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                <gmx:Anchor xlink:href="https://ror.org/00ysfqy60" xlink:title="ROR ID" xlink:actuate="onRequest">Oregon State University</gmx:Anchor>
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            <gco:CharacterString>Cite this dataset as: Tamborski, J., Lindgren, A., Alorda-Kleinglass, A., Buck, K. N., Boiteau, R. M., Chappell, P. D., Conway, T. M., Smith, C., Knapp, A. N. (2025) Dissolved radium from STING I Cruise AE2305 on R/V Atlantic Explorer and STING II Cruise EN704 on R/V Endeavor and U.S. Geological Survey small boat surveys in the Gulf of Mexico from Feb to Jul 2023. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2025-09-18 [if applicable, indicate subset used]. doi:10.26008/1912/bco-dmo.982223.1 [access date]</gco:CharacterString>
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        <gco:CharacterString>STING I and STING II radium Dataset Description:  Methods and Sampling: &amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Collection&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples were collected&amp;amp;nbsp;on&amp;amp;nbsp;STING I and STING II during cruises AE2305 (R/V Atlantic Explorer, Feb 20th - Mar 5th 2023), EN704 (R/V Endeavor Jul 1-12, 2023), and&amp;amp;nbsp;23WFS02 (R/V Sallenger, Jun 3-7, 2023).&amp;amp;nbsp;Surface water salinity and temperature measurements were taken from the ship underway system (AE2305 and EN704) and a flow-cell (23WFS02; YSI ProDSS; Chestang et al., 2025), and from the ship CTD for intermediate and bottom waters.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Surface samples were collected at all stations via submersible pump lowered 1.5 m below the water’s surface. Intermediate depth and bottom water samples were collected at stations along three transects that crossed the entire shelf from nearshore to the shelf break via Niskin bottles on the CTD Rosette. Samples ranged from 114 to 170 L in volume&amp;amp;nbsp;on AE2305 and EN704, and ~45 – 60 L in volume on 23WFS02 (Chestang et al., 2025).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples were passed through a 1 µm prefilter to remove suspended particles before being filtered at &amp;amp;lt; 1L/min onto a MnO&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;-coated acrylic fiber to adsorb Ra. Samples were washed with Ra-free deionized water to remove salts and remaining particles, then dried to a 1:1 fiber:water mass ratio (Moore, 2008).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Measurements&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Short-lived &amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra were measured underway using a delayed coincidence counter (RaDeCC) (Moore and Arnold 1996), following recommended best-practices (Diego-Feliu et al. 2020). Additional measurements were performed in the laboratory one month (&amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Th) and two months (&amp;lt;sup&amp;gt;227&amp;lt;/sup&amp;gt;Ac) post-collection to assess parent activities supporting &amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra. &amp;lt;sup&amp;gt;232&amp;lt;/sup&amp;gt;Th standards in equilibrium with &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Th were measured separately in the lab and underway to assess detector efficiencies for &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra (Moore &amp;amp;amp; Cai, 2013); background counts were similarly measured both in the lab and at sea. Errors are propagated from counting statistics, chance-coincidence corrections, and detector efficiencies (Diego-Feliu et al. 2020). Short-lived Ra isotope specific activity from 23WFS02, with accompanying physicochemical parameters, is reported in Chestang et al. (2025).&amp;amp;nbsp;Following, the Mn-coated acrylic fibers were combusted at 850 °C for 16 hours, homogenized, sealed with epoxy resin, and incubated for a minimum of three weeks until &amp;lt;sup&amp;gt;222&amp;lt;/sup&amp;gt;Rn was in secular equilibrium with its parent &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra. Long-lived Ra isotopes measured via gamma spectroscopy in a Ge well-type detector for &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra (352 keV photopeak) and &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Ra (average of 338 and 911 keV photopeak’s), with efficiencies calibrated using standards prepared in the same fashion as the seawater samples (Charette et al., 2001).&amp;lt;/p&amp;gt;</gco:CharacterString>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/880515.rdf" xlink:title="OCE-2148836" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-2148836 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=2148836</gmx:Anchor>
