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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/918545.rdf" xlink:actuate="onRequest">Organic alkalinity data from estuary transects in Coastal Gulf of Maine (Pleasant, Maine; St. John, New Brunswick) in May and October of 2018 and 2019</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Hunt, C. (2024) Organic alkalinity data from estuary transects in Coastal Gulf of Maine (Pleasant, Maine; St. John, New Brunswick) in May and October of 2018 and 2019. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2024-01-25 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.918545.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Dataset Description: &amp;lt;p&amp;gt;This project was a collaboration between Dr. Christopher W. Hunt and Dr. Joseph Salisbury (of the University of New Hampshire) and Dr. Xuewu Liu and Dr. Robert H. Byrne (of the University of South Florida).&amp;lt;/p&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;Sampling was conducted during day trips on Pleasant (Maine, USA) and St. John (New Brunswick, CA) estuaries in May and October 2018 and 2019.&amp;amp;nbsp;&amp;amp;nbsp;&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
* See &amp;quot;Related Datasets&amp;quot; section for access to the related Underway Data described below.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;em&amp;gt;Sample Collection:&amp;lt;/em&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp; Four surveys were conducted of both the Pleasant and St. John estuaries, in May and October 2018, and again in May and October 2019 in order to assess potential differences in estuary conditions between spring and fall seasons. Estuary samples were collected during single-day surveys on small vessels in each system, departing from Addison Maine for Pleasant estuary surveys and from St. John, New Brunswick, for St. John surveys. Estuary water was continuously pumped to an underway measurement system, which recorded location, salinity(Seabird SBE-45), water temperature (Seabird SBE-45), and the partial pressure of carbon dioxide (pCO&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;) among other parameters. Surveys were started on the incoming tide and lasted through high tide and into the ebb tide. At intervals determined from the underway salinity, surface water was captured for discrete sample collection. During the October 2017 and May 2018 surveys a Niskin bottle was lowered overboard by hand; during the later surveys a 10-liter high-density polyethylene (HDPE) carboy was rinsed and filled from the outflow of the underway system, then tightly capped until samples were drawn from a spout at the bottom of the carboy. River endmember samples were collected from above the final downstream dam on each river. For the Pleasant, this dam formed a physical tidal barrier, and the transition from river to estuary was immediate. For the St. John the closest site was in Fredericton New Brunswick, a location over 120 km from the estuary mouth along the river’s course. For both endmember sites, a plastic bucket was lowered from the center of a bridge over the river, rinsed three times with river water, and samples were collected as described above. The temperature and conductivity of samples were measured directly from the bucket with a handheld meter (YSI, Yellow Springs, Ohio).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp; Water from the Niskin or carboy was transferred without bubbling into individual, previously-flushed borosilicate glass BOD bottles: 500 mL for alkalinity and pH&amp;lt;sub&amp;gt;T&amp;lt;/sub&amp;gt;&amp;amp;nbsp;analyses, and 300 mL for inorganic carbon (DIC) analysis. All bottles had greased stoppers and positive closure mechanisms, were filled to leave less than 1% headspace in the bottle, and were preserved with saturated mercuric chloride solution. Samples for silicate and phosphate analysis were filtered using a plastic syringe and 0.2 µm cartridge filter into acid-washed and previously-rinsed 50 mL HDPE vials and preserved with chloroform. Samples for DOC were filtered as was done for the nutrients into acid-washed and previously-rinsed 30 mL HDPE bottles. All samples were immediately placed on ice. Alkalinity, pH, and DIC samples were refrigerated until analysis; nutrient and DOC samples were frozen until analysis.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Instruments:&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Discrete sample salinity was measured with a Guildline Portasal salinometer (Guildline, Smiths Falls Canada). The pHT of samples above pHT 7.0 was measured spectrophotometrically with meta-cresol purple (mCP), using 10 cm pathlength cylindrical glass cells and an Agilent Technologies Cary 8454 UV-Vis spectrometer.