http://lod.bco-dmo.org/id/dataset/957694
eng; USA
utf8
dataset
Highest level of data collection, from a common set of sensors or instrumentation, usually within the same research project
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
2025-04-02
ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data
ISO 19115-2:2009(E)
Total alkalinity from an experiment testing the suitability of high-density polyethylene (HDPE) for collection and long-term storage of total alkalinity samples using laboratory-manipulated oligotrophic Atlantic surface water
2025-04-03
publication
2025-04-03
revision
Marine Biological Laboratory/Woods Hole Oceanographic Institution Library (MBLWHOI DLA)
2025-04-09
publication
https://doi.org/10.26008/1912/bco-dmo.957694.1
Ryan Woosley
Massachusetts Institute of Technology
principalInvestigator
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
publisher
Cite this dataset as: Woosley, R., Neithardt, D., Bruno, J. A. (2025) Total alkalinity from an experiment testing the suitability of high-density polyethylene (HDPE) for collection and long-term storage of total alkalinity samples using laboratory-manipulated oligotrophic Atlantic surface water. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2025-04-03 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.957694.1 [access date]
TA HDPE bottle storage test Dataset Description: Methods and Sampling: <p>125-milliliter (mL) high-density polyethylene (HDPE)&nbsp;oblong wide-mouth bottles certified to meet EPA performance-based standards for metals, cyanide, and fluoride (Fisher Scientific product number 05-721-147) were used. The bottles had been previously used on GP17-OCE (R/V Roger Revelle cruise RR2214). Bottles were pretreated in one of five treatments: 1.) no further conditioning, 2.) 1-week soak in low nutrient surface seawater, 3.) 2-week soak in low nutrient surface seawater 4.) 1-week soak in milli-Q water or 5.) a 2-week soak in milli-Q water.</p>
<p>After the treatment, the bottles were rinsed with milli-Q water 3 times and allowed to dry in a fume hood. All of the bottles were then filled with low-nutrient surface seawater collected from the North Atlantic (39˚ 46.406'&nbsp;N, 70˚ 53.065'&nbsp;W on October 10, 2019). A 20-liter (L)&nbsp;carboy was filled with the seawater (that had previously been poisoned to ~0.04% HgCl2) by filtering through a 0.8/0.2-micrometer (um)&nbsp;AcroPak™ 1000 filter (Pall Laboratories, Port Washington, New York USA, product number 1515-002). After filtering, the carboy was shaken vigorously to ensure it was well mixed and allowed to equilibrate overnight. The practical salinity of the water was 34.992, and the initial TA was determined to be 2299.68 ±0.59 (N=5). More details can be found in Woosley et al. (submitted).</p>
<p><strong>Instrumentation:</strong><br />
Samples were analyzed in the lab for total alkalinity using a custom-designed open cell titration with non-linear least squares fitting designed and built by the laboratory of Andrew G. Dickson (University of California, San Diego) and described in detail in Dickson et al. (2003).</p>
Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-2148468 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=2148468
completed
Ryan Woosley
Massachusetts Institute of Technology
617-253-1984
77 Massachusetts Ave Bldg. 54-1414
Cambridge
MA
02139
USA
rwoosley@mit.edu
pointOfContact
asNeeded
Dataset Version: 1
Unknown
Bottle_ID
Soak_solution
Soak_Duration
Bottle_Number
Analysis_Date_Time_EST
Total_Alkalinity
Analysis_Flag
high-density polyethylene (HDPE) oblong wide-mouth bottles
custom designed open cell titration
theme
None, User defined
sample identification
treatment
number of replicates
ISO_DateTime_Local
total alkalinity (TA)
quality flag
featureType
BCO-DMO Standard Parameters
High density polyethylene water bottle
Titrator
instrument
BCO-DMO Standard Instruments
otherRestrictions
otherRestrictions
Access Constraints: none. Use Constraints: Please follow guidelines at: http://www.bco-dmo.org/terms-use Distribution liability: Under no circumstances shall BCO-DMO be liable for any direct, incidental, special, consequential, indirect, or punitive damages that result from the use of, or the inability to use, the materials in this data submission. If you are dissatisfied with any materials in this data submission your sole and exclusive remedy is to discontinue use.
