/m3)
	Description: &lt;p&gt;The concentration of particulate nitrogen in the sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/880441.rdf
	Name: PN_Flux
	Units: micromoles per square meter per day (mmol/m2/d)
	Description: &lt;p&gt;The flux of particulate nitrogen in the sample&lt;/p&gt; 
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&amp;lt;p&amp;gt;Subsamples were split gravimetrically and packed directly into tin capsules for elemental and isotopic composition.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Analyses were carried out using a Thermo Fisher Scientific Flash Elemental Analyzer (EA) coupled to a MAT 253 Plus Isotope Ratio Mass Spectrometer (IRMS) via a Conflo IV open split interface. The EA oxidation reactor was held at 980 degrees C, the reduction reactor at 650 degrees C, and the gas chromatography column at 65 degrees C.&amp;lt;/p&amp;gt;</gco:CharacterString>
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&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;BCO-DMO Processing:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
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Ambient water is drawn through a modular filter holder onto a 142-millimeter (mm) membrane without passing through the pump. The standard two-tier filter holder provides prefiltering and size fractioning. Collection targets include chlorophyll maximum, particulate trace metals, and phytoplankton. It features different flow rates and filter porosity to support a range of specimen collection. Sampling can be programmed to start at a scheduled time or begin with a countdown delay. It also features a dynamic pump speed algorithm that adjusts flow to protect the sample as material accumulates on the filter. Several pump options range from 0.5 to 30 liters per minute, with a max volume of 2,500 to 36,000 liters depending on the pump and battery pack used. The standard model is depth rated to 5,500 meters, with a deeper 7,000-meter option available. The operating temperature is -4 to 35 degrees Celsius.

The WTS-LV is available in four different configurations: Standard, Upright, Bore Hole, and Dual Filter Sampler. The high-capacity upright WTS-LV model provides three times the battery life of the standard model. The Bore-Hole WTS-LV is designed to fit through a narrow opening such as a 30-centimeter borehole. The dual filter WTS-LV features two vertical intake 142 mm filter holders to allow simultaneous filtering using two different porosities.</gco:CharacterString>
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