&amp;amp;nbsp; The same instrument was used to verify the response slope of a combination glass pH electrode (Metrohm EcoTode Plus). For samples of pHT less than 7.0, and therefore outside the working range of mCP, the initial electrode mV reading and zero-pHT intercept potential (E0) value determined from the AlkGran1 titration were used to calculate the pHT of the untitrated sample. DOC was measured with an uncertainty of 1.5 µmol kg-1 using a Shimadzu high temperature catalytic oxidation analyzer with chemiluminescent detection. Nutrients including phosphate and silicate were analyzed using a SmartChem automated analyzer (Westco Scientific) according to standard colorimetric methods. The resulting measurement uncertainties were 0.8 µmol kg-1 and 0.25 µmol kg-1, respectively (Strickland and Parsons 1972). DIC was measured by acidifying each sample in a custom-built gas extraction system and measuring the evolved CO2 with a Picarro G5131-I cavity ringdown spectrometer (Picarro, Santa Clara CA).&amp;amp;nbsp;&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Alkalinity Titrations&amp;lt;br /&amp;gt;
Total alkalinity and organic alkalinity titrations were conducted using a custom-built apparatus similar to that presented in Cai et al. (1998). This system performed several successive titrations on the same water sample. The total alkalinity was measured by Gran titration (AlkGran1) , followed by the carbonate-free alkalinity that was also measured using the Gran titration approach (AlkGran2), and finally the carbonate-free alkalinity was measured according to an endpoint approach at pHT 4.5 (Alk4.5).&amp;amp;nbsp; Samples were initially titrated from the initial pHT (pHi) to a pHT of 3.5, bubbled with nitrogen, then titrated to pHT 3.0 (AlkGran1).&amp;amp;nbsp; CO2-free NaOH was then added to return the sample to an alkaline pHi.&amp;amp;nbsp; The sample was then titrated to pHT 3.0 (AlkGran2).&amp;amp;nbsp; This process was then repeated, with the final titration ending at pHT 4.5 (Alk4.5).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
NaOH titrations&amp;lt;br /&amp;gt;
We generally followed the methods presented by Cai et al. (1998), Song et al. (2020), and Kerr et al. (2023a) to estimate both organic functional group concentrations (XTi) and corresponding acid dissociation constants (pKai). Briefly, a sample was acidified to pHT 3.0 via Gran titration (AlkGran1), then automatically titrated stepwise under nitrogen with small additions of CO2-free NaOH from pHT 3.0 to pHT 8.5 or 10, resulting in several hundred sequential NaOH additions.&amp;lt;/p&amp;gt;</gco:CharacterString>
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&lt;p&gt;Estuaries are bodies of water formed where rivers meet the ocean, and are important ecosystems that provide protected environments and abundant food for fish and shellfish to reproduce. Many estuary systems are under pressure by changing atmospheric and oceanic conditions, as well as impacts on the rivers that empty into them. Scientists from the University of New Hampshire and the University of South Florida propose that the total alkalinity of some coastal systems, influenced by river runoff, may contain a large fraction of organic acids that have been previously ignored and may play a role in the acid-base chemistry of the estuary. This project would focus on understanding the organic and inorganic acid-base chemistry in estuaries. The project will support a PhD student and several undergraduate students, as well as high school interns from minority communities, broadening participation in the ocean sciences. Also, the monitoring and outreach capacity of a regional wild fishery conservation group will be enhanced, allowing the public to be more fully informed on the effect of ongoing estuarine changes on fisheries.&lt;/p&gt;
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http://lod.bco-dmo.org/id/dataset-parameter/918635.rdf
	Name: T_Alk
	Units: micromoles per kilogram
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http://lod.bco-dmo.org/id/dataset-parameter/918636.rdf
	Name: DIC
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	Name: OrgAlk_from_Endpoint_Titration
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http://lod.bco-dmo.org/id/dataset-parameter/918638.rdf
	Name: OrgAlk_from_Second_Gran_Titration
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http://lod.bco-dmo.org/id/dataset-parameter/918639.rdf
	Name: SiO2
