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            <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/dataset/957165.rdf" xlink:actuate="onRequest">Vanadium concentrations and isotope compositions of seawater samples collected from the South Atlantic Ocean (2010 UK GEOTRACES cruise GA10/D357 Leg 1) and the Black Sea (2013 MedBlack GEOTRACES cruise leg 2, 64PE373, R/V Pelagia)</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Li, S., Owens, J. D., Nielsen, S. G. (2025) Vanadium concentrations and isotope compositions of seawater samples collected from the South Atlantic Ocean (2010 UK GEOTRACES cruise GA10/D357 Leg 1) and the Black Sea (2013 MedBlack GEOTRACES cruise leg 2, 64PE373, R/V Pelagia). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2025-04-01 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.957165.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>Seawater profiles of vanadium concentrations and isotope compositions Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Collection protocols for the South Atlantic Ocean seawater samples (Owens et al., 2017):&amp;lt;/strong&amp;gt; a &amp;quot;trace metal-clean&amp;quot; titanium rosette with a PTFE-coated CTD system was used and deployed using a plasma rope to collect the seawater samples. Seawater samples were filtered through 0.2-micrometer (μm) filter capsules and transferred into 1-liter (L) HDPE bottles in a trace metal clean container. Then seawater samples were acidified at WHOI (Woods Hole Oceanographic Institution) to pH ~2 using concentrated distilled HCl.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Collection protocols for the Black Sea seawater samples (Cruise Report 64PE373 on RV Pelagia):&amp;lt;/strong&amp;gt; an ultra-clean titanium CTD system was deployed to collect the seawater samples. The collected seawater was filtered with 0.2 μm Sartobran 300 filter cartridges (Sartorius) and acidified on board to pH ~2 with Baseline grade Seastar HCl. (See: &amp;lt;a href=&amp;quot;https://www.geotraces.org/ga04-2/&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;https://www.geotraces.org/ga04-2/&amp;lt;/a&amp;gt;)&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Here we describe the general protocols for chemical procedures.&amp;lt;/strong&amp;gt; The in-lab column chromatography procedures to pre-concentrate and purify seawater vanadium (V) for concentration and isotope composition measurement are described in detail in Li et al. (under review). The chemical reagents utilized were trace-metal clean.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;For seawater V concentration measurement, the column chromatography utilizing Bio-rad AG 50W-X12 cation resin was used to pre-concentrate V (Li et al., under review). The acidified seawater samples (pH ~2) were doped with H2O2 solution to contain 2% H2O2 before being loaded onto the resin column. Vanadium was yielded with weakly acidic H2O2 solution (0.01 M HCl + 2% H2O2) with the matrix metal elements being retained on the resin.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;For seawater V isotope composition measurement, a four-column chromatography (Wu et al., 2019) was used to pre-concentrate and purify seawater V. Details of further improvements on this column chromatography method have been described in Li et al. (under review). The pre-cleaned Hitachi Nobias Chelate PA-1 resin and Bio-rad AG1-X8 anion resin were utilized to pre-concentrate and purify seawater V. The first column utilized Nobias Chelate PA-1 resin. Seawater samples were buffered to pH at 6.0 ± 0.1 with acetic acid and ammonia solutions before being loaded onto the column. Then V was yielded with 3 M HNO3. The following three columns utilized Bio-rad AG1-X8 anion resin to further purify seawater V, and the yielded V from the previous column was redissolved in 0.01 M HCl + 2% H2O2 solution before being loaded onto the column. Then, clean the resin column after the complete dripping of the sample solution using 0.01M HCl + 2% H2O2. Finally, V was yielded with 6M HCl and 2M HNO3.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The artificial seawater standards SW Matrix-AA and SW Matrix-BDH were made as in-lab standards for isotope composition measurement. The matrix elutes of two seawater samples were yielded after the first Nobias resin column and were separately doped with pure V solution standards, ~900 nanograms (ng) AA-V (SW Matrix-AA) and ~900 ng BDH V (SW Matrix-BDH). The two artificial seawater standards were processed parallelly with seawater samples with the same chemical procedures.&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/775700.rdf" xlink:title="OCE-1434785" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1434785 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1434785</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/775707.rdf" xlink:title="OCE-1624895" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-1624895 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=1624895</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/957169.rdf" xlink:title="Exobiology Grant NNX16AJ60G" xlink:actuate="onRequest">Funding provided by National Aeronautics &amp; Space Administration (NASA) Award Number: Exobiology Grant NNX16AJ60G</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/957171.rdf" xlink:title="FG-2020-13552" xlink:actuate="onRequest">Funding provided by Alfred P. Sloan Foundation (Sloan) Award Number: FG-2020-13552</gmx:Anchor>
