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        <gco:CharacterString>Radium isotope measurements from bottom waters in the South Atlantic Bight from 2015-2020 Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Methods &amp;amp;amp; Sampling&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Bottom water samples were obtained by lowering a submersible pump to near the seafloor and filling two 26-liter carboys. Subsamples for salinity were usually taken from each sample and measured with a YSI conductivity meter to confirm the CTD measurement. Radium samples were filtered through a column of Mn-fiber to quantitatively remove Ra [Moore, 1976]. The Mn-fiber was returned to the lab, where short-lived radium isotopes (&amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra, half-life = 11.4 days, and &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra, half-life = 3.66 days) were measured using a delayed-coincidence counting system [Moore and Arnold, 1996]. After the short-lived measurements were complete, Ra and Mn were stripped from the Mn-fiber and radium was coprecipitated with BaSO&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt; and transferred to a small tube. &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Ra were measured by gamma spectrometry after &amp;lt;sup&amp;gt;222&amp;lt;/sup&amp;gt;Rn had equilibrated with &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra [Moore et al., 1985]. The RaDeCC systems were calibrated for 224Ra with a NIST standard solution of 232Th adsorbed to Mn-fiber and for 223Ra by the technique of Moore and Cai [2013]. The gamma detector was calibrated with NIST standard solutions for &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Ra in a BaSO&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt; matrix [Moore, 1984].&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples were taken from R/V Trinity, owned by a private charter company called Charleston SCUBA. This company is no longer in operation.&amp;amp;nbsp;&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/712749.rdf" xlink:title="OCE-1736557" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1736557 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1736557</gmx:Anchor>
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&amp;lt;p&amp;gt;Bottom water samples were obtained by lowering a submersible pump to near the seafloor and filling two 26-liter carboys. Subsamples for salinity were usually taken from each sample and measured with a YSI conductivity meter to confirm the CTD measurement. Radium samples were filtered through a column of Mn-fiber to quantitatively remove Ra [Moore, 1976]. The Mn-fiber was returned to the lab, where short-lived radium isotopes (&amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra, half-life = 11.4 days, and &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra, half-life = 3.66 days) were measured using a delayed-coincidence counting system [Moore and Arnold, 1996]. After the short-lived measurements were complete, Ra and Mn were stripped from the Mn-fiber and radium was coprecipitated with BaSO&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt; and transferred to a small tube. &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Ra were measured by gamma spectrometry after &amp;lt;sup&amp;gt;222&amp;lt;/sup&amp;gt;Rn had equilibrated with &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra [Moore et al., 1985]. The RaDeCC systems were calibrated for 224Ra with a NIST standard solution of 232Th adsorbed to Mn-fiber and for 223Ra by the technique of Moore and Cai [2013]. The gamma detector was calibrated with NIST standard solutions for &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Ra in a BaSO&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt; matrix [Moore, 1984].&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples were taken from R/V Trinity, owned by a private charter company called Charleston SCUBA. This company is no longer in operation.&amp;amp;nbsp;&amp;lt;/p&amp;gt;</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Processing notes from researcher:&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The 224Ra and 223Ra counting data were analyzed using the procedure detailed in Moore and Arnold [1996] to correct for chance coincidence events. The gamma spectra for 228Ra and 226Ra were analyzed using the program HYPERMET, which employs multiple iterations to fit each peak in the spectra to an energy range [Phillips and Marlow, 1996]. The energy ranges are assigned to specific radionuclides based on the measurements of NIST standards.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;BCO-DMO processing notes:&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;Added a date field (a concatenation of the year, day and month fields)&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;Replaced spaces in column names with underscores &amp;quot;_&amp;quot;&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;Removed units and special characters from column names&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;Renamed column names that started with numerical characters (e.g., 226Ra is now Measured_226_Ra)&amp;lt;/li&amp;gt;
&amp;lt;/ul&amp;gt;</gco:CharacterString>
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                        <gco:CharacterString>Specified by the Principal Investigator(s)</gco:CharacterString>
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                      <gmd:date gco:nilReason="unknown"/>
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				    <gco:CharacterString>508-289-2009</gco:CharacterString>
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				    <gco:CharacterString>WHOI MS#36</gco:CharacterString>
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				    <gco:CharacterString>Woods Hole</gco:CharacterString>
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              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/670659.rdf" xlink:title="Gamma Ray Spectrometer" xlink:actuate="onRequest">Gamma Spectrometer, ORTEC</gmx:Anchor>
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            <gco:CharacterString>PI Supplied Instrument Name: Gamma Spectrometer, ORTEC PI Supplied Instrument Description:After the short-lived measurements were complete, Ra and Mn were stripped from the Mn-fiber and radium was coprecipitated with BaSO4 and transferred to a small tube. 226Ra and 228Ra were measured by gamma spectrometry after 222Rn had equilibrated with 226Ra [Moore et al., 1985]. Instrument Name: Gamma Ray Spectrometer Instrument Short Name:   Instrument Description: Instruments measuring the relative levels of electromagnetic radiation of different wavelengths in the gamma-ray waveband.</gco:CharacterString>
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                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/726.rdf" xlink:title="Pump" xlink:actuate="onRequest">Submersible pump, Granger</gmx:Anchor>
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            <gco:CharacterString>PI Supplied Instrument Name: Submersible pump, Granger PI Supplied Instrument Description:Bottom water samples were obtained by lowering a submersible pump to near the seafloor and filling two 26-liter carboys. Instrument Name: Pump Instrument Short Name:   Instrument Description: A pump is a device that moves fluids (liquids or gases), or sometimes slurries, by mechanical action. Pumps can be classified into three major groups according to the method they use to move the fluid: direct lift, displacement, and gravity pumps</gco:CharacterString>
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                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/688.rdf" xlink:title="Radium Delayed Coincidence Counter" xlink:actuate="onRequest">RaDeCC System</gmx:Anchor>
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References:
Giffin, C., A. Kaufman, W.S. Broecker (1963). Delayed coincidence counter for the assay of actinon and thoron. J. Geophys. Res., 68, pp. 1749-1757.
Moore, W.S., R. Arnold (1996). Measurement of 223Ra and 224Ra in coastal waters using a delayed coincidence counter. J. Geophys. Res., 101 (1996), pp. 1321-1329.
Charette, Matthew A.; Dulaiova, Henrieta; Gonneea, Meagan E.; Henderson, Paul B.; Moore, Willard S.; Scholten, Jan C.; Pham, M. K. (2012). GEOTRACES radium isotopes interlaboratory comparison experiment. Limnology and Oceanography - Methods, vol 10, pg 451.</gco:CharacterString>
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