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http://lod.bco-dmo.org/id/dataset-parameter/918640.rdf
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&amp;lt;br /&amp;gt;
* See &amp;quot;Related Datasets&amp;quot; section for access to the related Underway Data described below.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;em&amp;gt;Sample Collection:&amp;lt;/em&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp; Four surveys were conducted of both the Pleasant and St. John estuaries, in May and October 2018, and again in May and October 2019 in order to assess potential differences in estuary conditions between spring and fall seasons. Estuary samples were collected during single-day surveys on small vessels in each system, departing from Addison Maine for Pleasant estuary surveys and from St. John, New Brunswick, for St. John surveys. Estuary water was continuously pumped to an underway measurement system, which recorded location, salinity(Seabird SBE-45), water temperature (Seabird SBE-45), and the partial pressure of carbon dioxide (pCO&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;) among other parameters. Surveys were started on the incoming tide and lasted through high tide and into the ebb tide. At intervals determined from the underway salinity, surface water was captured for discrete sample collection. During the October 2017 and May 2018 surveys a Niskin bottle was lowered overboard by hand; during the later surveys a 10-liter high-density polyethylene (HDPE) carboy was rinsed and filled from the outflow of the underway system, then tightly capped until samples were drawn from a spout at the bottom of the carboy. River endmember samples were collected from above the final downstream dam on each river. For the Pleasant, this dam formed a physical tidal barrier, and the transition from river to estuary was immediate. For the St. John the closest site was in Fredericton New Brunswick, a location over 120 km from the estuary mouth along the river’s course. For both endmember sites, a plastic bucket was lowered from the center of a bridge over the river, rinsed three times with river water, and samples were collected as described above. The temperature and conductivity of samples were measured directly from the bucket with a handheld meter (YSI, Yellow Springs, Ohio).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp; Water from the Niskin or carboy was transferred without bubbling into individual, previously-flushed borosilicate glass BOD bottles: 500 mL for alkalinity and pH&amp;lt;sub&amp;gt;T&amp;lt;/sub&amp;gt;&amp;amp;nbsp;analyses, and 300 mL for inorganic carbon (DIC) analysis. All bottles had greased stoppers and positive closure mechanisms, were filled to leave less than 1% headspace in the bottle, and were preserved with saturated mercuric chloride solution. Samples for silicate and phosphate analysis were filtered using a plastic syringe and 0.2 µm cartridge filter into acid-washed and previously-rinsed 50 mL HDPE vials and preserved with chloroform. Samples for DOC were filtered as was done for the nutrients into acid-washed and previously-rinsed 30 mL HDPE bottles. All samples were immediately placed on ice. Alkalinity, pH, and DIC samples were refrigerated until analysis; nutrient and DOC samples were frozen until analysis.&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Instruments:&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Discrete sample salinity was measured with a Guildline Portasal salinometer (Guildline, Smiths Falls Canada). The pHT of samples above pHT 7.0 was measured spectrophotometrically with meta-cresol purple (mCP), using 10 cm pathlength cylindrical glass cells and an Agilent Technologies Cary 8454 UV-Vis spectrometer.&amp;amp;nbsp; The same instrument was used to verify the response slope of a combination glass pH electrode (Metrohm EcoTode Plus). For samples of pHT less than 7.0, and therefore outside the working range of mCP, the initial electrode mV reading and zero-pHT intercept potential (E0) value determined from the AlkGran1 titration were used to calculate the pHT of the untitrated sample. DOC was measured with an uncertainty of 1.5 µmol kg-1 using a Shimadzu high temperature catalytic oxidation analyzer with chemiluminescent detection. Nutrients including phosphate and silicate were analyzed using a SmartChem automated analyzer (Westco Scientific) according to standard colorimetric methods. The resulting measurement uncertainties were 0.8 µmol kg-1 and 0.25 µmol kg-1, respectively (Strickland and Parsons 1972). DIC was measured by acidifying each sample in a custom-built gas extraction system and measuring the evolved CO2 with a Picarro G5131-I cavity ringdown spectrometer (Picarro, Santa Clara CA).&amp;amp;nbsp;&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