US GEOTRACES GP17-OCE and GP17-ANT: Inorganic Carbon Cycling in the South Pacific and Southern Oceans by Direct Measurement
https://osprey.bco-dmo.org/project/890561
US GEOTRACES GP17-OCE and GP17-ANT: Inorganic Carbon Cycling in the South Pacific and Southern Oceans by Direct Measurement
<p><em><strong>NSF Award Abstract</strong></em><br />
The oceans help to slow climate change by absorbing about a quarter of the carbon dioxide (CO2) produced by burning of fossil fuels and other human activities. The Pacific and Southern Oceans are known to take up and store significant amounts of anthropogenic CO2, but many questions regarding the amount, variability, and biogeochemical and ecological impacts remain unanswered. This research will focus on answering some of those questions in two areas of the Pacific by analyzing samples for total CO2, total alkalinity, and pH on two GEOTRACES cruises, GP17-OCE and GP17-ANT. The project will support several undergraduate student researchers and create educational modules on ocean acidification for general public and K-12 students.</p>
<p>On the GP17-OCE expedition in the south Pacific, sub-decadal scale variability in the uptake of CO2 and resulting decrease in pH (termed ocean acidification) will be examined by comparing data collected on this expedition with data from prior occupations of the line in 1991, 2005 and 2014. An extended multilinear regression technique will be used to separate natural variability from human induced changes. The second expedition, GP17-ANT, covers the Amundsen Sea, an area with few prior carbon measurements. This sea is perennially ice-covered with several seasonal polynyas (areas of open water surrounded by sea ice) and exhibits complex water circulation making the contribution to the global carbon cycle uncertain. The data collected from this expedition will examine several hypotheses regarding how carbon is taken up, mixed, and recirculated in the region, how glacial ice melt, sea ice, and biological productivity influence the carbon cycle, and provide baseline measurements against future data to determine changes in the carbon cycle of the region over time. Both expeditions will leverage the myriad of other parameters being measured, particularly trace metals such as iron and zinc, to examine how cycling of carbon and trace metals are interlinked through pH.</p>
<p>This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.</p>
GP17-OCE and GP17-ANT Inorganic Carbon
largerWorkCitation
project
eng; USA
oceans
2025-01-07
2025-01-24
South Pacific and Amundsen Sea
0
BCO-DMO catalogue of parameters from Total alkalinity from an experiment testing the suitability of high-density polyethylene (HDPE) for collection and long-term storage of total alkalinity samples using laboratory-manipulated oligotrophic Atlantic surface water
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
http://lod.bco-dmo.org/id/dataset-parameter/957753.rdf
Name: Bottle_ID
Units: unitless
Description: <p>Bottle identifier (label given to sample)</p>
http://lod.bco-dmo.org/id/dataset-parameter/957754.rdf
Name: Soak_solution
Units: unitless
Description: <p>Solution used for pre-treatment soak (None, Milli-q water, or Seawater)</p>
http://lod.bco-dmo.org/id/dataset-parameter/957755.rdf
Name: Soak_Duration
Units: weeks
Description: <p>Soak duration (number of weeks)</p>
http://lod.bco-dmo.org/id/dataset-parameter/957756.rdf
Name: Bottle_Number
Units: unitless
Description: <p>Number of bottle for each treatment</p>
http://lod.bco-dmo.org/id/dataset-parameter/957757.rdf
Name: Analysis_Date_Time_EST
Units: unitless
Description: <p>Analysis date and time in Eastern Standard Time in ISO8601 format</p>
http://lod.bco-dmo.org/id/dataset-parameter/957758.rdf
Name: Total_Alkalinity
Units: micromoles per kilogram seawater (umol/kg_sw)
Description: <p>Total Alkalinity</p>
http://lod.bco-dmo.org/id/dataset-parameter/957759.rdf
Name: Analysis_Flag
Units: unitless
Description: <p>WOCE QC flagging scheme</p>
GB/NERC/BODC > British Oceanographic Data Centre, Natural Environment Research Council, United Kingdom
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
5175
https://darchive.mblwhoilibrary.org/server/api/core/bitstreams/3cb349cd-2d33-41a1-91df-3e4969feea9d/content
download
https://doi.org/10.26008/1912/bco-dmo.957694.1
