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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/949729.rdf" xlink:actuate="onRequest">Houston Galveston Bay pCO2 from the Hurricane Harvey Texas Lagoons project</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Hu, X., Dias, L. M., Liu, H. (2025) Houston Galveston Bay pCO2. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2025-01-27 [if applicable, indicate subset used]. http://lod.bco-dmo.org/id/dataset/949729 [access date]</gco:CharacterString>
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        <gco:CharacterString>Dataset Description: &amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;File naming convention notes:&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;1.&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp; Calibration&amp;amp;nbsp;files:&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;See the &amp;quot;Supplemental Files&amp;quot; section of this dataset to access calibration files.&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;Standard calibrations title format: “standardMMDDYYYY_pCO2_notes_mmddhhhh.txt”, where MMDDYYYY is the month, date, and year of sample collection, and mmddhhhh is the month, date, and hour of data processing in local time.&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;Pre-sampling calibrations title format: “precalibrationMMDDYYYY_pCO2_notes_mmddhhhh.txt”, where MMDDYYYY is the month, date, and year of sample collection, and mmddhhhh is the month, date, and hour of data processing in local time.&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;Post-sampling calibrations title format: “postcalibrationMMDDYYYY_pCO2_notes_mmddhhhh.txt”, where MMDDYYYY is the month, date, and year of sample collection, and mmddhhhh is the month, date, and hour of data processing in local time.&amp;lt;/li&amp;gt;
&amp;lt;/ul&amp;gt;

&amp;lt;p&amp;gt;2.&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp; In situ notes files:&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;See the &amp;quot;Supplemental Files&amp;quot; section of this dataset to access notes files.&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;“GB_pCO2_MMDDYYYY_pCO2_notes_mmddhhhh.txt”, where MMDDYYYY is the month, date, and year of sample collection and mmddhhhh is the month, date, and hour of notes.&amp;amp;nbsp;&amp;lt;/li&amp;gt;
&amp;lt;/ul&amp;gt;

&amp;lt;p&amp;gt;3.&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp;&amp;amp;nbsp; Data files&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The original files (.txts)&amp;amp;nbsp;have been merged into one file, which is the primary data file of this dataset (949729_v1_houston_galveston_bay_pco2). The original filenames can be found in the Source_File column of this primary data file.&amp;amp;nbsp;&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;GB_pCO2_MMDDYYYY_pCO2_mmddhhhh.txt”, where MMDDYYYY is the month, date, and year of sample collection and mmddhhhh is the month, date, and hour of data processing.&amp;lt;/li&amp;gt;
&amp;lt;/ul&amp;gt; Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Field Sampling&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Galveston Bay is a semi-enclosed microtidal estuary located in the northwestern Gulf of Mexico (nwGOM) (Montagna, Palmer, &amp;amp;amp; Pollack, 2013). With an average water depth of 3 m and a surface area of 1554 km², Galveston Bay is the seventh largest estuary in the U.S. and the second largest estuary on the Texas coast (Bass, Torres, Irza, Proft, Sebastian, Dawson, Bedient, 2018; Morse et al., 1993; Solis &amp;amp;amp; Powell, 1999). Galveston Bay receives freshwater from the Trinity River, San Jacinto River, Clear Creek, and smaller bayous and creeks, with the Trinity River providing 70% of the freshwater entering the Bay (Bass et al., 2018; Morse et al., 1993; Solis &amp;amp;amp; Powell, 1999). The Bolivar Peninsula and Galveston Island separate Galveston Bay from the Gulf of Mexico (GOM), with exchange of water between the Bay and the GOM occurring through Bolivar Roads, the mouth of the Bay (Glass, Rooker, Kraus, &amp;amp;amp; Holt, 2008).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Monthly cruises were conducted between October 2017 and September 2018 aboard the R/V &amp;lt;em&amp;gt;Trident&amp;lt;/em&amp;gt;. The timing of the study allowed for examination of the factors regulating CO2 flux over the course of a year following Hurricane Harvey in late August 2017. Although the study began more than 45 days after the hurricane (the residence time of the Bay), salinity recovery of the Bay was likely still ongoing in the inner and middle sections (Du &amp;amp;amp; Park, 2019; Du, Park, Dellapenna, &amp;amp;amp; Clay, 2019).