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	Name: Cruise_ID
	Units: unitless
	Description: &lt;p&gt;Cruise identifier&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957208.rdf
	Name: Location
	Units: unitless
	Description: &lt;p&gt;Location description&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957209.rdf
	Name: Station
	Units: unitless
	Description: &lt;p&gt;Station number&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957210.rdf
	Name: Sample_ID
	Units: unitless
	Description: &lt;p&gt;Sample ID number. The &amp;quot;dup&amp;quot; and the number in the bracket indicate the re-dilution and remeasurement of the same solution.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957211.rdf
	Name: Longitude
	Units: degrees East
	Description: &lt;p&gt;Longitude of collection location&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957212.rdf
	Name: Latitude
	Units: degrees North
	Description: &lt;p&gt;Latitude of collection location; negative values = South&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957213.rdf
	Name: Date
	Units: unitless
	Description: &lt;p&gt;Year and month of sample collection&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957214.rdf
	Name: Depth
	Units: meters (m)
	Description: &lt;p&gt;Depth below the sea surface&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957215.rdf
	Name: Salinity
	Units: PSU
	Description: &lt;p&gt;Salinity (The salinity data are from Conway et al. (2016) and Horner et al. (2015).)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957216.rdf
	Name: Seawater_V_ng_g
	Units: nanograms per gram (ng/g)
	Description: &lt;p&gt;Seawater vanadium concentration in ng/g&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957217.rdf
	Name: Seawater_V_nmol_kg
	Units: nanomoles per kilogram (nmol/kg)
	Description: &lt;p&gt;Seawater vanadium concentration in nmol/kg. The seawater V concentration is averaged with duplicate measurements. The uncertainty 1RSD is calculated with duplicate measurements, otherwise the instrumental measurement precision with 1RSD better than 5% is assigned.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957218.rdf
	Name: one_RSD
	Units: percent (%)
	Description: &lt;p&gt;One relative standard deviation&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957219.rdf
	Name: Seawater_V_normalized_nmol_kg
	Units: nanomoles per kilogram (nmol/kg)
	Description: &lt;p&gt;The seawater V concentration is normalized to salinity = 35‰.&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957220.rdf
	Name: Yielded_V
	Units: nanograms per gram
	Description: &lt;p&gt;Yielded vanadium after column chromatography&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957221.rdf
	Name: Yielding_rate
	Units: percent (%)
	Description: &lt;p&gt;Yielding rate&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957222.rdf
	Name: d51V
	Units: per mil (‰)
	Description: &lt;p&gt;delta 51V; Vanadium isotope composition&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957223.rdf
	Name: two_SD
	Units: per mil (‰)
	Description: &lt;p&gt;Two standard deviations&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/957224.rdf
	Name: number_duplicates
	Units: unitless
	Description: &lt;p&gt;Number of duplicate measurements&lt;/p&gt; 
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&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Collection protocols for the Black Sea seawater samples (Cruise Report 64PE373 on RV Pelagia):&amp;lt;/strong&amp;gt; an ultra-clean titanium CTD system was deployed to collect the seawater samples. The collected seawater was filtered with 0.2 μm Sartobran 300 filter cartridges (Sartorius) and acidified on board to pH ~2 with Baseline grade Seastar HCl. (See: &amp;lt;a href=&amp;quot;https://www.geotraces.org/ga04-2/&amp;quot; target=&amp;quot;_blank&amp;quot;&amp;gt;https://www.geotraces.org/ga04-2/&amp;lt;/a&amp;gt;)&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Here we describe the general protocols for chemical procedures.&amp;lt;/strong&amp;gt; The in-lab column chromatography procedures to pre-concentrate and purify seawater vanadium (V) for concentration and isotope composition measurement are described in detail in Li et al. (under review). The chemical reagents utilized were trace-metal clean.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;For seawater V concentration measurement, the column chromatography utilizing Bio-rad AG 50W-X12 cation resin was used to pre-concentrate V (Li et al., under review). The acidified seawater samples (pH ~2) were doped with H2O2 solution to contain 2% H2O2 before being loaded onto the resin column. Vanadium was yielded with weakly acidic H2O2 solution (0.01 M HCl + 2% H2O2) with the matrix metal elements being retained on the resin.