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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/896884.rdf" xlink:actuate="onRequest">Dissolved trace metal (Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb) and labile particulate elemental (P, V, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb) concentrations from shipboard incubation experiments conducted on the 2018 EXPORTS cruise (RR1813) near Ocean Station PAPA</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Buck, K., Burns, S. M., Jenkins, B. D., Brzezinski, M. A. (2023) Dissolved trace metal (Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb) and labile particulate elemental (P, V, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb) concentrations from shipboard incubation experiments conducted on the 2018 EXPORTS cruise (RR1813) near Ocean Station PAPA. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2023-06-06 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.896884.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Dissolved Trace Metals and Labile Particulate Elements from Shipboard Incubations Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;Seawater for six shipboard incubation experiments was collected using a surface towfish (Mellett and Buck 2020) at ~2 meters (m) depth on the R/V Roger Revelle between 15 August 2018 and 29 August 2018. Water was prefiltered through a 150-µm mesh to remove large grazers. For incubations (Inc) 1-2 and 4-5, water was homogenized into 20-liter (L) carboys, and three carboys were amended for each treatment indicated in Table 1 (see Supplemental Files), yielding triplicates for each treatment and timepoint sampled. Each carboy was sampled once at the indicated timepoints. Control carboys sampled at the beginning and end of each incubation were unique to the timepoint (i.e., no carboy was resampled over time). For Incs 3 and 6, water was first homogenized into two 20-L carboys, from which 4-L bottles were filled and amended with the treatments indicated in Table 1. Three 4-L bottles were amended for each treatment, and each 4-L bottle was sampled once at the indicated timepoints, yielding triplicates.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Incubations 1 and 4 were carried out for 24 hours, Inc 2 and 3 for 6 days, and Inc 5 and 6 for 8 days (Table 1). The nutrient amendments for each experiment were selected to induce nutrient stress. For Inc 2 and Inc 5, we refer to the +20 μM nitrate +1.25 μM phosphate +20 μM silicic acid treatment as &amp;quot;AllButFe&amp;quot; and the +20 μM nitrate +1.25 μM phosphate +5 nM ⁵⁷FeCl₃ treatment as &amp;quot;AllButSi&amp;quot;.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Dissolved (&amp;amp;lt;0.4 μm) trace metal samples were collected in acid-cleaned 125-milliliter (mL) low-density polyethylene (LDPE, Nalgene) bottles, and acidified to 0.024 M hydrochloric acid (HCl, Fisher Optima). Dissolved trace metal (Fe, Cu, Mn, Co, Ni, Cu, Zn, Cd, Pb) concentrations were determined by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) at the University of South Florida (USF) on an Element XR (Hollister et al. 2020; Burns et al. 2023).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Leachable particulate trace metals were collected on 0.4-μm and 5-μm polycarbonate track etch (PCTE) filters, transferred into 1.5-mL high-density polyethylene (HDPE) snap-cap vials, and frozen at -20 degrees Celsius until processed. Filters were leached in a heated 25% acetic acid leach with a reducing step, &amp;quot;Berger Leach&amp;quot;, at National High Magnetic Field Laboratory (NHMFL) to extract the leachable particulate trace metals (Berger et al. 2008). Leachable particulate elemental (P, V, Fe, Cu, Mn, Co, Ni, Cu, Zn, Cd, Pb) concentrations were determined by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) on an Element 2 with the assistance of Dr. Peter Morton of Florida State University (FSU).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Sample analyses for dissolved trace metals and leachable particulate trace metals were performed by Shannon Burns (USF). Detection limits and quality control results are presented in Table 2 (see Supplemental Files).&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/757386.rdf" xlink:title="OCE-1756816" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1756816 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1756816</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/757391.rdf" xlink:title="OCE-1756433" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1756433 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1756433</gmx:Anchor>
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This project focuses on a group of microscopic single-celled photosynthetic organisms in the ocean called diatoms. Diatoms float in the surface ocean as part of a group of organisms collectively called phytoplankton. There are thousands of different species of diatoms distributed across the global ocean. A famous oceanographer Henry Bigelow once said &quot;All fish is diatoms&quot; reflecting the importance of diatoms as the base of the food chain that supports the world's largest fisheries. Despite their small size, diatom photosynthesis produces 20% of the oxygen on earth each year. That's more than all of the tropical rain forests on land. The major objective of the research is to understand how the metabolic differences among diatom species affects the amount of diatom organic carbon that is carried, or exported, from the surface ocean to the deep ocean. As diatoms are photo-synthesizers like green plants, their biological carbon comes from