Alkalinity Titrations&amp;lt;br /&amp;gt;
Total alkalinity and organic alkalinity titrations were conducted using a custom-built apparatus similar to that presented in Cai et al. (1998). This system performed several successive titrations on the same water sample. The total alkalinity was measured by Gran titration (AlkGran1) , followed by the carbonate-free alkalinity that was also measured using the Gran titration approach (AlkGran2), and finally the carbonate-free alkalinity was measured according to an endpoint approach at pHT 4.5 (Alk4.5).&amp;amp;nbsp; Samples were initially titrated from the initial pHT (pHi) to a pHT of 3.5, bubbled with nitrogen, then titrated to pHT 3.0 (AlkGran1).&amp;amp;nbsp; CO2-free NaOH was then added to return the sample to an alkaline pHi.&amp;amp;nbsp; The sample was then titrated to pHT 3.0 (AlkGran2).&amp;amp;nbsp; This process was then repeated, with the final titration ending at pHT 4.5 (Alk4.5).&amp;lt;br /&amp;gt;
&amp;lt;br /&amp;gt;
NaOH titrations&amp;lt;br /&amp;gt;
We generally followed the methods presented by Cai et al. (1998), Song et al. (2020), and Kerr et al. (2023a) to estimate both organic functional group concentrations (XTi) and corresponding acid dissociation constants (pKai). Briefly, a sample was acidified to pHT 3.0 via Gran titration (AlkGran1), then automatically titrated stepwise under nitrogen with small additions of CO2-free NaOH from pHT 3.0 to pHT 8.5 or 10, resulting in several hundred sequential NaOH additions.&amp;lt;/p&amp;gt;</gco:CharacterString>
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              <gmd:URL>http://www.bco-dmo.org</gmd:URL>
            </gmd:linkage>
          </gmd:CI_OnlineResource>
        </gmd:onlineResource>
		  <gmd:hoursOfService>
        <gco:CharacterString>Monday - Friday 8:00am - 5:00pm</gco:CharacterString>
      </gmd:hoursOfService>
		  <gmd:contactInstructions>
		    <gco:CharacterString>For questions regarding this resource, please contact BCO-DMO via the email address provided.</gco:CharacterString>
		  </gmd:contactInstructions>
		</gmd:CI_Contact>
  </gmd:contactInfo>
  <gmd:role>
    <gmd:CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="pointOfContact"  codeSpace="007">pointOfContact</gmd:CI_RoleCode>
  </gmd:role>
</gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation>
    <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/654337.rdf" xlink:title="Discrete Analyzer" xlink:actuate="onRequest">SmartChem automated analyzer (Westco Scientific)</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>SmartChem automated analyzer (Westco Scientific)</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: SmartChem automated analyzer (Westco Scientific) Instrument Name: Discrete Analyzer Instrument Short Name:Discrete Analyzer   Instrument Description: Discrete analyzers utilize discrete reaction wells to mix and develop the colorimetric reaction, allowing for a wide variety of assays to be performed from one sample. These instruments are ideal for drinking water, wastewater, soil testing, environmental and university or research applications where multiple assays and high throughput are required.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/413.rdf" xlink:title="Niskin bottle" xlink:actuate="onRequest"></gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString></gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name:  Instrument Name: Niskin bottle Instrument Short Name:Niskin bottle   Instrument Description: A Niskin bottle (a next generation water sampler based on the Nansen bottle) is a cylindrical, non-metallic water collection device with stoppers at both ends. The bottles can be attached individually on a hydrowire or deployed in 12, 24, or 36 bottle Rosette systems mounted on a frame and combined with a CTD. Niskin bottles are used to collect discrete water samples for a range of measurements including pigments, nutrients, plankton, etc. Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0412/</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/674.rdf" xlink:title="pH Sensor" xlink:actuate="onRequest">pH electrode (Metrohm EcoTode Plus)</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>pH electrode (Metrohm EcoTode Plus)</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: pH electrode (Metrohm EcoTode Plus) Instrument Name: pH Sensor Instrument Short Name:pH Sensor   Instrument Description: An instrument that measures the hydrogen ion activity in solutions.

