Dataset: PO4_SiOH4

Name: Phosphate (PO4) and Silicate (SiOH4) concentrations from R/V Thomas G. Thompson and R/V Kilo Moana cruises TN277, KM1301, KM1312 in the Eastern North Pacific Ocean from 2012-2013 (POWOW project)
Published: 2014-07-10
Keywords: oceans

Cite This Dataset

DOI:10.1575/1912/bco-dmo.3756.2

Spatial Extent: N:46.6888 E:-118.316 S:21.3428 W:-160.6166

Temporal Extent: 2012-03-01 - 2013-07-27

Project:

Seasonal and decadal changes in temperature drive Prochlorococcus ecotype distribution patterns (POWOW)

Principal Investigator:

Zackary I. Johnson (Duke University)

BCO-DMO Data Manager:

Shannon Rauch (Woods Hole Oceanographic Institution, WHOI BCO-DMO)

Version:

Version Date:

2014-07-10

Restricted:

Validated:

Yes

Current State:

Final no updates expected

Phosphate (PO4) and Silicate (SiOH4) concentrations from R/V Thomas G. Thompson and R/V Kilo Moana cruises TN277, KM1301, KM1312 in the Eastern North Pacific Ocean from 2012-2013 (POWOW project)

Abstract:

Phosphate (PO4) and Silicate (SiOH4) concentrations from R/V Thomas G. Thompson and R/V Kilo Moana cruises TN277, KM1301, KM1312 in the Eastern North Pacific Ocean from 2012-2013 (POWOW project)

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Archival Copy

Version Date	Archive	Persistent Identifier	Date Assigned
2014-07-10	Marine Biological Laboratory/Woods Hole Oceanographic Institution Library (MBLWHOI DLA)	10.1575/1912/bco-dmo.3756.2	2019-03-05

Description

Phosphate (PO4) and Silicate (SiOH4) concentrations in uM from 3 POWOW cruises (TN277, KM1301, and KM1312). Samples that had a mean concentration (mean of replicated samples) below the nominal detection limit are reported as zero.

Also see related inorganic nutrient data from this project:
Ammonium (NH4) https://www.bco-dmo.org/dataset/3754
Nitrite and Nitrate (NO2, NO3) https://www.bco-dmo.org/dataset/3755

Methods & Sampling

Water for later nutrient analysis was sampled in duplicate into HCl-cleaned HDPE bottles (VWR#414004-110) and stored at -80 degrees C until later analysis using an Astoria-Pacific A2 autoanalyzer following the manufacturer's recommended protocols running each replicate sample in duplicate. Certified reference materials were used to verify protocols (Inorganic Ventures: QCP-NT, QCP-NUT-1, CGSI1-1). The detection limits are as follows:
The detection limit of PO4 was 0.05 uM for samples from all 3 cruises.
The detection limit of SiOH4 was 0.2 uM for samples from POWOW1 and POWOW2 cruises.
The detection limit of SiOH4 was 0.1 uM for samples from POWOW3 cruise.

Data Processing Description

BCO-DMO edits made:
- Parameter names have been changed to conform to BCO-DMO conventions.
- month_utc, day_utc, year, and time_utc were added, based on the original ISO_DateTime_UTC field.
- Rosette bottle numbers were added from the CTD cast sheets for POWOW1.
- Changed latitude of POWOW3 cast CTD028 to value on cast sheet.
- 'NaN' was replaced with 'nd' to indicate 'no data'.

Data Files

File
PO4_SiOH4.csv (Comma Separated Values (.csv), 121.70 KB) MD5:c8d36fdef956e4b34ef7fd1bb37daad6 Primary data file for dataset ID 3756

More Information about this dataset

Funding Sources

Funding Source	Award Number
NSF Division of Ocean Sciences	OCE-1031064

Deployments

Deployment	Synonyms	Start Date	Platform	Investigator
KM1301	POWOW2	2013-01-10	R/V Kilo Moana	Zackary I. Johnson (Chief Scientist) Erik Zinser (Co-Chief Scientist) Zackary I. Johnson (Contact)	data info
KM1312	POWOW3	2013-07-01	R/V Kilo Moana	Zackary I. Johnson (Chief Scientist) Erik Zinser (Co-Chief Scientist) Zackary I. Johnson (Contact)	data info
TN277	POWOW1	2012-02-29	R/V Thomas G. Thompson	Zackary I. Johnson (Chief Scientist) Erik Zinser (Co-Chief Scientist) Zackary I. Johnson (Contact)	data info

Instruments

Niskin bottle

Supplied Description:

Instrument Type

Generic Name: Niskin bottle

Community Identifier: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0412/

Generic Description:

A Niskin bottle (a next generation water sampler based on the Nansen bottle) is a cylindrical, non-metallic water collection device with stoppers at both ends. The bottles can be attached individually on a hydrowire or deployed in 12, 24, or 36 bottle Rosette systems mounted on a frame and combined with a CTD. Niskin bottles are used to collect discrete water samples for a range of measurements including pigments, nutrients, plankton, etc.

Nutrient Autoanalyzer

Supplied Description:

Nutrients were analyzed using an Astoria-Pacific A2 autoanalyzer following the manufacturer’s recommended protocols.

Instrument Type

Generic Name: Nutrient Autoanalyzer

Community Identifier: http://vocab.nerc.ac.uk/collection/L05/current/LAB04/

Generic Description:

Nutrient Autoanalyzer is a generic term used when specific type, make and model were not specified. In general, a Nutrient Autoanalyzer is an automated flow-thru system for doing nutrient analysis (nitrate, ammonium, orthophosphate, and silicate) on seawater samples.

Parameters

Date and time formats are described in python strftime() syntax.

Supplied Name	Supplied description	Supplied Units	Standard Name
cruise_name	Cruise identifier (POWOW1 = TN277 = R/V Thomas G. Thompson cruise 277; POWOW2 = KM1301 = R/V Kilo Moana cruise 1301; POWOW3 = KM1312 = R/V Kilo Moana cruise 1312).	text	cruise_name
cast	Consecutive CTD cast number. CTD numbers are unique and sequential across stations.	unitless	cast
lat	Latitude at start of CTD cast. Positive = North.	decimal degrees	lat
lon	Longitude at start of CTD cast. Positive = East.	decimal degrees	lon
depth_w	Depth of the water (bottom depth) at sampling station.	meters	depth_w
month_utc	2-digit month of year, UTC.	mm (01 to 12)	month_utc
day_utc	2-digit day of month, UTC.	dd (01 to 31)	day_utc
year	4-digit year. in YYYY format	unitless	year
time_utc	Time (UTC) at start of sample collection, 24-hour clock.	HHMM.mm	time_utc
ISO_DateTime_UTC	Date/Time (UTC) ISO8601 formatted. T indicates start of time string; Z indicates UTC.	YYYY-mm-ddTHH:MM:SS.ssZ	ISO_DateTime_UTC
depth	Sample depth.	meters	depth
bot	Rosette position of the bottle.	unitless	bot
PO4	Phosphate (PO4) concentration, uM.	micromolar (uM)	PO4
SiOH4	Silicate (SiOH4) concentration, uM.	micromolar (uM)	Silicate

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