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        <gmx:Anchor xlink:href="http://lod.bco-dmo.org/id/award/880530.rdf" xlink:title="OCE-2149091" xlink:actuate="onRequest">Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-2149091 Award URL: https://www.nsf.gov/awardsearch/show-award?AWD_ID=2149091</gmx:Anchor>
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This project will investigate how groundwater discharge delivers important nutrients to the coastal ecosystems of the West Florida Shelf. Preliminary studies indicate that groundwater may supply both dissolved organic nitrogen (DON) and iron in this region. In coastal ecosystems like the West Florida Shelf that have very low nitrate and ammonium concentrations, DON is the main form of nitrogen available to organisms. Nitrogen cycling is strongly affected by iron availability because iron is essential for both photosynthesis and for nitrogen fixation. This study will investigate the sources and composition of DON and iron, and their influence on the coastal ecosystem. The team will sample offshore groundwater wells, river and estuarine waters, and conduct two expeditions across the West Florida Shelf in winter and summer. Investigators will participate in K-12 and outreach activities to increase awareness of the project and related science. The project will fund the work of six graduate and eight undergraduate students across five institutions, furthering NSF’s goals of education and training.&lt;/p&gt;
&lt;p&gt;Motivated by preliminary observations of unexplained, tightly-correlated DON and dissolved iron concentrations across the West Florida Shelf (WFS), the proposed work will quantify the flux and isotopic signatures of submarine groundwater discharge (SGD)-derived DON and iron to the WFS, and evaluate the bioavailability of this temporally-variable source using four seasonal near-shore campaigns sampling offshore groundwater wells, estuarine, and riverine endmembers and two cross-shelf cruises. The work will evaluate whether SGD stimulates nitrogen fixation on the WFS, and the potential for the stimulated nitrogen fixation to further modify the chemistry of DON and dissolved iron in the region. The cross-shelf cruises will investigate hypothesized periods of maximum SGD and Trichodesmium abundance (June), and reduced river discharge and SGD (February), thus comparing two distinct biogeochemical regimes. The concentrations and isotopic compositions of DON and dissolved iron, molecular composition of DON, and the concentration and composition of iron-binding ligands will be characterized. Nitrogen fixation rates and Trichodesmium spp. abundance and expression of iron stress genes will be measured. Fluxes of DON and iron from SGD and rivers will be quantified with radium isotope mass balances. The impacts of SGD on nitrogen fixation and DON/ligand production will be constrained with incubations of natural phytoplankton communities with submarine groundwater amendments. Two hypotheses will be tested: 1) SGD is the dominant source of bioavailable DON and dissolved iron on the WFS, and 2) SGD-alleviation of iron stress changes the dominant Trichodesmium species on the WFS, increases nitrogen fixation rates and modifies DON and iron composition. Overall, the work will establish connections between marine nitrogen and iron cycling and evaluate the potential for coastal inputs to modify water along the WFS before export to the Atlantic Ocean. This study will thus provide a framework to consider these boundary fluxes in oligotrophic coastal systems and the relative importance of rivers and SGD as sources of nitrogen and iron in other analogous locations, such as coastal systems in Australia, India, and Africa, where nitrogen fixation and SGD have also been documented.&lt;/p&gt;
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	Name: Cruise_name
	Units: unitless
	Description: &lt;p&gt;Cruise name&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983907.rdf
	Name: Station
	Units: unitless
	Description: &lt;p&gt;Station number&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983908.rdf
	Name: STING_ID
	Units: unitless
	Description: &lt;p&gt;STING cruise sample ID&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983909.rdf
	Name: Sample_Name
	Units: unitless
	Description: &lt;p&gt;Sample ID. ID code = cruise_YYMMDD_station;&amp;quot;S&amp;quot; refers to &amp;quot;surface&amp;quot;; &amp;quot;D&amp;quot; refers to &amp;quot;deep&amp;quot;&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983911.rdf
	Name: DateTime_UTC
	Units: unitless
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http://lod.bco-dmo.org/id/dataset-parameter/983912.rdf
	Name: Latitude
	Units: decimal degrees
	Description: &lt;p&gt;Latitude of station (Positive is North)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983913.rdf
	Name: Longitude
	Units: decimal degrees
