Dataset: Concentrations and radiocarbon signatures of SPE-DOC extracted from seawater samples on GO-SHIP cruises P16N, P18, and IO7N in the North Pacific, Eastern Pacific, and Western Indian Oceans

ValidatedFinal no updates expectedDOI: 10.26008/1912/bco-dmo.853101.1Version 1 (2021-06-28)Dataset Type:Cruise Results

Principal Investigator, Contact: Ellen R.M. Druffel (University of California-Irvine)

Student: Christian Blair Lewis (University of California-Irvine)

BCO-DMO Data Manager: Taylor Heyl (Woods Hole Oceanographic Institution)

BCO-DMO Data Manager: Shannon Rauch (Woods Hole Oceanographic Institution)


Project: Cycling of Dissolved Organic Matter in the Pacific and Indian Oceans Using Radiocarbon (DOC 14C and 13C)


Abstract

This dataset includes concentrations and radiocarbon signatures of solid-phase extracted dissolved organic carbon (SPE-DOC) from seawater samples. Water samples were collected on GO-SHIP cruises P16N, P18, and IO7N in the North Pacific, Eastern Pacific, and Western Indian Oceans from 2015 to 2018.

Seawater was sampled from Niskin bottles on GO-SHIP P16N, P18, and IO7N cruises using acid-cleaned silicone tubing (soaked in 10% HCl). Seawater from depths shallower than 200m was filtered using pre-combusted Whatman GF/F 0.7 micrometer (µm) filters. Solid-phase extracted dissolved organic carbon (SPE-DOC) was extracted using Bond Elut PPL 1 gram resins and established protocols (Dittmar et al., 2008). On P18 and IO7N, SPE-DOC was extracted on the vessel. Seawater from P16N was stored frozen until processing at the laboratory at University of California, Irvine (UCI).

SPE-DOC elutions in methanol follow established protocols (Dittmar et al., 2008), that have been slightly adapted to increase carbon yields (Lewis et al., 2020). After elution, SPE-DOC was dried using a centrifugal evaporator, sealed on a vacuum line, and combusted at 850C for 2 hours. SPE-DOC concentrations were measured manometrically on a vacuum line, and radiocarbon measurements were performed at the Keck Carbon Cycle Accelerator Mass Spectrometry Lab at the University of California, Irvine.

Refer to "Related Datasets" for the related Niskin bottle data from these GO-SHIP cruises. Seawater from multiple Niskin bottles was integrated for solid-phase extraction. The stations and depth ranges listed (between the minimum and maximum depths) refer to the Niskin bottles from the GO-SHIP bottle file in related datasets.


Related Datasets

IsRelatedTo

Dataset: SPE-DOC 13C from GO-SHIP cruises (2015 to 2018)
Lewis, C. B., Walker, B. D., Druffel, E. R. (2024) Stable carbon isotopic signatures of solid-phase extracted DOC from seawater collected on three GO-SHIP Repeat Hydrography Cruises in 2015-2018 along transects P16N, P18, and I07N. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2024-04-09 doi:10.26008/1912/bco-dmo.924605.1
IsSupplementedBy

Dataset: https://doi.org/10.7942/C2WC7C
Cross, J. (2015). P16N/1 2015 [Data set]. CCHDO: CLIVAR and Carbon Hydrographic Data Office. https://doi.org/10.7942/C2WC7C
IsSupplementedBy

Dataset: https://doi.org/10.7942/C21T0F
Rolf Sonnerup, B. C. (2016). P18 2016 [Data set]. CCHDO: CLIVAR and Carbon Hydrographic Data Office. https://doi.org/10.7942/C21T0F
IsSupplementedBy

Dataset: https://doi.org/10.7942/C25H2B
Volkov, D. L. (2018). I07N 2018 [Data set]. CCHDO: CLIVAR and Carbon Hydrographic Data Office. https://doi.org/10.7942/C25H2B

Related Publications

Results

Druffel, E. R. M., Griffin, S., Lewis, C. B., Rudresh, M., Garcia, N. G., Key, R. M., … Walker, B. D. (2021). Dissolved Organic Radiocarbon in the Eastern Pacific and Southern Oceans. Geophysical Research Letters, 48(10). doi:10.1029/2021gl092904
Results

Lewis, C. B., Walker, B. D., & Druffel, E. R. M. (2021). New Radiocarbon Constraints on the Global Cycling of Solid‐Phase Extractable Dissolved Organic Carbon. Geophysical Research Letters, 48(14). doi:10.1029/2020gl090995
Methods

Dittmar, T., Koch, B., Hertkorn, N., & Kattner, G. (2008). A simple and efficient method for the solid-phase extraction of dissolved organic matter (SPE-DOM) from seawater. Limnology and Oceanography: Methods, 6(6), 230–235. doi:10.4319/lom.2008.6.230
Methods

Lewis, C. B., Walker, B. D., & Druffel, E. R. M. (2020). Isotopic and optical heterogeneity of solid phase extracted marine dissolved organic carbon. Marine Chemistry, 219, 103752. doi:10.1016/j.marchem.2020.103752