converting carbon dioxide dissolved in seawater from the atmosphere into organic forms. Diatoms also require a series of other nurtrients supplied by the ocean such as nitrogen and phosphorous and, uniquely for diatoms, the silicon used to construct their glass shells. This research will investigate how genetic and physiological differences among diatoms influence how each species react to changes in nutrient levels in the ocean and how those shifts affect the export of diatom carbon to the deep sea. The link between diatoms' physiological response and their carbon export comes about because shifts in physiology affect diatom attributes like how fast they sink and how tasty they are to predators. So if we can relate the physiological condition of different diatoms to the food-web pathways followed by different species, we can ultimately use knowledge of diatom physiological status and food web structure to predict how much diatom carbon gets to the deep sea. The research involves investigators with expertise in the physiology and genomics of diatoms and in the ocean's chemistry. The work will initially take place in the subarctic North Pacific in conjunction with the NASA Export Processes in the Ocean from RemoTe Sensing (EXPORTS) field program. The EXPORTS program is using a wide variety of methods to quantify the export and fate of photo-synthetically fixed carbon in the upper ocean. The research supports the training of undergraduate students, graduate students and a postdoctoral scholar. The research will also serve as the basis for activities aimed at K-12 and junior high school students.&lt;/p&gt;
&lt;p&gt;The research will broadly impact our understanding of the biology of the biological pump (the transport of photo-synthetically fixed organic carbon to the deep sea) by forming a mechanistic basis for predicting the export of diatom carbon. It is hypothesized that the type and degree of diatom physiological stress are vital aspects of ecosystem state that drive export. To test this hypothesis, the genetic composition, rates of nutrient use and growth response of diatom communities will be evaluated and supported with measurements of silicon and iron stress to evaluate stress as a predictor of the path of diatom carbon export. The subarctic N. Pacific ecosystem is characterized as high nutrient low chlorophyll (HNLC) due to low iron (Fe) levels that are primary controllers constraining phytoplankton utilization of other nutrients. It has been a paradigm in low Fe, HNLC systems that diatoms grow at elevated Si:C and Si:N ratios and should be efficiently exported as particles significantly enriched in Si relative to C. However, Fe limitation also alters diatoms species composition and the high Si demand imposed by low Fe can drive HNLC regions to Si limitation or Si/Fe co-limitation. Thus, the degree of Si and/or Fe stress in HNLC waters can all alter diatom taxonomic composition, the elemental composition of diatom cells, and the path cells follow through the food web ultimately altering diatom carbon export.&lt;/p&gt;
&lt;p&gt;This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.&lt;/p&gt;</gco:CharacterString>
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            http://lod.bco-dmo.org/id/dataset-parameter/897130.rdf
	Name: SAMPLE_DATE
	Units: unitless
	Description: &lt;p&gt;Date when incubation sample was collected.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897131.rdf
	Name: JULIAN_DAY
	Units: unitless
	Description: &lt;p&gt;Day of year sampled.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897132.rdf
	Name: EPOCH
	Units: unitless
	Description: &lt;p&gt;Assigned time block (8 or 9 days each) during the cruise, #1-3.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897133.rdf
	Name: EPOCH_DAY
	Units: unitless
	Description: &lt;p&gt;Day within the epoch time block.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897134.rdf
	Name: INCUBATION
	Units: unitless
	Description: &lt;p&gt;Incubation number, #1-6.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897135.rdf
	Name: TIMEPOINT
	Units: unitless
	Description: &lt;p&gt;Stage of incubation, initial or final.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897136.rdf
	Name: TREATMENT
	Units: unitless
	Description: &lt;p&gt;Nutrient amendment; see Table 1 (Supplemental File)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897137.rdf
	Name: REPLICATE
	Units: unitless
	Description: &lt;p&gt;Incubations were conducted with triplicate bottles or carboys per treatment. Carboy (20-liters) or bottle (4-liters), #1-3.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897138.rdf
	Name: Mn_D_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of dissolved manganese (Mn).&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897139.rdf
	Name: Mn_D_CONC_STDEV
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897140.rdf
	Name: Mn_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897141.rdf
	Name: Mn_D_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Mn_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897142.rdf
	Name: Fe_D_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of total dissolved iron (Fe) in a sample. NOTE: Dissolved Fe concentrations in the incubations were higher than the towfish surface samples collected during incubation initiation. These samples were likely contaminated during incubation setup or sampling and are accompanied by Flag 3.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897143.rdf
	Name: Fe_D_CONC_STDEV
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897144.rdf
	Name: Fe_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897145.rdf