	Description: &lt;p&gt;Longitude of station (Negative is West)&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983914.rdf
	Name: Depth
	Units: meters
	Description: &lt;p&gt;Depth of sample&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983915.rdf
	Name: Salinity
	Units: psu
	Description: &lt;p&gt;Surface water salinity measurements taken from the ship underway system (AE2305 and EN704) and a flow-cell (23WFS02; YSI ProDSS; Chestang et al., 2025), and from the ship CTD for intermediate and bottom waters&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983916.rdf
	Name: Temperature
	Units: degrees Celsius
	Description: &lt;p&gt;Surface water temperature measurements taken from the ship underway system (AE2305 and EN704) and a flow-cell (23WFS02; YSI ProDSS; Chestang et al., 2025), and from the ship CTD for intermediate and bottom waters&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983917.rdf
	Name: Ra223
	Units: dpm/100L
	Description: &lt;p&gt;Ra-223 isotope specific activity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983918.rdf
	Name: Ra223_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-223 isotope specific activity; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983919.rdf
	Name: Ra223_err
	Units: dpm/100L
	Description: &lt;p&gt;Ra-223 isotope specific activity uncertainty&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983920.rdf
	Name: Ra223_err_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-223 isotope specific activity uncertainty; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983921.rdf
	Name: Ra224
	Units: dpm/100L
	Description: &lt;p&gt;Ra-224 isotope specific activity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983922.rdf
	Name: Ra224_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-224 isotope specific activity; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983923.rdf
	Name: Ra224_err
	Units: dpm/100L
	Description: &lt;p&gt;Ra-224 isotope specific activity uncertainty&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983924.rdf
	Name: Ra224_err_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-224 isotope specific activity uncertainty; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983925.rdf
	Name: Ra226
	Units: dpm/100L
	Description: &lt;p&gt;Ra-226 isotope specific activity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983926.rdf
	Name: Ra226_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-226 isotope specific activity; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983927.rdf
	Name: Ra226_err
	Units: dpm/100L
	Description: &lt;p&gt;Ra-226 isotope specific activity uncertainty&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983928.rdf
	Name: Ra226_err_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-226 isotope specific activity uncertainty; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983929.rdf
	Name: Ra228
	Units: dpm/100L
	Description: &lt;p&gt;Ra-228 isotope specific activity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983930.rdf
	Name: Ra228_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-228 isotope specific activity; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983931.rdf
	Name: Ra228_err
	Units: dpm/100L
	Description: &lt;p&gt;Ra-228 isotope specific activity uncertainty&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983932.rdf
	Name: Ra228_err_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ra-228 isotope specific activity uncertainty; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983933.rdf
	Name: Th228
	Units: dpm/100L
	Description: &lt;p&gt;Th-228 isotope specific activity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983934.rdf
	Name: Th228_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Th-228 isotope specific activity; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983935.rdf
	Name: Th228_err
	Units: dpm/100L
	Description: &lt;p&gt;Th-228 isotope specific activity uncertainty&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983936.rdf
	Name: Th228_err_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Th-228 isotope specific activity uncertainty; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983937.rdf
	Name: Ac227
	Units: dpm/100L
	Description: &lt;p&gt;Ac-227 isotope specific activity&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983938.rdf
	Name: Ac227_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ac-227 isotope specific activity; 0=N/A 1=BDL&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983939.rdf
	Name: Ac227_err
	Units: dpm/100L
	Description: &lt;p&gt;Ac-227 isotope specific activity uncertainty&lt;/p&gt; 
http://lod.bco-dmo.org/id/dataset-parameter/983940.rdf
	Name: Ac227_err_BDL_flag
	Units: unitless
	Description: &lt;p&gt;Below detection limit (BDL) flag for Ac-227 isotope specific activity uncertainty; 0=N/A 1=BDL&lt;/p&gt; 
