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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/908342.rdf" xlink:actuate="onRequest">1-decibar binned CTD data from 103 stations collected during R/V Roger Revelle cruise RR2004 along the 150W meridian from 30S to 60S</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Balch, W. M., McGillicuddy, D. J., Oliver, H. (2023) 1-decibar binned CTD data from 103 stations collected during R/V Roger Revelle cruise RR2004 along the 150W meridian from 30S to 60S. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2023-09-22 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.908342.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>RR2004 CTD Data Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;These data were collected during cruise RR2004 on the R/V Roger Revelle using a Sea-Bird SBE911plus CTD. This cruise departed Honolulu, Hawaii on December 26, 2020 and the ship transited south along the great circle route from Honolulu to 30°S x 150°W, returning to Hawaii on February 23, 2021. CTD casts were performed at 103 stations, encompassing Subtropical, Subantarctic, and Polar waters in the Pacific Sector of the Southern Ocean.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Hydrographic profiles were performed along the transect with the CTD (the &amp;quot;full-water cast&amp;quot;), sampling for Freons, dissolved oxygen, DIC, alkalinity, extracted chlorophyll, nutrients, POC, PIC, biogenic silica, coccolithophore counts and FlowCAM analyses. Each CTD full-water cast was alternated with a &amp;quot;trip-on-fly&amp;quot; water cast. The latter casts involved tripping bottles at 24 depths &amp;quot;on the fly&amp;quot; as they passed the following 24 depth targets. These trip-on-fly casts served to provide greater resolution in hydrographic sections across the features.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Evaluation and calibration of CTD conductivity and oxygen sensors&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Salinity:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
For the first 62 stations of RR2004, there was a consistent salinity offset of 0.016 ± 0.033 between conductivity sensors. There was a 0.013 ± 0.006 difference in salinity estimated from the salinometer and conductivity sensor 1, and a -0.004 ± 0.034 difference for conductivity sensor 2. The large standard deviations in the offset for conductivity sensor 2 were due to casts 32 and 33, where the pump for CTD 2 became disconnected. Removing these stations reduces the salinometer/conductivity sensor 2 offset to -0.0005 ± 0.006. Given the high agreement of conductivity sensor 2 with the salinometer, conductivity sensor 1 was replaced for stations 63 through the end of the cruise. After switching out the sensor, the difference between salinities between conductivity sensor 1 and 2 was reduced to 0.004 ± 0.002 (see Figure S1 Supplemental File), with a difference between the salinometer and CTD 1 0.0001 ± 0.0233 and a difference between the salinometer and CTD 2 of -0.0039 ± 0.0233. The difference between CTD 1 and the salinometer and CTD 2 and the salinometer was statistically significant (Student's t-test, t = -49.9, 95% confidence interval: -0.0041 – -0.0038, p &amp;amp;lt; 0.001, 452 degrees of freedom), and so the salinometer measurements are significantly better represented by salinities measured by CTD 1 than CTD 2 for stations 63 onwards.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;To summarize, users of salinities from RR2004 conductivity sensors should consider:&amp;lt;br /&amp;gt;
1) applying a correction factor of ~0.01 to conductivity sensor 1 salinities, at least for stations 32 and 33 where conductivity sensor 2 was not operational;&amp;lt;br /&amp;gt;
2) using salinities from conductivity sensor 2 for stations 1-62, except stations 32 and 33; and&amp;lt;br /&amp;gt;
3) using salinities from conductivity sensor 1 for stations 63 onward.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Oxygen:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Systematically low measurements recorded by CTD oxygen sensor during casts 1 and 2 led to its replacement for the remainder of the cruise. For stations 3 and onward, there was good agreement between the O2 sensor and the oxygen measurements made in the Hydrolab (see Figure S2 Supplemental File), with&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
2 = 1.0079[CTD O2] + 0.0643&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
which has R² &amp;amp;gt; 0.99. For stations 1-2, the calibration is&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
O2 = 1.5205[CTD O2] + 0.9017&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
which has R² = 0.91.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/738117.rdf" xlink:title="OCE-1735664" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1735664 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1735664</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/738122.rdf" xlink:title="OCE-1735783" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1735783 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1735783</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/738128.rdf" xlink:title="OCE-1735846" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1735846 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1735846</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/738130.rdf" xlink:title="OCE-1736375" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1736375 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1736375</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/738132.rdf" xlink:title="OCE-1735436" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1735436 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1735436</gmx:Anchor>
