Dataset: 234Th flux in epipelagic waters at Station ALOHA and the Equatorial Pacific from R/V Kilo Moana cruises KM1407, KM1418, & KM1515 during 2014-2015

ValidatedFinal no updates expectedDOI: 10.26008/1912/bco-dmo.806471.1Version 1 (2020-03-19)Dataset Type:Cruise Results

Principal Investigator: Claudia R. Benitez-Nelson (University of South Carolina)

Co-Principal Investigator: Jeffrey C. Drazen (University of Hawaiʻi at Mānoa)

Co-Principal Investigator: Brian N. Popp (University of Hawaiʻi at Mānoa)

BCO-DMO Data Manager: Shannon Rauch (Woods Hole Oceanographic Institution)


Project: Evaluating the relative importance of suspended and sinking particles to the meso and bathypelagic food web in the central North Pacific (SuspendSinkPart)

Project: Collaborative Research: Isotopic insights to mercury in marine food webs and how it varies with ocean biogeochemistry (Hg_Biogeochemistry)


Abstract

234Th flux in epipelagic waters at Station ALOHA and the Equatorial Pacific from R/V Kilo Moana cruises KM1407, KM1418, & KM1515 during 2014-2015.

Total ²³⁴Th was measured in samples of seawater collected at discrete depths using Niskin bottles as described in Umhau et al. (2019). Briefly, 2 L of seawater was collected at each selected depth. Samples were spiked with ²³⁰Th as a yield tracer and acidified to pH ~ 1 using concentrated nitric acid. After equilibration, ~ 6 hours later, KMnO₄ and MnCl₂ were added and the pH adjusted to ~ 9 with concentrated NH₄OH in order to co-precipitate Th via the formation of MnO₂. After eight hours, total ²³⁴Th samples were filtered onto 25 mm QMA filters, air dried, and frozen.

The ²³⁴Th flux (dpm m⁻² d⁻¹) was calculated from the ²³⁴Th:²³⁸U disequilibrium and assuming a steady state (Umhau et al. 2019). The ²³⁴Th flux at each depth was obtained by integrating the flux for the overlying depths using trapezoidal integration.

Thorium counts were made using a low level RISO beta counter within 2 weeks of sample collection.


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Results

Umhau, B. P., Benitez-Nelson, C. R., Close, H. G., Hannides, C. C. S., Motta, L., Popp, B. N., … Drazen, J. C. (2019). Seasonal and spatial changes in carbon and nitrogen fluxes estimated using 234Th:238U disequilibria in the North Pacific tropical and subtropical gyre. Marine Chemistry, 217, 103705. doi:10.1016/j.marchem.2019.103705