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;For seawater V isotope composition measurement, a four-column chromatography (Wu et al., 2019) was used to pre-concentrate and purify seawater V. Details of further improvements on this column chromatography method have been described in Li et al. (under review). The pre-cleaned Hitachi Nobias Chelate PA-1 resin and Bio-rad AG1-X8 anion resin were utilized to pre-concentrate and purify seawater V. The first column utilized Nobias Chelate PA-1 resin. Seawater samples were buffered to pH at 6.0 ± 0.1 with acetic acid and ammonia solutions before being loaded onto the column. Then V was yielded with 3 M HNO3. The following three columns utilized Bio-rad AG1-X8 anion resin to further purify seawater V, and the yielded V from the previous column was redissolved in 0.01 M HCl + 2% H2O2 solution before being loaded onto the column. Then, clean the resin column after the complete dripping of the sample solution using 0.01M HCl + 2% H2O2. Finally, V was yielded with 6M HCl and 2M HNO3.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;The artificial seawater standards SW Matrix-AA and SW Matrix-BDH were made as in-lab standards for isotope composition measurement. The matrix elutes of two seawater samples were yielded after the first Nobias resin column and were separately doped with pure V solution standards, ~900 nanograms (ng) AA-V (SW Matrix-AA) and ~900 ng BDH V (SW Matrix-BDH). The two artificial seawater standards were processed parallelly with seawater samples with the same chemical procedures.&amp;lt;/p&amp;gt;</gco:CharacterString>
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                  <gco:CharacterString>- Imported original file &amp;quot;Seawater vanadium concentrations and isotope compositions_Update.xlsx&amp;quot; into the BCO-DMO system.
- Flagged &amp;quot;N/A&amp;quot; as a missing data value (missing data are empty/blank in the final CSV file).
- Renamed fields to comply with BCO-DMo naming conventions.
- Made the south latitude values negative.
- Saved the final file as &amp;quot;957165_v1_vanadium_concentrations_and_isotope_compositions.csv&amp;quot;.
- Saved the &amp;quot;NASS-6 V concentration&amp;quot; sheet as a PDF and attached as a Supplemental File.
- Saved the &amp;quot;Seawater standards&amp;quot; sheet as a PDF and attached as a Supplemental File.</gco:CharacterString>
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            <gco:CharacterString>PI Supplied Instrument Name: Agilent 7500ce Inductively Coupled Plasma Mass Spectrometry (ICP-MS) PI Supplied Instrument Description:The vanadium concentrations were measured with the Agilent 7500ce Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Thermo Element 2 ICP‑MS. Instrument Name: Agilent 7500ce inductively coupled plasma mass spectrometer Instrument Short Name:Agilent 7500ce ICP-MS   Instrument Description: The Agilent 7500ce is a laboratory benchtop inductively coupled plasma mass spectrometer (ICP-MS) for metal analysis. The instrument comprises a sample introduction system (micromist glass concentric nebuliser, quartz Scott-type spray chamber, peristaltic pump), an interface of nickel cones and dual on-axis extraction lenses, a vacuum system, mass flow controllers (plasma, auxiliary, makeup, and carrier gas and two Octopole Reaction System (ORS) reaction gas lines), a shieldtorch system (STS), an all-solid state digitally-driven 27 MHz RF generator and an off-axis Omega lens. The octopole cell of the ORS can be used with no gas, operated in collision mode using pure He cell gas or used in H2 reaction mode for ultra-trace Se analysis and semiconductor applications. All three of these modes come as standard in the 7500ce model. The instrument has been discontinued.</gco:CharacterString>
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This term applies to profiling CTDs. For fixed CTDs, see https://www.bco-dmo.org/instrument/869934. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/130/</gco:CharacterString>
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            <gco:CharacterString>PI Supplied Instrument Name: Neptune Multi-collector-ICP-MS PI Supplied Instrument Description:The vanadium isotope compositions were measured with the Neptune Multi-collector-ICP-MS. Instrument Name: Thermo Finnigan Neptune inductively coupled plasma mass spectrometer Instrument Short Name:Neptune ICP-MS   Instrument Description: A laboratory high mass resolution inductively coupled plasma mass spectrometer (ICP-MS) designed for elemental and isotopic analysis. The instrument is based on a multicollector platform, comprising eight moveable collector supports and one fixed center channel equipped with a Faraday cup and, optionally, an ion counter with or without a retardation lens. The Faraday cup is connected to a current amplifier, whose signal is digitized by a high linearity voltage to frequency converter. The instrument was originally manufactured by Thermo Finnigan, which has since been replaced by Thermo Scientific (part of Thermo Fisher Scientific). This model is no longer in production.</gco:CharacterString>
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