The overall concentration of hydrogen ions is inversely related to its pH.  The pH scale ranges from 0 to 14 and indicates whether acidic (more H+) or basic (less H+). </gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/677.rdf" xlink:title="Salinometer" xlink:actuate="onRequest">Guildline Portasal salinometer (Guildline, Smiths Falls Canada)</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Guildline Portasal salinometer (Guildline, Smiths Falls Canada)</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: Guildline Portasal salinometer (Guildline, Smiths Falls Canada) PI Supplied Instrument Description:Discrete sample salinity was measured with a Guildline Portasal salinometer (Guildline, Smiths Falls Canada).  Instrument Name: Salinometer Instrument Short Name:Salinometer   Instrument Description: A salinometer is a device designed to measure the salinity, or dissolved salt content, of a solution.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/528063.rdf" xlink:title="Sea-Bird SBE 45 MicroTSG Thermosalinograph" xlink:actuate="onRequest"></gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString></gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name:  PI Supplied Instrument Description:. Estuary water was continuously pumped to an underway measurement system, which recorded location, salinity(Seabird SBE-45), water temperature (Seabird SBE-45), and the partial pressure of carbon dioxide (pCO2) among other parameters.  Instrument Name: Sea-Bird SBE 45 MicroTSG Thermosalinograph Instrument Short Name:SBE 45 MicroTSG   Instrument Description: A small externally powered, high-accuracy instrument, designed for shipboard determination of sea surface (pumped-water) conductivity and temperature. It is constructed of plastic and titanium to ensure long life with minimum maintenance. It may optionally be interfaced to an external SBE 38 hull temperature sensor.

Sea Bird SBE 45 MicroTSG (Thermosalinograph) Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0190/</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/527277.rdf" xlink:title="Shimadzu TOC-L Analyzer" xlink:actuate="onRequest">Shimadzu high temperature catalytic oxidation analyzer with chemiluminescent detection</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Shimadzu high temperature catalytic oxidation analyzer with chemiluminescent detection</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: Shimadzu high temperature catalytic oxidation analyzer with chemiluminescent detection PI Supplied Instrument Description:DOC was measured with an uncertainty of 1.5 µmol kg-1 using a Shimadzu high temperature catalytic oxidation analyzer with chemiluminescent detection. Instrument Name: Shimadzu TOC-L Analyzer Instrument Short Name:Shimadzu TOC-L   Instrument Description: A Shimadzu TOC-L Analyzer measures DOC by high temperature combustion method.

Developed by Shimadzu, the 680 degree C combustion catalytic oxidation method is now used worldwide. One of its most important features is the capacity to efficiently oxidize hard-to-decompose organic compounds, including insoluble and macromolecular organic compounds. The 680 degree C combustion catalytic oxidation method has been adopted for the TOC-L series.

http://www.shimadzu.com/an/toc/lab/toc-l2.html Community Standard Description: http://onto.nerc.ac.uk/CAST/124.html</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/667.rdf" xlink:title="Spectrometer" xlink:actuate="onRequest">Picarro G5131-I cavity ringdown spectrometer (Picarro, Santa Clara CA)</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Picarro G5131-I cavity ringdown spectrometer (Picarro, Santa Clara CA)</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: Picarro G5131-I cavity ringdown spectrometer (Picarro, Santa Clara CA) Instrument Name: Spectrometer Instrument Short Name:Spectrometer   Instrument Description: A spectrometer is an optical instrument used to measure properties of light over a specific portion of the electromagnetic spectrum. Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0460/</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/667.rdf" xlink:title="Spectrometer" xlink:actuate="onRequest">Agilent Technologies Cary 8454 UV-Vis spectrometer</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Agilent Technologies Cary 8454 UV-Vis spectrometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: Agilent Technologies Cary 8454 UV-Vis spectrometer Instrument Name: Spectrometer Instrument Short Name:Spectrometer   Instrument Description: A spectrometer is an optical instrument used to measure properties of light over a specific portion of the electromagnetic spectrum. Community Standard Description: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0460/</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument>
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/instrument/470.rdf" xlink:title="Thermosalinograph" xlink:actuate="onRequest">handheld meter (YSI, Yellow Springs, Ohio).</gmx:Anchor>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>handheld meter (YSI, Yellow Springs, Ohio).</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>PI Supplied Instrument Name: handheld meter (YSI, Yellow Springs, Ohio). Instrument Name: Thermosalinograph Instrument Short Name:TSG   Instrument Description: A thermosalinograph (TSG) is used to obtain a continuous record of sea surface temperature and salinity.  On many research vessels the TSG is integrated into the ship's underway seawater sampling system and reported with the underway or alongtrack data. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/133/</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>