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;During each monthly survey, a transect was run between five water sampling stations, extending northwest from the Bay mouth (Station 1) to the Five Mile Marker on the Houston Ship Channel (Station 5). One offshore cruise in the nwGOM outside Galveston Bay was conducted in October 2018. Underway pCO2 measurements were taken along a northwesterly transect from stations 1 through 5. A SUPER-CO2 System equipped with a LI-COR® LI-840A infrared gas analyzer was used to collect both water and air xCO2 after drying through a Peltier thermoelectric device. The xCO2 data, after removing residual water vapor (Honkanen et al., 2021), was converted to pCO2 at sea surface temperature assuming 100% water vapor pressure (Jiang et al., 2008). Underway seawater was taken from a steel pipe attached to the side of the research vessel, as it did not have a dedicated water intake system, and a diaphragm water pump was used to feed water to the equilibrator. In situ sea surface temperature (SST) and salinity were measured with a SeaBird Scientific SBE45® Thermosalinograph mounted parallel to the equilibrator of the SUPER-CO2 System. Prior to and following each sampling trip, the SUPER-CO2 System was calibrated using standards of known CO2 concentrations (273.3, 774.3, and 1468.7 ppm).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;To calculate the pCO2 of seawater and air from measurements, the measured mole fraction of CO2 in seawater (xCO2, water) and measured equilibrator barometric pressure and xH2O were first used to calculate xCO2 in dry air (xCO2, air). This xCO2, air was then converted to pCO2 of equilibration (pCO2, eq) using measured temperature of equilibration (Teq) and water vapor pressure of equilibration, which was calculated from salinity and Teq according to methods outlined in Weiss and Price (1980). Next, SST and Teq were used to convert pCO2, eq to pCO2, water (Weiss &amp;amp;amp; Price, 1980). For pCO2, air, xCO2, air was converted to pCO2, air using water vapor pressure at SST and salinity, assuming 100% humidity (Borges et al., 2004).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Meteorological Data&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Three National Oceanic and Atmospheric Administration (NOAA) buoys from throughout Galveston Bay provided six-minute interval averages of continuous wind speed data (NOAA, 2022). The average wind speed for all three buoys during sampling times was calculated and applied to the timing of sampling in Galveston Bay. Prior to calculations, wind speeds were converted to a height of 10 m (u10) using the wind profile power law (Hsu, Meindl, &amp;amp;amp; Gilhousen, 1994):&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;u1/u2 = (z1/z2)^P&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;where u2 is wind speed at height z2 = 10 m, u1 is the collected wind speed data at height z1, and the exponent P (0.11) around the GOM area is extracted by Hsu et al. (1994).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;United States Geological Survey (USGS) streamgages for the Trinity River (gage #08066500) and San Jacinto River, east fork (SJE; gage #08070200) and west fork (SJW; gage #08068000), were used to obtain freshwater discharge (USGS, 2021). These stations were identified as the closest gages to the mouths of the rivers having complete discharge data for the period of study. Discharges of less than or equal to 45 days (residence time of the Bay) prior to flux estimates were utilized (Bass et al., 2018; Morse et al., 1993). The Texas Commission on Environmental Quality (TCEQ) performs routine water quality monitoring, and TCEQ water sampling stations were used for river endmember values from the San Jacinto (average of west fork station #11243 and east fork station #11238) and Trinity (station #10896) rivers (TCEQ, 2022). River endmember DIC was calculated from TA and pH measurements using K1 and K2 constants from Millero (1980), and pH values on the NBS scale. Seasonally weighted averages were calculated by summing the TA or DIC concentration multiplied by daily discharge values for all river measurements of that season and dividing by the sum of all discharge values for all river measurements of that season (using meteorological seasons).