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Cold surface water in the southern Indian Ocean sinks to about 500 meters and travels in the dark for thousands of miles before it resurfaces some 40 years later near the equator in the other ocean basins. This major water mass is named the Sub-Antarctic Mode Water (SAMW). Nutrients it contains when it warms and rises into the sunlit subtropical and tropical waters are estimated to fuel up to 75% of the microscopic plant growth there. Before it sinks, the chemical properties of the SAMW are modified by the growth and distinct physiology of two common phytoplankton; diatoms with shells made of silica, and coccolithophores with carbonate shells. Local physical dynamics influence where and how fast these two phytoplankton classes grow. Consequently, differing nutrient and trace chemical fingerprints are established at the point of SAMW formation. This project is an exceptionally detailed field and modeling effort that will document and quantify the remarkable, interconnected processes that chemically connect two important oceanic ecosystems half a world apart. The scientists leading the project will study the complexity of the biological and chemical conditioning of the SAMW and thus provide critical data about the large-scale oceanic controls of the biological carbon pump that removes atmospheric carbon dioxide to the deep ocean over millennial timescales. Scientific impact from this project will stem from significant peer-reviewed publications and improved predictive models. Societal benefits will develop from training of a range of scholars, including high school, undergraduate, and graduate students, as well as technical and post-doctoral participants. A high school teacher and science communication specialist will go to sea with the project and share experiences from the ship with students on shore via social media and scheduled web interactions.&lt;/p&gt;
&lt;p&gt;To examine how SAMW formation and subduction controls the productivity of global waters well to the north, two January expeditions to the SE Indian Ocean will identify, track, and study the unique mesoscale eddies that serve as discrete water parcels supporting rich populations of either coccolithophores or diatoms plus their associated microbial communities. The eddies will be tracked with Lagrangian Argo drifters and observations will be made of exactly how SAMW is chemically conditioned (i.e. Si, N, P, Fe, and carbonate chemistry) over time scales of months. Using data obtained on the feedback between ecological processes and nutrient, trace metal, and carbonate chemistry in these eddies and on related transect cruises, the project will have three main goals: (1) determine the rates at which SAMW coccolithophores and diatoms condition the carbonate chemistry plus nutrient and trace metal concentrations, as well as assess taxonomic and physiological diversity in the study area with traditional methods plus next-generation sequence DNA/RNA profiling, (2) explore growth limitations by iron, silicate and/or nitrate in controlling algal assemblages and genetic diversity, and (3) combine these findings with the Ekman- and eddy-driven subduction of SAMW to examine biogeochemical impact on a basin scale, using both observations and global numerical models. A meridional survey from 30 to 60 degrees south latitude will be used to characterize the larger-scale variability of carbonate chemistry, nutrient distributions, productivity, genetics and biomass of various plankton groups as SAMW is subducted and proceeds northward.&lt;/p&gt;</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;These data were collected during cruise RR2004 on the R/V Roger Revelle using a Sea-Bird SBE911plus CTD. This cruise departed Honolulu, Hawaii on December 26, 2020 and the ship transited south along the great circle route from Honolulu to 30°S x 150°W, returning to Hawaii on February 23, 2021. CTD casts were performed at 103 stations, encompassing Subtropical, Subantarctic, and Polar waters in the Pacific Sector of the Southern Ocean.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Hydrographic profiles were performed along the transect with the CTD (the &amp;quot;full-water cast&amp;quot;), sampling for Freons, dissolved oxygen, DIC, alkalinity, extracted chlorophyll, nutrients, POC, PIC, biogenic silica, coccolithophore counts and FlowCAM analyses. Each CTD full-water cast was alternated with a &amp;quot;trip-on-fly&amp;quot; water cast. The latter casts involved tripping bottles at 24 depths &amp;quot;on the fly&amp;quot; as they passed the following 24 depth targets. These trip-on-fly casts served to provide greater resolution in hydrographic sections across the features.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Evaluation and calibration of CTD conductivity and oxygen sensors&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Salinity:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
For the first 62 stations of RR2004, there was a consistent salinity offset of 0.016 ± 0.033 between conductivity sensors. There was a 0.013 ± 0.006 difference in salinity estimated from the salinometer and conductivity sensor 1, and a -0.004 ± 0.034 difference for conductivity sensor 2. The large standard deviations in the offset for conductivity sensor 2 were due to casts 32 and 33, where the pump for CTD 2 became disconnected. Removing these stations reduces the salinometer/conductivity sensor 2 offset to -0.0005 ± 0.006. Given the high agreement of conductivity sensor 2 with the salinometer, conductivity sensor 1 was replaced for stations 63 through the end of the cruise. After switching out the sensor, the difference between salinities between conductivity sensor 1 and 2 was reduced to 0.004 ± 0.002 (see Figure S1 Supplemental File), with a difference between the salinometer and CTD 1 0.0001 ± 0.0233 and a difference between the salinometer and CTD 2 of -0.0039 ± 0.0233. The difference between CTD 1 and the salinometer and CTD 2 and the salinometer was statistically significant (Student's t-test, t = -49.9, 95% confidence interval: -0.0041 – -0.0038, p &amp;amp;lt; 0.001, 452 degrees of freedom), and so the salinometer measurements are significantly better represented by salinities measured by CTD 1 than CTD 2 for stations 63 onwards.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;To summarize, users of salinities from RR2004 conductivity sensors should consider:&amp;lt;br /&amp;gt;
1) applying a correction factor of ~0.01 to conductivity sensor 1 salinities, at least for stations 32 and 33 where conductivity sensor 2 was not operational;&amp;lt;br /&amp;gt;
2) using salinities from conductivity sensor 2 for stations 1-62, except stations 32 and 33; and&amp;lt;br /&amp;gt;
3) using salinities from conductivity sensor 1 for stations 63 onward.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Oxygen:&amp;lt;/strong&amp;gt;&amp;lt;br /&amp;gt;
Systematically low measurements recorded by CTD oxygen sensor during casts 1 and 2 led to its replacement for the remainder of the cruise. For stations 3 and onward, there was good agreement between the O2 sensor and the oxygen measurements made in the Hydrolab (see Figure S2 Supplemental File), with&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
2 = 1.0079[CTD O2] + 0.0643&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
which has R² &amp;amp;gt; 0.99. For stations 1-2, the calibration is&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
O2 = 1.5205[CTD O2] + 0.9017&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
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