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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/896598.rdf" xlink:actuate="onRequest">Dissolved inorganic carbon and total alkalinity fluxes from sediment incubation experiments during four R/V Pelican cruises to the Louisiana shelf in 2017 and 2018</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Lehrter, J., Fung, M., Hagemeyer, A. (2023) Dissolved inorganic carbon and total alkalinity fluxes from sediment incubation experiments during four R/V Pelican cruises to the Louisiana shelf in 2017 and 2018. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2023-05-30 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.896598.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Methods and Sampling: &amp;lt;p&amp;gt;At each site during the R/V Pelican cruises, a box corer was used to collect surface sediment. The box core was subsampled in triplicate using 40 cm acrylic tubes that were pushed into the sediment to refusal, i.e. 20-30 cm. Cores were extracted in the acrylic tubes, capped on the bottom with an acrylic cap and o-ring, and submerged in a dark incubator filled with bottom water collected at the site. Each core was carefully filled with &amp;lt;em&amp;gt;in situ &amp;lt;/em&amp;gt;near bottom water with minimum disturbance to the sediment-water interface and closed to ensure no visible headspace or air bubbles at the top.&amp;amp;nbsp;The submerged cores were allowed to equilibrate with the water in the incubator for 12 hours. A control was included that was an acrylic liner filled with bottom water only. Following this equilibration step, the cores were capped on their tops with an acrylic cap and o-ring. The top caps contained two sampling ports that were opened to collect water samples from the water overlying the sediments in the core tubes.&amp;amp;nbsp;The overlying water was mixed by a slowly turning magnetic stir bar suspended from the top cap. All cores were attached to a reservoir containing bottom water for gravity driven replenishment of water inside the core tubes during sampling.&amp;amp;nbsp;After capping, sampling commenced.&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples for DIC were taken every 4-8 hours for up to 23 hours (4-6 time points) from the four cores, i.e. one control core with bottom water only (identified as ‘Control’)&amp;amp;nbsp; and three cores with sediments and bottom water (identified as ‘Rep1’, ‘Rep2’, and ‘Rep3’).&amp;amp;nbsp; Dissolved inorganic carbon (DIC) and total alkalinity (TA) concentrations were analyzed in each sample by Wei Jun Cai’s lab at the University of Delaware. For DIC, 1 ml of water sample was measured in triplicate with an infrared CO2 detector-based DIC analyzer (AS-C3 Apollo Scitech). For TA, a 25 ml water sample was measured in duplicate with the open-cell Gran titration method using a temperature-controlled, semi-automated titrator (AS-ALK2 Apollo Scitech). Certified Reference Materials provided by A. G. Dickson, Scripps Institution of Oceanography, were analyzed for DIC and TA for quality control.&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;em&amp;gt;Detailed methods are provided in Wang et al. (2020) and Lehrter et al. (2012).&amp;amp;nbsp;&amp;amp;nbsp;&amp;lt;/em&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;u&amp;gt;Problem report&amp;lt;/u&amp;gt;: &amp;amp;nbsp;Data for a few time points are missing due to lost or broken sample containers.&amp;amp;nbsp; For 1801 C6, there is missing data, so assumed depths are presented based on the depths similar to the last sampling on cruise 1710 C6-2.&amp;amp;nbsp;&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/781475.rdf" xlink:title="OCE-1760747" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1760747 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1760747</gmx:Anchor>
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	Description: &lt;p&gt;Density of water sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/896651.rdf
	Name: DIC_conc_weight
	Units: micromoles per kilogram (umol/kg)
	Description: &lt;p&gt;DIC concentration (weight)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/896652.rdf
	Name: TA
	Units: micromoles per kilogram (umol/kg)
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http://lod.bco-dmo.org/id/dataset-parameter/896653.rdf
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	Units: unitless
	Description: &lt;p&gt;Sample replicate names where Rep 1, Rep 2, Rep 3 for sediment cores and Control for cores with bottom water only&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/896654.rdf
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http://lod.bco-dmo.org/id/dataset-parameter/896655.rdf
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	Units: meters
	Description: &lt;p&gt;Depth of the bottom water within the sampling tubes&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/896656.rdf
	Name: Bottom_Depth
	Units: meters
	Description: &lt;p&gt;Depth of the seafloor at sampling site&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/896657.rdf
	Name: CruiseStation
	Units: unitless
	Description: &lt;p&gt;Cruise and Station ID combination&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/896658.rdf
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	Description: &lt;p&gt;Date of sediment collection&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/896659.rdf
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&amp;lt;p&amp;gt;Samples for DIC were taken every 4-8 hours for up to 23 hours (4-6 time points) from the four cores, i.e. one control core with bottom water only (identified as ‘Control’)&amp;amp;nbsp; and three cores with sediments and bottom water (identified as ‘Rep1’, ‘Rep2’, and ‘Rep3’).&amp;amp;nbsp; Dissolved inorganic carbon (DIC) and total alkalinity (TA) concentrations were analyzed in each sample by Wei Jun Cai’s lab at the University of Delaware. For DIC, 1 ml of water sample was measured in triplicate with an infrared CO2 detector-based DIC analyzer (AS-C3 Apollo Scitech). For TA, a 25 ml water sample was measured in duplicate with the open-cell Gran titration method using a temperature-controlled, semi-automated titrator (AS-ALK2 Apollo Scitech). Certified Reference Materials provided by A. G. Dickson, Scripps Institution of Oceanography, were analyzed for DIC and TA for quality control.&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;em&amp;gt;Detailed methods are provided in Wang et al. (2020) and Lehrter et al. (2012).&amp;amp;nbsp;&amp;amp;nbsp;&amp;lt;/em&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;u&amp;gt;Problem report&amp;lt;/u&amp;gt;: &amp;amp;nbsp;Data for a few time points are missing due to lost or broken sample containers.&amp;amp;nbsp; For 1801 C6, there is missing data, so assumed depths are presented based on the depths similar to the last sampling on cruise 1710 C6-2.&amp;amp;nbsp;&amp;amp;nbsp;&amp;lt;/p&amp;gt;

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A box corer is a marine geological tool that recovers undisturbed soft surface sediments. It is designed for minimum disturbance of the sediment surface by bow wave effects. Traditionally, it consists of a weighted stem fitted to a square sampling box. The corer is lowered vertically until it impacts with the seabed. At this point the instrument is triggered by a trip as the main coring stem passes through its frame. While pulling the corer out of the sediment a spade swings underneath the sample to prevent loss. When hauled back on board, the spade is under the box. (definition from the SeaVox Device Catalog)

Box corers are one of the simplest and most commonly used types of sediment corers. The stainless steel sampling box can contain a surface sediment block as large as 50cm x 50cm x 75cm with negligible disturbance. Once the sediment is recovered onboard, the sediment box can be detached from the frame and taken to a laboratory for subsampling and further analysis. The core sample size is controlled by the speed at which the corer is lowered into the ocean bottom. When the bottom is firm, a higher speed is required to obtain a complete sample. A depth pinger or other depth indicator is generally used to determine when the box is completely filled with sediment. Once the core box is filled with sediment, the sample is secured by moving the spade-closing lever arm to lower the cutting edge of the spade into the sediment, until the spade completely covers the bottom of the sediment box. (definition from Woods Hole Oceanographic Institution). Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/51/</gco:CharacterString>
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