	Name: Fe_D_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Fe_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897146.rdf
	Name: ADD_Fe57_D_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of added Fe-57 in a sample. In the treatments where no 57Fe was added, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897147.rdf
	Name: ADD_Fe57_D_CONC_STDEV
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897148.rdf
	Name: ADD_Fe57_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897149.rdf
	Name: ADD_Fe57_D_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for ADD_Fe57_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897150.rdf
	Name: Co_D_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of dissolved cobalt (Co).&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897151.rdf
	Name: Co_D_CONC_STDEV
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897152.rdf
	Name: Co_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897153.rdf
	Name: Co_D_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Co_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897154.rdf
	Name: Ni_D_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of dissolved nickel (Ni).&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897155.rdf
	Name: Ni_D_CONC_STDEV
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897156.rdf
	Name: Ni_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897157.rdf
	Name: Ni_D_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Ni_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897158.rdf
	Name: Cu_D_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of dissolved copper (Cu).&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897159.rdf
	Name: Cu_D_CONC_STDEV
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897160.rdf
	Name: Cu_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897161.rdf
	Name: Cu_D_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Cu_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897162.rdf
	Name: Zn_D_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of dissolved zinc (Zn). NOTE: Dissolved Zn concentrations in the incubations were higher than the towfish surface samples collected during incubation initiation. These samples were likely contaminated during incubation setup or sampling and are accompanied by Flag 3.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897163.rdf
	Name: Zn_D_CONC_STDEV
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897164.rdf
	Name: Zn_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897165.rdf
	Name: Zn_D_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Zn_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897166.rdf
	Name: Cd_D_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of dissolved cadmium (Cd).&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897167.rdf
	Name: Cd_D_CONC_STDEV
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897168.rdf
	Name: Cd_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897169.rdf
	Name: Cd_D_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Cd_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897170.rdf
	Name: Pb_D_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of dissolved lead (Pb).&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897171.rdf
	Name: Pb_D_CONC_STDEV
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Standard deviation of replicate analyses of this sample, or difference about the mean if n=2. When no replicate analyses were performed, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897172.rdf
	Name: Pb_D_CONC_n
	Units: unitless
	Description: &lt;p&gt;Number of times this sample was analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897173.rdf
	Name: Pb_D_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Pb_D_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897174.rdf
	Name: P_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) phosphorus (P). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897175.rdf
	Name: P_SLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for P_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897176.rdf
	Name: V_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) vanadium (V). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897177.rdf
	Name: V_SLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for V_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897178.rdf
	Name: Mn_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) manganese (Mn). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897179.rdf
	Name: Mn_SLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Mn_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897180.rdf
	Name: Fe_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) iron (Fe). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897181.rdf
	Name: Fe_SLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Fe_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897182.rdf
	Name: ADD_Fe57_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) added iron-57 (Fe57). In the treatments where no 57Fe was added, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used. The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was also used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897183.rdf
	Name: ADD_Fe57_SLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for ADD_Fe57_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897184.rdf
	Name: Co_SLP_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) cobalt (Co). The &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897185.rdf
	Name: Co_SLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Co_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897186.rdf