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Historical Data&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Results from this study were compared to historical data for Galveston Bay obtained from the Surface Ocean CO2 Atlas (SOCAT) database, which provided fCO2, water and xCO2, air values, along with surface seawater salinity, temperature, and depth, with observations from 2006 and 2010 through 2016, primarily during the month of September (Bakker et al., 2016). SOCAT transects followed a similar route to our study transect, beginning near Station 4 and continuing outward into the GOM, with a side transect through the Galveston Channel, which separates Pelican Island from Galveston Island. fCO2 values were converted to pCO2 using the R package &amp;lt;em&amp;gt;seacarb&amp;lt;/em&amp;gt; (Gattuso et al., 2022). SOCAT data were analyzed independently from the results of this study. As done previously with ship data, SOCAT xCO2, air was converted to pCO2, air by accounting for water vapor pressure based on SST and SSS, assuming 100% humidity (Borges et al., 2004).&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/783255.rdf" xlink:title="OCE-1760006" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1760006 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1760006</gmx:Anchor>
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              <gmd:description>
                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Field Sampling&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Galveston Bay is a semi-enclosed microtidal estuary located in the northwestern Gulf of Mexico (nwGOM) (Montagna, Palmer, &amp;amp;amp; Pollack, 2013). With an average water depth of 3 m and a surface area of 1554 km², Galveston Bay is the seventh largest estuary in the U.S. and the second largest estuary on the Texas coast (Bass, Torres, Irza, Proft, Sebastian, Dawson, Bedient, 2018; Morse et al., 1993; Solis &amp;amp;amp; Powell, 1999). Galveston Bay receives freshwater from the Trinity River, San Jacinto River, Clear Creek, and smaller bayous and creeks, with the Trinity River providing 70% of the freshwater entering the Bay (Bass et al., 2018; Morse et al., 1993; Solis &amp;amp;amp; Powell, 1999). The Bolivar Peninsula and Galveston Island separate Galveston Bay from the Gulf of Mexico (GOM), with exchange of water between the Bay and the GOM occurring through Bolivar Roads, the mouth of the Bay (Glass, Rooker, Kraus, &amp;amp;amp; Holt, 2008).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Monthly cruises were conducted between October 2017 and September 2018 aboard the R/V &amp;lt;em&amp;gt;Trident&amp;lt;/em&amp;gt;. The timing of the study allowed for examination of the factors regulating CO2 flux over the course of a year following Hurricane Harvey in late August 2017. Although the study began more than 45 days after the hurricane (the residence time of the Bay), salinity recovery of the Bay was likely still ongoing in the inner and middle sections (Du &amp;amp;amp; Park, 2019; Du, Park, Dellapenna, &amp;amp;amp; Clay, 2019).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;During each monthly survey, a transect was run between five water sampling stations, extending northwest from the Bay mouth (Station 1) to the Five Mile Marker on the Houston Ship Channel (Station 5). One offshore cruise in the nwGOM outside Galveston Bay was conducted in October 2018. Underway pCO2 measurements were taken along a northwesterly transect from stations 1 through 5. A SUPER-CO2 System equipped with a LI-COR® LI-840A infrared gas analyzer was used to collect both water and air xCO2 after drying through a Peltier thermoelectric device. The xCO2 data, after removing residual water vapor (Honkanen et al., 2021), was converted to pCO2 at sea surface temperature assuming 100% water vapor pressure (Jiang et al., 2008). Underway seawater was taken from a steel pipe attached to the side of the research vessel, as it did not have a dedicated water intake system, and a diaphragm water pump was used to feed water to the equilibrator. In situ sea surface temperature (SST) and salinity were measured with a SeaBird Scientific SBE45® Thermosalinograph mounted parallel to the equilibrator of the SUPER-CO2 System. Prior to and following each sampling trip, the SUPER-CO2 System was calibrated using standards of known CO2 concentrations (273.3, 774.3, and 1468.7 ppm).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;To calculate the pCO2 of seawater and air from measurements, the measured mole fraction of CO2 in seawater (xCO2, water) and measured equilibrator barometric pressure and xH2O were first used to calculate xCO2 in dry air (xCO2, air). This xCO2, air was then converted to pCO2 of equilibration (pCO2, eq) using measured temperature of equilibration (Teq) and water vapor pressure of equilibration, which was calculated from salinity and Teq according to methods outlined in Weiss and Price (1980). Next, SST and Teq were used to convert pCO2, eq to pCO2, water (Weiss &amp;amp;amp; Price, 1980). For pCO2, air, xCO2, air was converted to pCO2, air using water vapor pressure at SST and salinity, assuming 100% humidity (Borges et al., 2004).