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&amp;lt;p&amp;gt;Samples were collected&amp;amp;nbsp;on&amp;amp;nbsp;STING I and STING II during cruises AE2305 (R/V Atlantic Explorer, Feb 20th - Mar 5th 2023), EN704 (R/V Endeavor Jul 1-12, 2023), and&amp;amp;nbsp;23WFS02 (R/V Sallenger, Jun 3-7, 2023).&amp;amp;nbsp;Surface water salinity and temperature measurements were taken from the ship underway system (AE2305 and EN704) and a flow-cell (23WFS02; YSI ProDSS; Chestang et al., 2025), and from the ship CTD for intermediate and bottom waters.&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Surface samples were collected at all stations via submersible pump lowered 1.5 m below the water’s surface. Intermediate depth and bottom water samples were collected at stations along three transects that crossed the entire shelf from nearshore to the shelf break via Niskin bottles on the CTD Rosette. Samples ranged from 114 to 170 L in volume&amp;amp;nbsp;on AE2305 and EN704, and ~45 – 60 L in volume on 23WFS02 (Chestang et al., 2025).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Samples were passed through a 1 µm prefilter to remove suspended particles before being filtered at &amp;amp;lt; 1L/min onto a MnO&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt;-coated acrylic fiber to adsorb Ra. Samples were washed with Ra-free deionized water to remove salts and remaining particles, then dried to a 1:1 fiber:water mass ratio (Moore, 2008).&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;&amp;lt;strong&amp;gt;Measurements&amp;lt;/strong&amp;gt;&amp;lt;/p&amp;gt;

&amp;lt;p&amp;gt;Short-lived &amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra were measured underway using a delayed coincidence counter (RaDeCC) (Moore and Arnold 1996), following recommended best-practices (Diego-Feliu et al. 2020). Additional measurements were performed in the laboratory one month (&amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Th) and two months (&amp;lt;sup&amp;gt;227&amp;lt;/sup&amp;gt;Ac) post-collection to assess parent activities supporting &amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra. &amp;lt;sup&amp;gt;232&amp;lt;/sup&amp;gt;Th standards in equilibrium with &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Th were measured separately in the lab and underway to assess detector efficiencies for &amp;lt;sup&amp;gt;224&amp;lt;/sup&amp;gt;Ra and &amp;lt;sup&amp;gt;223&amp;lt;/sup&amp;gt;Ra (Moore &amp;amp;amp; Cai, 2013); background counts were similarly measured both in the lab and at sea. Errors are propagated from counting statistics, chance-coincidence corrections, and detector efficiencies (Diego-Feliu et al. 2020). Short-lived Ra isotope specific activity from 23WFS02, with accompanying physicochemical parameters, is reported in Chestang et al. (2025).&amp;amp;nbsp;Following, the Mn-coated acrylic fibers were combusted at 850 °C for 16 hours, homogenized, sealed with epoxy resin, and incubated for a minimum of three weeks until &amp;lt;sup&amp;gt;222&amp;lt;/sup&amp;gt;Rn was in secular equilibrium with its parent &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra. Long-lived Ra isotopes measured via gamma spectroscopy in a Ge well-type detector for &amp;lt;sup&amp;gt;226&amp;lt;/sup&amp;gt;Ra (352 keV photopeak) and &amp;lt;sup&amp;gt;228&amp;lt;/sup&amp;gt;Ra (average of 338 and 911 keV photopeak’s), with efficiencies calibrated using standards prepared in the same fashion as the seawater samples (Charette et al., 2001).&amp;lt;/p&amp;gt;</gco:CharacterString>
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                  <gco:CharacterString>- Imported &amp;quot;BCO-DMO_STING-I_Radium_Dataset.xlsx&amp;quot; and &amp;quot;BCO-DMO_STING-II_Radium_Dataset.xlsx&amp;quot; into the BCO-DMO system without any formatting
- Concatenated the data sources together, creating a cruise name column to identify &amp;quot;STING I&amp;quot; and STING II&amp;quot;
- Created flag column for all measurements to indicate BDL
- Converted local datetime into a new UTC datetime field and removed the local timestamp, as requested by submitter
- Exported file as &amp;quot;982223_v1_sting1_sting2_radium.csv&amp;quot;</gco:CharacterString>
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References:
Giffin, C., A. Kaufman, W.S. Broecker (1963). Delayed coincidence counter for the assay of actinon and thoron. J. Geophys. Res., 68, pp. 1749-1757.
Moore, W.S., R. Arnold (1996). Measurement of 223Ra and 224Ra in coastal waters using a delayed coincidence counter. J. Geophys. Res., 101 (1996), pp. 1321-1329.
Charette, Matthew A.; Dulaiova, Henrieta; Gonneea, Meagan E.; Henderson, Paul B.; Moore, Willard S.; Scholten, Jan C.; Pham, M. K. (2012). GEOTRACES radium isotopes interlaboratory comparison experiment. Limnology and Oceanography - Methods, vol 10, pg 451.</gco:CharacterString>
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