	Name: Ni_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) nickel (Ni). The &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897187.rdf
	Name: Ni_SLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Data quality flag for&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897188.rdf
	Name: Cu_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) copper (Cu). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897189.rdf
	Name: Cu_SLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Cu_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897190.rdf
	Name: Zn_SLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) zinc (Zn). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897191.rdf
	Name: Zn_SLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Zn_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897192.rdf
	Name: Cd_SLP_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) cadmium (Cd). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897193.rdf
	Name: Cd_SLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Cd_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897194.rdf
	Name: Pb_SLP_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of small leachable particulate (SLP; 0.4-5 micrometer (um) size fraction) lead (Pb). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897195.rdf
	Name: Pb_SLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for P_SLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897196.rdf
	Name: P_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) phosphorus (P). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897197.rdf
	Name: P_LLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for P_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897198.rdf
	Name: V_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) vanadium (V). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897199.rdf
	Name: V_LLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897200.rdf
	Name: Mn_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) manganese (Mn). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897201.rdf
	Name: Mn_LLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Mn_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897202.rdf
	Name: Fe_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) iron (Fe). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897203.rdf
	Name: Fe_LLP_CONC_Flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Mn_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897204.rdf
	Name: ADD_Fe57_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) added iron-57 (Fe57). In the treatments where no 57Fe was added, the notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used. The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was also used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897205.rdf
	Name: ADD_Fe57_LLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for ADD_Fe57_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897206.rdf
	Name: Co_LLP_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) cobalt (Co). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897207.rdf
	Name: Co_LLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Co_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897208.rdf
	Name: Ni_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) nickel (Ni). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897209.rdf
	Name: Ni_LLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Ni_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897210.rdf
	Name: Cu_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) copper (Cu). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897211.rdf
	Name: Cu_LLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Cu_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897212.rdf
	Name: Zn_LLP_CONC
	Units: nanomoles per liter (nM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) zinc (Zn). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897213.rdf
	Name: Zn_LLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Zn_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897214.rdf
	Name: Cd_LLP_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) cadmium (Cd). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897215.rdf
	Name: Cd_LLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Cd_LLP_CONC.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897216.rdf
	Name: Pb_LLP_CONC
	Units: picomoles per liter (pM)
	Description: &lt;p&gt;Concentration of large leachable particulate (LLP; &amp;gt;5 micrometers (um) size fraction) lead (Pb). The notation &amp;#039;na&amp;#039; = &amp;#039;not applicable&amp;#039; was used for samples not analyzed. Values below the limit of detection [see Table 2 for detection limits] are replaced with &amp;#039;nd&amp;#039; for &amp;#039;not detectable&amp;#039; and accompanied by Flag 6 in the dataset.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/897217.rdf
	Name: Pb_LLP_CONC_flag
	Units: unitless
	Description: &lt;p&gt;Ocean Data View quality flag (see Processing Description for definitions) for Pb_LLP_CONC.&lt;/p&gt; 