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Meteorological Data&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Three National Oceanic and Atmospheric Administration (NOAA) buoys from throughout Galveston Bay provided six-minute interval averages of continuous wind speed data (NOAA, 2022). The average wind speed for all three buoys during sampling times was calculated and applied to the timing of sampling in Galveston Bay. Prior to calculations, wind speeds were converted to a height of 10 m (u10) using the wind profile power law (Hsu, Meindl, &amp;amp;amp; Gilhousen, 1994):&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;u1/u2 = (z1/z2)^P&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;where u2 is wind speed at height z2 = 10 m, u1 is the collected wind speed data at height z1, and the exponent P (0.11) around the GOM area is extracted by Hsu et al. (1994).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;United States Geological Survey (USGS) streamgages for the Trinity River (gage #08066500) and San Jacinto River, east fork (SJE; gage #08070200) and west fork (SJW; gage #08068000), were used to obtain freshwater discharge (USGS, 2021). These stations were identified as the closest gages to the mouths of the rivers having complete discharge data for the period of study. Discharges of less than or equal to 45 days (residence time of the Bay) prior to flux estimates were utilized (Bass et al., 2018; Morse et al., 1993). The Texas Commission on Environmental Quality (TCEQ) performs routine water quality monitoring, and TCEQ water sampling stations were used for river endmember values from the San Jacinto (average of west fork station #11243 and east fork station #11238) and Trinity (station #10896) rivers (TCEQ, 2022). River endmember DIC was calculated from TA and pH measurements using K1 and K2 constants from Millero (1980), and pH values on the NBS scale. Seasonally weighted averages were calculated by summing the TA or DIC concentration multiplied by daily discharge values for all river measurements of that season and dividing by the sum of all discharge values for all river measurements of that season (using meteorological seasons).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Historical Data&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Results from this study were compared to historical data for Galveston Bay obtained from the Surface Ocean CO2 Atlas (SOCAT) database, which provided fCO2, water and xCO2, air values, along with surface seawater salinity, temperature, and depth, with observations from 2006 and 2010 through 2016, primarily during the month of September (Bakker et al., 2016). SOCAT transects followed a similar route to our study transect, beginning near Station 4 and continuing outward into the GOM, with a side transect through the Galveston Channel, which separates Pelican Island from Galveston Island. fCO2 values were converted to pCO2 using the R package &amp;lt;em&amp;gt;seacarb&amp;lt;/em&amp;gt; (Gattuso et al., 2022). SOCAT data were analyzed independently from the results of this study. As done previously with ship data, SOCAT xCO2, air was converted to pCO2, air by accounting for water vapor pressure based on SST and SSS, assuming 100% humidity (Borges et al., 2004).&amp;lt;/p&amp;gt;</gco:CharacterString>
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                <gco:CharacterString>&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Air-water CO2 Flux Calculation&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Prior to calculating CO2 flux based on in situ measurements, outliers were identified graphically and removed from the final datasets. Air-water CO2 flux was calculated using the following equation:&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;F = k * K0 * (pCO2,water - pCO2,air)&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Where:&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;k (m d-1) is the gas transfer velocity calculated from wind speed,&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;K0 (mol m-3 atm-1) is the gas solubility at the measured in situ temperature and salinity.&amp;lt;/li&amp;gt;
&amp;lt;/ul&amp;gt;

&amp;lt;p&amp;gt;Gas transfer velocity (piston velocity) at a Schmidt number of 600, referenced to wind speed at 10 m above the sea surface, was calculated and compared for consistency using several methods. Ultimately, the equation from Jiang et al. (2008), which was designed for estuaries and allows for wind speeds up to 12 m/s, was chosen as the most appropriate for calculating gas transfer velocity within the study area:&amp;lt;/p&amp;gt;