download
onLine
dataset
<p>125-milliliter (mL) high-density polyethylene (HDPE)&nbsp;oblong wide-mouth bottles certified to meet EPA performance-based standards for metals, cyanide, and fluoride (Fisher Scientific product number 05-721-147) were used. The bottles had been previously used on GP17-OCE (R/V Roger Revelle cruise RR2214). Bottles were pretreated in one of five treatments: 1.) no further conditioning, 2.) 1-week soak in low nutrient surface seawater, 3.) 2-week soak in low nutrient surface seawater 4.) 1-week soak in milli-Q water or 5.) a 2-week soak in milli-Q water.</p>
<p>After the treatment, the bottles were rinsed with milli-Q water 3 times and allowed to dry in a fume hood. All of the bottles were then filled with low-nutrient surface seawater collected from the North Atlantic (39˚ 46.406'&nbsp;N, 70˚ 53.065'&nbsp;W on October 10, 2019). A 20-liter (L)&nbsp;carboy was filled with the seawater (that had previously been poisoned to ~0.04% HgCl2) by filtering through a 0.8/0.2-micrometer (um)&nbsp;AcroPak™ 1000 filter (Pall Laboratories, Port Washington, New York USA, product number 1515-002). After filtering, the carboy was shaken vigorously to ensure it was well mixed and allowed to equilibrate overnight. The practical salinity of the water was 34.992, and the initial TA was determined to be 2299.68 ±0.59 (N=5). More details can be found in Woosley et al. (submitted).</p>
<p><strong>Instrumentation:</strong><br />
Samples were analyzed in the lab for total alkalinity using a custom-designed open cell titration with non-linear least squares fitting designed and built by the laboratory of Andrew G. Dickson (University of California, San Diego) and described in detail in Dickson et al. (2003).</p>
Specified by the Principal Investigator(s)
<p>Data were quality controlled and flagged for any known analytical issues that occurred for a given sample.</p>
Specified by the Principal Investigator(s)
- Imported original file "HDPE Lab Test Submit to BCODMO.xlsx" into the BCO-DMO system.
- Marked "-999" as a missing data value (missing data are empty/blank in the final csv file).
- Renamed fields to comply with BCO-DMO naming conventions.
- Converted the date-time column to ISO 8601 format.
- Saved final file as "957694_v1_ta_hdpe_bottle_storage_test.csv".
Specified by BCO-DMO Data Managers
asNeeded
7.x-1.1
Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Unavailable
508-289-2009
WHOI MS#36
Woods Hole
MA
02543
USA
info@bco-dmo.org
http://www.bco-dmo.org
Monday - Friday 8:00am - 5:00pm
For questions regarding this resource, please contact BCO-DMO via the email address provided.
pointOfContact
high-density polyethylene (HDPE) oblong wide-mouth bottles
high-density polyethylene (HDPE) oblong wide-mouth bottles
PI Supplied Instrument Name: high-density polyethylene (HDPE) oblong wide-mouth bottles PI Supplied Instrument Description:125 mL HDPE oblong wide-mouth bottles certified to meet EPA performance-based standards for metals, cyanide, and fluoride (Fisher Scientific product number 05-721-147) were used. Instrument Name: High density polyethylene water bottle Instrument Short Name:HDPE bottle Instrument Description: A high density polyethylene (HDPE) water bottle. Often used for surface sampling from small boats. HDPE has a somewhat higher chemical resistance than low density polyethylene (LDPE). HDPE is also somewhat harder and more opaque and it can withstand higher temperatures (120 degrees Celsius for short periods, 110 degrees Celsius continuously).
custom designed open cell titration
custom designed open cell titration
PI Supplied Instrument Name: custom designed open cell titration PI Supplied Instrument Description:Samples were analyzed in the lab for total alkalinity using a custom designed open cell titration with non-linear least squares fitting designed and built by the laboratory of Andrew G. Dickson (University of California, San Diego) and described in detail in Dickson et al. (2003). Instrument Name: Titrator Instrument Short Name:Titrator Instrument Description: Titrators are instruments that incrementally add quantified aliquots of a reagent to a sample until the end-point of a chemical reaction is reached. Community Standard Description: http://vocab.nerc.ac.uk/collection/L05/current/LAB12/