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&amp;lt;p&amp;gt;Incubations 1 and 4 were carried out for 24 hours, Inc 2 and 3 for 6 days, and Inc 5 and 6 for 8 days (Table 1). The nutrient amendments for each experiment were selected to induce nutrient stress. For Inc 2 and Inc 5, we refer to the +20 μM nitrate +1.25 μM phosphate +20 μM silicic acid treatment as &amp;quot;AllButFe&amp;quot; and the +20 μM nitrate +1.25 μM phosphate +5 nM ⁵⁷FeCl₃ treatment as &amp;quot;AllButSi&amp;quot;.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Dissolved (&amp;amp;lt;0.4 μm) trace metal samples were collected in acid-cleaned 125-milliliter (mL) low-density polyethylene (LDPE, Nalgene) bottles, and acidified to 0.024 M hydrochloric acid (HCl, Fisher Optima). Dissolved trace metal (Fe, Cu, Mn, Co, Ni, Cu, Zn, Cd, Pb) concentrations were determined by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) at the University of South Florida (USF) on an Element XR (Hollister et al. 2020; Burns et al. 2023).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Leachable particulate trace metals were collected on 0.4-μm and 5-μm polycarbonate track etch (PCTE) filters, transferred into 1.5-mL high-density polyethylene (HDPE) snap-cap vials, and frozen at -20 degrees Celsius until processed. Filters were leached in a heated 25% acetic acid leach with a reducing step, &amp;quot;Berger Leach&amp;quot;, at National High Magnetic Field Laboratory (NHMFL) to extract the leachable particulate trace metals (Berger et al. 2008). Leachable particulate elemental (P, V, Fe, Cu, Mn, Co, Ni, Cu, Zn, Cd, Pb) concentrations were determined by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) on an Element 2 with the assistance of Dr. Peter Morton of Florida State University (FSU).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Sample analyses for dissolved trace metals and leachable particulate trace metals were performed by Shannon Burns (USF). Detection limits and quality control results are presented in Table 2 (see Supplemental Files).&amp;lt;/p&amp;gt;</gco:CharacterString>
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Data were processed using ESI SC version 2.9.0.380.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Data Quality Flags:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
The standard Ocean Data View (ODV) / SeaDataNet qualifying flags were used (reference all flags at &amp;lt;a href=&amp;quot;http://vocab.nerc.ac.uk/collection/L20/current/&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;http://vocab.nerc.ac.uk/collection/L20/current/&amp;lt;/a&amp;gt;). The notation 'na' = 'not applicable' was used for samples not analyzed.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;1: Good Value:&amp;lt;/strong&amp;gt; Good quality data value that is not part of any identified malfunction and has been verified as consistent with real phenomena during the quality control process. [Used when replicates were in good agreement and/or when dataset agreed with previously published results].&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;2: Probably Good Value:&amp;lt;/strong&amp;gt; Data value that is probably consistent with real phenomena but this is unconfirmed. [Used when no replicates or published datasets to compare.]&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;3: Probably Bad Value:&amp;lt;/strong&amp;gt; Data value recognized as unusual during quality control that forms part of a feature that is probably inconsistent with real phenomena. [Used when data not oceanographically consistent but replicate analyses agreed.]&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;4: Bad Value:&amp;lt;/strong&amp;gt; An obviously erroneous data value. [Used when replicates did not agree].&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;5: Changed Value:&amp;lt;/strong&amp;gt; Data value adjusted during quality control. [Not used.]&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;6: Value Below Detection Limit:&amp;lt;/strong&amp;gt; The level of the measured phenomenon was too small to be quantified by the technique employed to measure it. Values are replaced with 'nd' for 'not detectable'. [See Table 2 for detection limits.]&amp;lt;br /&amp;gt;
&amp;lt;strong&amp;gt;7: Value in Excess:&amp;lt;/strong&amp;gt; The level of the measured phenomenon was too large to be quantified by the technique employed to measure it. The accompanying value is the measurement limit for the technique. [Not used.]&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;BCO-DMO Processing:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
- converted SAMPLE_DATE column to YYYY-MM-DD format;&amp;lt;br /&amp;gt;
- renamed fields to comply with BCO-DMO naming conventions.&amp;lt;/p&amp;gt;</gco:CharacterString>
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    <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/affiliation/191.rdf" xlink:actuate="onRequest">Biological and Chemical Oceanography Data Management Office (BCO-DMO)</gmx:Anchor>
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         <gmx:Anchor xlink:href="http://shipsked.ucsd.edu/Ships/Roger_Revelle/" xlink:actuate="onRequest">R/V Roger Revelle</gmx:Anchor>
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    <gmi:citation>
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         <gmx:Anchor xlink:href="http://vocab.nerc.ac.uk/collection/C17/current/33RR" xlink:actuate="onRequest">Community Standard Description</gmx:Anchor>
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              <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/authority/1.rdf" xlink:actuate="onRequest">International Council for the Exploration of the Sea</gmx:Anchor>
            </gmd:title>
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          <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54013.rdf"
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      <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/platform/54013.rdf" xlink:title="R/V Roger Revelle" xlink:actuate="onRequest">vessel</gmx:Anchor>
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