&amp;lt;p class=&amp;quot;rtecenter&amp;quot;&amp;gt;k = (0.314 * u10² - 0.436 * u10 + 3.990) * (ScSST/600)^(-0.5)&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Where:&amp;lt;/p&amp;gt;

&amp;lt;ul&amp;gt;
&amp;lt;li&amp;gt;u10 is the wind speed at 10 m above the water surface (m/s),&amp;lt;/li&amp;gt;
&amp;lt;li&amp;gt;ScSST is the Schmidt number of CO2 at in situ temperature, calculated for seawater.&amp;lt;/li&amp;gt;
&amp;lt;/ul&amp;gt;

&amp;lt;p&amp;gt;To assess the best calculation method, air-sea CO2 flux, sea surface pCO2, temperature, salinity, wind speed, and atmospheric pressure were averaged over 0.01° and 0.025° latitude increments, and values were used to calculate flux in two separate analyses. A two-tailed Student’s t-test showed that CO2 flux calculations did not significantly differ between the two groupings for any of the sampling months (p ≥ 0.50 for all months). For all further analyses, CO2 flux was calculated based on the larger 0.025° latitude increments to simplify calculations.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Linear interpolation between adjacent months was used to estimate CO2 flux, salinity, temperature, pCO2, air, and pCO2, water during months where values were missing for some of the latitudinal increments. Missing values for monthly atmospheric pCO2 were also calculated using linear interpolation. Seasonal values were determined by averaging monthly CO2 flux estimates by season, with fall including September, October, and November; winter including December, January, and February; spring including March, April, and May; and summer including June, July, and August measurements.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Resulting pCO2, water and sea surface salinity (SSS) from underway measurements were compared to pCO2, water calculated from pH and DIC measured from discrete samples and SSS from discrete samples. Since pCO2 is strongly influenced by temperature, thermally-adjusted water pCO2 was calculated according to the equation from Takahashi [79] to assess changes in pCO2 due to factors other than temperature (e.g., photosynthesis, respiration).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Statistical Analyses&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Galveston Bay, located adjacent to the urban Houston and Galveston metroplex, may experience high localized atmospheric CO2 levels due to local emissions, which could depend on wind speed and direction. To determine the influence of wind speed (u10) and direction on pCO2, air, Pearson’s correlation coefficients with p-values were calculated for each variable and pCO2, air. Predictor variables with a Pearson’s correlation p-value &amp;amp;lt;0.05 and an absolute correlation coefficient value &amp;amp;gt;0.7 were designated as significantly correlated to pCO2, air.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Due to non-normality of data and non-homogeneity of variances, Kruskal-Wallis nonparametric Analysis of Variance (ANOVA) tests were performed in R to compare carbonate system parameters (DIC, TA, pH, and ΩAr) across seasons and stations. Further exploration of values was conducted using Dunn tests, which assess individual differences between each pair of groups when nonparametric data are used.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;To fully assess the influences of biogeochemistry on pCO2, several multiple linear regression models were compared based on residuals, R² values, and significance. Initial potential predictor variables for the discrepancy in pCO2 between calculated and underway measured values (calculated – measured, or dpCO2) included the difference in salinity between discrete and measured values, discrete salinity measurements, SST, DIC, TA, ΩAr, and pHT. All but salinity difference and SST remained in the final chosen model.&amp;lt;/p&amp;gt;</gco:CharacterString>
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                  <gco:CharacterString>- Merged all of the raw pCO2 data (txt) files into one CSV file, which is the primary data file for this dataset. 
- Added a datetime column to the primary datafile from the Date and Time columns in the primary data file. This new column is called ISO_DateTime_UTC.
- All of the related callibration and note files for this dataset are served as supplemental files. 
- Special characters were removed from the column names within the primary data file.
- Column &amp;quot;820pwrV&amp;quot; renamed to &amp;quot;Voltage_output_820pwrV.&amp;quot;</gco:CharacterString>
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